Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 67, Pages 17697-17700Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201805140
Keywords
arynes; dendrimers; nanographenes; scanning probe microscopy; starphenes
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Funding
- European Union [610446]
- Agencia Estatal de Investigacion [MAT2016-78293-C6-3-R, CTQ2016-78157-R]
- Xunta de Galicia (Centro singular de investigacion de Galicia) [ED431G/09]
- Fondo Europeo de Desarrollo Regional (FEDER)
- European Research Council [682144]
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The synthesis of a threefold symmetric nanographene with 19 cata-fused benzene rings distributed within six branches is reported. This flat dendritic starphene, which is the largest unsubstituted cata-condensed PAH that has been obtained to date, was prepared in solution by means of a palladium-catalyzed aryne cyclotrimerization reaction and it was characterized on surface by scanning probe microscopy with atomic resolution.
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