Journal
CHEMISTRY OF MATERIALS
Volume 30, Issue 22, Pages 8352-8358Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.8b03926
Keywords
-
Funding
- Mitsubishi Chemical Company (Mitsubishi Chemical Center for Advanced Materials)
- Institute for Collaborative Biotechnologies [W911NF-09-0001]
Ask authors/readers for more resources
Polyhexahydrotriazines (PHT) are promising high-performance thermosets exhibiting enhanced thermal and mechanical properties. Here, we demonstrate a new solvent-free approach for the fabrication of PHT based on low-melting-point diamines enabling the production of adhesives with comparable properties to well-established epoxy adhesives. Structure property relationships were supported by small molecule model reactions that mimic the cross-linking hexahydrotriazine (HT) cores and allowed the unique reactivity of benzylamine building blocks to be demonstrated. Through a variety of spectroscopic and physical techniques, this increased molecular level understanding of monomer design led to the ability to tune acidic degradation and thermal properties.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available