Journal
CHEMICAL ENGINEERING JOURNAL
Volume 363, Issue -, Pages 285-291Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.01.089
Keywords
Ni-3(BO3)(2); Micron-rods; Anode materials; Sodium-ion batteries
Categories
Funding
- National Natural Science Foundation of China [21673136]
- national key research and development Program of China [2016YFB0901500]
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In this paper, Ni-3(BO3)(2) was synthesized via a simple solid-state reaction method and used as anode materials for sodium-ion batteries for the first time. The Ni-3(BO3)(2) exhibits a desodiation capacity of 428.9 mA h g(-1) at 200 mA g(-1) and a high capacity of 304.4 mA h g(-1) even at 2000 mA g(-1). The resulting material also shows a good cycling stability with a capacity retention of 85.4% over 50 cycles. In-situ X-ray diffraction analysis reveals the phase transition behavior of Ni-3(BO3)(2) in the first discharge process. Kinetics analysis reveals that the high-performance sodium storage is dominated by pseudocapacitance, especially at the high rate. These highlights indicate that Ni-3(BO3)(2) would have hopeful prospects as an anode material for sodium-ion batteries.
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