Article
Chemistry, Applied
Hui Su, Bijia Wang, Zhouquan Sun, Sali Wang, Xueling Feng, Zhiping Mao, Xiaofeng Sui
Summary: This study demonstrates, for the first time, the high-efficient non-destructive dissolution of cellulose in cryogenic aqueous phosphoric acid. The findings highlight the importance of phosphoric acid as a promising cellulose solvent for various applications.
CARBOHYDRATE POLYMERS
(2022)
Article
Chemistry, Applied
Karel Thielemans, Yamina De Bondt, Sander Van den Bosch, An Bautil, Chiara Roye, Aron Deneyer, Christophe M. Courtin, Bert F. Sels
Summary: In this work, short-polymer microcrystalline celluloses (SMCC) with an average polymerization degree between 29 and 70 AGU were successfully produced by combining a planetary ball mill pretreatment with mild acid hydrolysis. The desired polymerization degree could be obtained by tuning the process parameters.
CARBOHYDRATE POLYMERS
(2022)
Article
Polymer Science
Yuriy N. Malyar, Irina G. Sudakova, Valentina S. Borovkova, Anna I. Chudina, Elena V. Mazurova, Sergey A. Vorobyev, Olga Yu. Fetisova, Eugene V. Elsufiev, Ivan P. Ivanov
Summary: This paper discusses a new approach of obtaining microfibrillated cellulose with low degree of polymerization through sulfuric acid hydrolysis with simultaneous ultrasonic treatment under mild conditions. The resulting microfibrillated cellulose retains the structure of cellulose I and has high stability and thermal stability. The simultaneous hydrolysis process with ultrasonic treatment reduces the number of stages, energy costs, and expands the scope of applications.
Article
Chemistry, Physical
Jungsoo Han, Yungbum Seo
Summary: In this study, three alkaline mixtures and sulfuric acid were used as cellulose solvents at low temperatures for comparison of cellulose solubility and films' physical properties. It was found that NaOH/urea/ZnO gave the film the highest tensile strength and stretch. While sulfuric acid could dissolve high DP cellulose at low temperatures, alkaline solvents were unable to dissolve high DP cellulose.
Article
Polymer Science
Pierre Delliere, Nathanael Guigo
Summary: Hydrolytic furan ring opening is utilized to open biobased furanic molecules into levulinic-like platform molecules. The quantitative assessment of ring opening in furanic macromolecules, which has been considered as a side reaction, has not been conducted. This study highlights the concept of monitoring furan ring opening during polymerization using poly(furfuryl alcohol) (PFA). The investigation reveals that a significant amount of carbonyl species is formed during the polymerization process, introducing the concept of degree of open structure (DOS). Polymerizing furfuryl alcohol (FA) in a 50% aqueous solution doubles the fraction of opened structures, reaching up to 15% of opened furanic entities. The accessibility of carbonyls in PFA is influenced by steric hindrance.
Article
Chemistry, Applied
Jie Zhou, Zhiqiang Fang, Kaihuang Chen, Jinyi Cui, Dongjie Yang, Xueqing Qiu
Summary: This study improves the degree of polymerization (DP) of wood cellulose nanofibrils (CNFs) by preserving the native structure of wood fibers, resulting in high DP CNFs. These CNFs have potential applications in the fabrication of strong and tough films and macrofibers.
CARBOHYDRATE POLYMERS
(2022)
Article
Polymer Science
Jasna Malesic, Ida Krasevec, Irena Kralj Cigic
Summary: By utilizing sodium chlorite/acetic acid pretreatment, this study successfully determined the average degree of polymerization of cellulose in groundwood papers, further confirming the applicability of viscometry in historical papers with high lignin content.
Article
Materials Science, Paper & Wood
Chuan Sun, Guanhui Li, Jingyu Wang, Zhiqiang Fang, Famei Qin, Kaihuang Chen, Jie Zhou, Xueqing Qiu
Summary: The research reveals the influence of the interaction between montmorillonites and cellulose nanofibrils on the properties of nanocomposite films. Monolayer montmorillonites form highly ordered nanostructures during self-assembly, leading to nanocomposite films with high tensile strength, light transmittance, and water vapor transmission rate. The introduction of cationic polyethylenimine further enhances the physical properties of the nanocomposite films, but excessive polyethylenimine content leads to a performance deterioration.
Article
Acoustics
K. A. Cherednichenko, A. R. Sayfutdinova, A. Kraynov, B. Anikushin, V. Ignatiev, M. I. Rubtsova, S. A. Konstantinova, D. G. Shchukin, V. A. Vinokurov
Summary: A new method for the synthesis of nanofibrillar cellulose/polystyrene composite is proposed, which involves ultrasonic treatment of styrene emulsion in cellulose-water solution. This method eliminates the need for additional heating and significantly reduces the synthesis time compared to previous methods. Comprehensive analysis indicates that the mechanical, physical, and biodegradable properties of the composite obtained by the ultrasonic method are comparable to those obtained by the conventional thermal method.
ULTRASONICS SONOCHEMISTRY
(2022)
Article
Biotechnology & Applied Microbiology
Zhiqiang Ou, Qi Zhou, Xin Rao, Haifeng Yang, Chunqing Huo, Xueyu Du
Summary: The study focuses on isolating cellulose nanocrystals from waste rubber wood and using them as reinforcing fillers in PLA composite films. Adding reinforcing fillers at a level equal to or less than 5% by weight significantly improves the mechanical properties and crystallinity of the composite films.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2021)
Article
Materials Science, Paper & Wood
Di Lu, Xiao Yu, Shoujun Zhu, Yan Xu
Summary: Nanocellulose ultrasonication red-shifts film photonic bandgap, enabling the production of right-handed circularly polarized light in the second near-infrared window. Laminated films of cellulose nanocrystals offer a promising tool for discriminating human cancer tissues.
Article
Polymer Science
Tereza Jurczykova, Frantisek Kacik, Iveta Cabalova, Katerina Hajkova
Summary: This study evaluates the effect of using inorganic chemicals as the main components of waterborne wood preservative systems on the degradation of cellulose in wood. It shows that the polymeric properties of cellulose and the homogeneity of the degradation process reflect the degree of cellulose deterioration. The results suggest that borates, NaCl, and ZnSO4 center dot 7H(2)O have the lowest degradation rate, while sulphates containing NH4+, Cu2+, and Fe3+ cations cause significant depolymerization.
Article
Materials Science, Paper & Wood
Shichen Yuan, Maksim Tyufekchiev, Michael T. Timko, Klaus Schmidt-Rohr
Summary: The quantification of reducing chain ends in hydrolyzed cellulose samples using solid-state C-13 NMR was demonstrated. This method can serve as a primary standard to calibrate other methods for molar-mass determination in hydrolyzed cellulose.
Article
Multidisciplinary Sciences
Theodore Tyrikos-Ergas, Soeun Gim, Jhih-Yi Huang, Sandra Pinzon Martin, Daniel Varon Silva, Peter H. Seeberger, Martina Delbianco
Summary: Polysaccharide functionalization in bacterial biofilms alters their properties, and can be tuned using synthetic oligosaccharides. The study establishes a model system to explore the role of polysaccharides in biofilm-inspired assemblies.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Applied
Erwan Le Goue, Christian Gardrat, Melanie Romain, Manuela Rollini, Christine Moresoli, Veronique Coma
Summary: The study found that oleic acid stabilizes THC encapsulation but has a negative impact on THC release, however CH-CMC FFDs exhibit significant antifungal activity. Coating blackberries with CH-CMC-THC FFDs is not affected by oleic acid and has a better appearance.
FOOD HYDROCOLLOIDS
(2022)