4.6 Article

The beta-cyclodextrin decorated with palladium nanoparticles without pretreatment: An efficient heterogeneous catalyst for biaryls synthesis

Journal

APPLIED ORGANOMETALLIC CHEMISTRY
Volume 32, Issue 12, Pages -

Publisher

WILEY
DOI: 10.1002/aoc.4608

Keywords

cyclodexterin; hiyama coupling; Pd-nanoparticle; Suzuki coupling; Ullmann coupling

Funding

  1. Research Council of Shahid Beheshti University

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beta-Cyclodextrin decorated with palladium nanoparticles (PdNPs@beta-CD) without pretreatment led to a suitable catalyst for the biaryls synthesis in water. A simple and straightforward method was developed for the preparation of PdNPs@beta-CD as a green catalyst. The prepared catalyst was characterized by Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), atomic absorption spectroscopy (AAS), transmission electron microscopy (TEM), and energy-dispersive X-ray spectroscopy (EDS) measurements. It was found that PdNPs@beta-CD exhibits high performance in Ullmann, Suzuki and Hiyama coupling reactions.

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