Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 361, Issue 2, Pages 283-288Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801240
Keywords
carbon dioxide fixation; iron; cycloaddition; homogeneous catalysis
Categories
Funding
- Ministero dell'Istruzione dell'Universita e della Ricerca (MIUR, Roma, Italy)
- Universita degli Studi di Salerno [FARB 2016-ORSA165551]
Ask authors/readers for more resources
A new [OSSO]-Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO2 to the epoxides, formed from the in situ reaction of the related [OSSO]-Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO2 at 1 bar pressure with good activity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available