Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 6, Pages 6031-6041Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b19420
Keywords
ordered porous materials; porous poly(ionic liquid)s; ionic polymer crystalline; covalent organic frameworks; solvothermal synthesis; carbon dioxide capture; carbon dioxide fixation; cycloaddition reaction
Funding
- National Natural Science Foundation of China [U1662107, 21476109, 21303084, 21136005]
- Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Porous poly(ionic liquid)s (PPILs) combine the features of porous materials, polymers, and ionic liquids (ILs) or their derivatives, but they are normally of amorphous structure with disordered pores. Here, we report the facile synthesis of ordered porous poly(ionic liquid) crystallines (OPICs, specialized as a kind of PPIL analogues) with diverse and adjustable framework IL moieties through the Schiff base condensation of IL-derived ionic salts and neutral monomers. Ternary monomer mixtures are employed to artistically control the chemical composition and pore configurations. Compact atomic packing was achieved to give spacing confined ionic surface with strong CO2 affinity. Through monomer control, OPICs exhibit high CO2 uptakes with excellent CO2/N-2(CH4) selectivities and efficiently implement CO2 fixation through catalyzing epoxides cycloaddition under down to ambient conditions.
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