4.2 Article

Intrinsic and extrinsic contributions to magnetodielectric effect in double perovskite La2CoMnO6 nanoparticles

Journal

APPLIED NANOSCIENCE
Volume 3, Issue 1, Pages 25-28

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13204-012-0069-9

Keywords

Magnetodielectric effect; La2CoMnO6 nanoparticles; Spin-lattice coupling; Maxwell-Wagner model

Funding

  1. DST [SR/FTP/PS-36/2007]
  2. IIT Kharagpur
  3. DST, New Delhi
  4. CSIR-UGC, Delhi

Ask authors/readers for more resources

We have studied the magnetic and magnetodielectric (MD) properties of La2CoMnO6 nanoparticles of size similar to 28 nm prepared by sol-gel method. Dielectric behavior showed two relaxations coinciding with the magnetic transitions at 218 and 150 K, respectively. At those relaxation maxima, a large MD effect of 11 and 8% (at 100 kHz) with 5T was observed and the magnitude of MD effect is dependent on frequency. Delta epsilon(MD) proportional to M-2 relation in the paramagnetic to ferromagnetic regime suggests the spin lattice coupling; however, within the ferromagnetic region (200-100 K), we have found Delta epsilon(MD) proportional to M-4 relation which may be due to the complicated spin-pair correlation interactions among next nearest neighbors. Complex impedance analysis showed large frequency dispersion of dielectric permittivity, and strong influence of both bulk and grain boundary impedances with magnetic field clearly suggests that both intrinsic spin-lattice coupling and extrinsic Maxwell-Wagner model combined with magnetoresistance effect contribute to the observed MD property.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.2
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Physics, Condensed Matter

Magnetic glassy state at low spin state of Co3+ in EuBaCo2O5+δ (δ = 0.47) cobaltite

Archana Kumari, C. Dhanasekhar, Praveen Chaddah, D. Chandrasekhar Kakarla, H. D. Yang, Z. H. Yang, B. H. Chen, Y. C. Chung, A. K. Das

JOURNAL OF PHYSICS-CONDENSED MATTER (2020)

Article Materials Science, Multidisciplinary

Magnetic field-induced metamagnetic, magnetocaloric and pyrocurrent behaviors of Eu2CoMnO6

J. Krishnamurthy, A. Venimadhav

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2020)

Article Materials Science, Multidisciplinary

Room-temperature magnetization reversal and magnetocaloric switching in Fe substituted GdMnO3

Arnab Pal, Manu Mohan, Adyam Venimadhav, Pattukkannu Murugavel

PHYSICAL REVIEW MATERIALS (2020)

Article Chemistry, Physical

High performance electrospun nanofiber coated polypropylene membrane as a separator for sodium ion batteries

S. Janakiraman, Mohammed Khalifa, Rasmita Biswal, Sudipto Ghosh, S. Anandhan, A. Venimadhav

JOURNAL OF POWER SOURCES (2020)

Article Engineering, Electrical & Electronic

A high thermally stable polyacrylonitrile (PAN)-based gel polymer electrolyte for rechargeable Mg-ion battery

Rupali Singh, S. Janakiraman, Mohammed Khalifa, S. Anandhan, Sudipto Ghosh, A. Venimadhav, K. Biswas

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2020)

Article Chemistry, Physical

Structural and electrochemical kinetics of Na-Fe-Mn-O thin-film cathode: a synergistic effect of deposition conditions

Debasis Nayak, Sudipto Ghosh, A. Venimadhav

Summary: The study investigates the deposition of NFMO thin films on various substrates using pulsed-laser-deposition technique and explores the influence of deposition temperature on the morphology, electronic state, and electrochemical properties of the films. NFMO thin films deposited on stainless steel substrates exhibit high energy storage performance under different deposition conditions.

IONICS (2021)

Article Physics, Applied

Spontaneous magnetization reversal and positive exchange bias effect in CoFeSiB/FeCrO3 heterostructures

Rajesh R. Kumar, J. Krishnamurthy, J. Arout Chelvane, A. Venimadhav

Summary: The study demonstrates the characteristics of exchange bias phenomenon through preparing heterostructures and focusing on the interface spin structure, especially the spontaneous phenomena at low temperatures.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2021)

Article Physics, Condensed Matter

Understanding the correlation between orbital degree of freedom, lattice-striction and magneto-dielectric coupling in ferrimagnetic Mn1.5Cr1.5O4

G. D. Dwivedi, S. M. Kumawat, Tsung-Wen Yen, C. W. Wang, D. Chandrasekhar Kakarla, Amish G. Joshi, H. D. Yang, Shin-Ming Huang, H. Chou

Summary: The study reveals the presence of a magneto-dielectric coupling in Mn1.5Cr1.5O4, which is attributed to changes in structural parameters caused by internal magnetism rather than a structural transition. Magneto-striction plays a key role as a link between magnetic and dielectric properties.

JOURNAL OF PHYSICS-CONDENSED MATTER (2021)

Article Physics, Condensed Matter

Electron transport characteristics of FeGa, Ni/n-Si junctions by impedance spectroscopy

Gourab Bhattacharya, N. Vijay Prakash Chaudhary, Tapasendra Adhikary, Shampa Aich, A. Venimadhav

Summary: This study investigated electron transport across Galfenol and Nickel-based Schottky contacts on n-Si substrates through DC current-voltage measurements and AC Impedance spectroscopy. Improper back contact can cause additional bias dependent Resistance-capacitance components, which were studied using proper equivalent circuit models. The results showed distinct behavior in capacitance and barrier height, with negative capacitance observed in certain conditions. The use of an equivalent circuit with inductor-resistor relaxation provided a better fit for the experimental results.

SUPERLATTICES AND MICROSTRUCTURES (2021)

Article Materials Science, Multidisciplinary

Spin-lattice-charge coupling in quasi-one-dimensional spin-chain NiTe2O5

Ajay Tiwari, D. Chandrasekhar Kakarla, G. Macam, C. H. Hsu, F. C. Chuang, H. C. Wu, T. W. Kuo, Arkadeb Pal, H. Chou, D. P. Gulo, H. L. Liu, Y. C. Chuang, Y. C. Lai, C. A. Lee, Mitch M. C. Chou, H. D. Yang

Summary: A high-quality NiTe2O5 single crystal was grown and investigated for its higher-order magnetoelectric coupling effect. The study revealed that magnetoelastic coupling plays a critical role in bridging the electrical and magnetic properties in this material, with p-d hybridization being a possible mechanism for the observed effect.

PHYSICAL REVIEW MATERIALS (2022)

Article Materials Science, Multidisciplinary

Interplay of lattice, spin, and dipolar properties in CoTeMoO6: Emergence of Griffiths-like

Arkadeb Pal, T. W. Kuo, Chia-Hsiu Hsu, D. Chandrasekhar Kakarla, Ajay Tiwari, M. C. Chou, Atanu Patra, P. Yanda, E. Blundo, A. Polimeni, A. Sundaresan, F. C. Chuang, H. D. Yang

Summary: This study investigates the physical properties of the noncentrosymmetric and quasi-two-dimensional canted antiferromagnetic material CoTeMoO6 (CTMO), revealing a spectrum of intriguing phenomena and the crucial role played by spin canting.

PHYSICAL REVIEW B (2022)

Article Chemistry, Physical

An amorphous polyvinylidene fluoride-co-hexafluoropropylene based gel polymer electrolyte for sodium-ion cells

S. Janakiraman, Ashutosh Agrawal, Rasmita Biswal, A. Venimadhav

Summary: In this study, an electrospun amorphous PVDF-co-HFP based separator was shown to be a superior gel electrolyte material suitable for sodium-ion batteries. The amorphous gel polymer electrolyte (AGPE) displayed high ionic conductivity and wide electrochemical stability, leading to excellent cycling performance in the sodium-ion cell system.

APPLIED SURFACE SCIENCE ADVANCES (2021)

Article Materials Science, Multidisciplinary

Single crystal growth and structural, magnetic, and magnetoelectric properties in spin-frustrated bow-tie lattice of α-Cu5O2(SeO3)2Cl2

D. Chandrasekhar Kakarla, Z. H. Yang, H. C. Wu, T. W. Kuo, Ajay Tiwari, W-H Li, C. H. Lee, Y-Y Wang, J-Y Lin, C. K. Chang, B. H. Chen, Chin-Wei Wang, C. A. Lee, Mitch M. C. Chou, H. D. Yang

Summary: Single crystals of alpha-Cu5O2(SeO3)(2)Cl-2 were prepared successfully and studied for their structural, magnetic, thermal, and dielectric properties. The presence of magnetodielectric effect and long-range antiferromagnetic transition were observed.

MATERIALS ADVANCES (2021)

Proceedings Paper Materials Science, Multidisciplinary

Investigation of current transport in Galfenol based Schottky diodes

Gourab Bhattacharya, N. Vijay Prakash Chaudhary, Suman Sekhar Takri, R. Rajesh Kumar, A. Venimadhav

MATERIALS TODAY-PROCEEDINGS (2020)

Article Materials Science, Multidisciplinary

Pressure and magnetic field effects on ferroelastic and antiferromagnetic orderings in honeycomb-lattice Mn2V2O7

H. C. Wu, D. J. Hsieh, T. W. Yen, P. J. Sun, D. Chandrasekhar Kakarla, J. L. Her, Y. H. Matsuda, C. K. Chang, Y. C. Lai, M. Gooch, L. Z. Deng, K. G. Webber, C. A. Lee, Mitch M. C. Chou, C. W. Chu, H. D. Yang

PHYSICAL REVIEW B (2020)

No Data Available