Journal
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS
Volume 229, Issue 6, Pages 427-434Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/zkri-2013-1720
Keywords
mayenite; neutron diffraction study; unusual anions
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Funding
- German Science Foundation (DFG) [PAK 596]
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The framework structure of O-mayenite (Ca12Al14O33) allows the substitution of extra framework oxygen anions by various anions. In this study we present two new anion substituted phases. Oxidation of CN-mayenite leads to the formation of NO2-mayenite and, in addition, there are some hints to a very unusual species present in N-mayenite: the hydrazide anion.
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