Cu-mediated C–H cyanation of arenes using N,N-dimethylformamide (DMF) as the “CN” source

Copper-Catalyzed RegioselectiveorthoCH Cyanation of Vinylarenes

(2014) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct C–H Bond Cyanation of Arenes with Isocyanide

(2014) Xiaohu Hong et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic cyanation of aryl iodides using DMF and ammonium bicarbonate as the combined source of cyanide: a dual role of copper catalysts

(2013) Amit B. Pawar et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile

(2013) Xuezhen Kou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthetic Uses of Ammonia in Transition-Metal Catalysis

(2013) Jinho Kim et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Mediated Direct C2-Cyanation of Indoles Using Acetonitrile as the Cyanide Source

(2013) Changduo Pan et al.   JOURNAL OF ORGANIC CHEMISTRY

Oxone-Mediated Oxidative Cleavage of β-Keto Esters and 1,3-Diketones to α-Keto Esters and 1,2-Diketones in Aqueous Medium

(2013) Anastasios Stergiou et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Cyanation of Aryl Halides with CuSCN

(2013) Guo-Ying Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Directed C–H Cyanation of Arenes with N-Cyano-N-phenyl-p-toluenesulfonamide

(2013) Tian-Jun Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Transformation of Organosilanes to Nitriles with DMF and Ammonium Iodide

(2013) Zhen Wang et al.   ORGANIC LETTERS

Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds

(2013) Manthena Chaitanya et al.   ORGANIC LETTERS

Copper-Mediated Direct Aryl C–H Cyanation with Azobisisobutyronitrile via a Free-Radical Pathway

(2013) Hao Xu et al.   ORGANIC LETTERS

Synthesis of Aromatic Nitriles Using Nonmetallic Cyano-Group Sources

(2012) Jinho Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N,N-Dimethylformamide: A Multipurpose Building Block

(2012) Shengtao Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate

(2012) Jisong Jin et al.   CHEMICAL COMMUNICATIONS

Brønsted Acid Enhanced Rhodium-Catalyzed Conjugate Addition of Aryl CH Bonds to α,β-Unsaturated Ketones under Mild Conditions

(2012) Lei Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Sequential Cyanation of Aryl C–B and Arene C–H Bonds Using Ammonium Iodide and DMF

(2012) Jinho Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Selective Cyanation of Indoles and 2-Phenylpyridines with Ammonium Iodide and DMF

(2012) Jinho Kim et al.   ORGANIC LETTERS

Ethyl Cyanoacetate: A New Cyanating Agent for the Palladium-Catalyzed Cyanation of Aryl Halides

(2012) Shuyan Zheng et al.   ORGANIC LETTERS

Palladium-Assisted Regioselective C–H Cyanation of Heteroarenes Using Isonitrile as Cyanide Source

(2012) Shuguang Xu et al.   ORGANIC LETTERS

The palladium-catalyzed cyanation of indole C–H bonds with the combination of NH4HCO3 and DMSO as a safe cyanide source

(2011) Xinyi Ren et al.   CHEMICAL COMMUNICATIONS

Iron-Catalyzed CH Bond Activation for the ortho-Arylation of Aryl Pyridines and Imines with Grignard Reagents

(2011) Naohiko Yoshikai et al.   Chemistry-An Asian Journal

Iodine-Catalyzed Synthesis of 1,2-Diaryldiketones by Oxidative Cleavage of 1,3-Diaryldiketones with DMSO

(2011) Yu Yuan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C–H bond functionalisation with [RuH(codyl)2]BF4 catalyst precursor

(2011) Wenbo Li et al.   GREEN CHEMISTRY

Iron-Promoted C–C Bond Cleavage of 1,3-Diketones: A Route to 1,2-Diketones under Mild Reaction Conditions

(2011) Lehao Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Transformation ofN,N-Dimethylformamide to −CN: Pd-Catalyzed Cyanation of Heteroarenes via C–H Functionalization

(2011) Shengtao Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air

(2011) Quan Chen et al.   ORGANIC LETTERS

Copper-Mediated Chelation-AssistedOrthoNitration of (Hetero)arenes

(2011) Lin Zhang et al.   ORGANIC LETTERS

New Reactivity of Oxaziridine: Pd(II)-Catalyzed Aromatic C–H Ethoxycarbonylation via C–C Bond Cleavage

(2011) Xingao Peng et al.   ORGANIC LETTERS

Photochemically Induced Radical Transformation of C(sp3)–H Bonds to C(sp3)–CN Bonds

(2011) Shin Kamijo et al.   ORGANIC LETTERS

Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source

(2011) Guoying Zhang et al.   ORGANIC LETTERS

Catalytic Dicyanative 5-exo- and 6-endo-Cyclization Triggered by Cyanopalladation of Alkynes

(2010) Shigeru Arai et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Titanium Catalyst for Enantioselective Cyanation of Aldehydes: Cooperative Catalysis

(2010) Zhipeng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mild and Efficient Palladium-Catalyzed Cyanation of Aryl Mesylates in Water or tBuOH/Water

(2010) Pui Yee Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent-Free Chemoselective Cyanation of α,α-Dibromoacetophenones Using Potassium Hexacyanoferrate(II) as an Eco-Friendly Cyanide Source

(2010) Zhouxing Zhao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles

(2010) Chong Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyanation of Arenes via Iridium-Catalyzed Borylation

(2010) Carl W. Liskey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Combined Source of “CN” fromN,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds

(2010) Jinho Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselectivity-Switchable Hydroarylation of Styrenes

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Cyanation of Heterocycle Carbon−Hydrogen Bonds

(2010) Hien-Quang Do et al.   ORGANIC LETTERS

Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C−H and N−H Bond Cleavages with Air as the Oxidant

(2010) Keisuke Morimoto et al.   ORGANIC LETTERS

An Efficient Transformation from Benzyl or Allyl Halides to Aryl and Alkenyl Nitriles

(2010) Wang Zhou et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Cyanation of Indoles with K4[Fe(CN)6]

(2010) Guobing Yan et al.   ORGANIC LETTERS

Pd(OAc)2-catalyzed C–H activation of indoles: a facile synthesis of 3-cyanoindoles

(2010) B.V. Subba Reddy et al.   TETRAHEDRON LETTERS

Sulfate additives generate robust and highly active palladium catalysts for the cyanation of aryl chlorides

(2010) Michael Shevlin   TETRAHEDRON LETTERS

N,N-Dimethylformamide as a Reaction Medium for Metal Nanoparticle Synthesis

(2009) Isabel Pastoriza-Santos et al.   ADVANCED FUNCTIONAL MATERIALS

Catalytic 1,2-Dicyanation of Alkynes by Palladium(II) under Aerobic Conditions

(2009) Shigeru Arai et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Oxidative Synthesis of Nitriles Directly from Primary Alcohols and Ammonia

(2009) Takamichi Oishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron catalyzed oxidative cyanation of tertiary amines

(2009) Wei Han et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Sequential Cyanation/N-Addition/N-Arylation in One-Pot: Efficient Synthesis of Luotonin A and Its Derivatives

(2009) Yi Ju et al.   ORGANIC LETTERS

Palladium-Catalyzed Acylation of sp2C−H bond: Direct Access to Ketones from Aldehydes

(2009) Xiaofei Jia et al.   ORGANIC LETTERS

Chelation-Assisted Palladium-Catalyzed Direct Cyanation of 2-Arylpyridine C−H Bonds

(2009) Xiaofei Jia et al.   ORGANIC LETTERS

N,N-Dimethylformamide: much more than a solvent

(2009) Jacques Muzart   TETRAHEDRON

Ligand-free CuI-catalyzed cyanation of aryl halides using K4[Fe(CN)6] as cyanide source and water as solvent

(2009) Catherine DeBlase et al.   TETRAHEDRON

Microwave-enhanced and ligand-free copper-catalyzed cyanation of aryl halides with K4[Fe(CN)6] in water

(2009) Yunlai Ren et al.   TETRAHEDRON LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes

(2008) Guojun Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3C−H Bond Activation and Carbon−Carbon Bond Formation

(2008) Shun-Ichi Murahashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C−H Bond with CO and Alcohols

(2008) Zheng-Hui Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights Into Palladium-Catalyzed Cyanation of Bromobenzene: Additive Effects on the Rate-Limiting Step

(2008) Frederic G. Buono et al.   ORGANIC LETTERS

Facile Preparation of α-Aryl Nitriles by Direct Cyanation of Alcohols with TMSCN Under the Catalysis of InX3

(2008) Gang Chen et al.   ORGANIC LETTERS

Halovinyl aldehydes: useful tools in organic synthesis

(2008) Sulagna Brahma et al.   TETRAHEDRON

Palladium-catalyzed cyanation of aryl halides using K4[Fe(CN)6] as cyanide source, water as solvent, and microwave heating

(2008) Sivan Velmathi et al.   TETRAHEDRON LETTERS

Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation

(2007) Thomas Vogler et al.   ORGANIC LETTERS