Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent

AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to α-CF3Alkenes and β-CF3Ketones

(2014) Bing Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deoxygenativegem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine

(2014) Fei Wang et al.   Beilstein Journal of Organic Chemistry

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

(2014) Chuanfa Ni et al.   CHEMICAL REVIEWS

gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction

(2014) Bing Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Stereoselective Nucleophilic Addition of Difluoromethyl-2-pyridyl Sulfone to Sugar Lactones and Efficient Synthesis of Fluorinated 2-Ketoses

(2014) Xiao Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone

(2014) Wenjun Miao et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis of N-(α-Fluorovinyl)azoles by the Reaction of Difluoroalkenes with Azoles

(2014) Yang Xiong et al.   JOURNAL OF ORGANIC CHEMISTRY

Domino Synthesis of Fluorine-Substituted Polycyclic Aromatic Hydrocarbons: 1,1-Difluoroallenes as Synthetic Platforms

(2013) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Difluoro(sulfinato)methylation of N-Sulfinyl Imines Facilitated by 2-Pyridyl Sulfone: Stereoselective Synthesis of Difluorinated β-Amino Sulfonic Acids and Peptidosulfonamides

(2013) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Fluorinated Heteroarylether Bioisosteres

(2013) Qianghui Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine

(2013) Jian Zheng et al.   CHEMICAL COMMUNICATIONS

The use of methyl 2,2-difluoro-2-(fluorosulfonyl)acetate as the difluorocarbene source to generate an in situ source of difluoromethylene triphenylphosphonium ylide

(2013) Charles S. Thomoson et al.   JOURNAL OF FLUORINE CHEMISTRY

Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base

(2013) Mingyou Hu et al.   JOURNAL OF FLUORINE CHEMISTRY

Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C–F Bond Cleavage

(2013) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient synthesis of silylated 2,2-difluorostyrene derivatives through Suzuki–Miyaura cross-coupling of 2,2-difluoro-1-iodo-1-silylethenes

(2013) Marc-Olivier Turcotte-Savard et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes

(2013) Bing Gao et al.   ORGANIC LETTERS

Palladium-Catalyzed Base-Free Suzuki-Miyaura Coupling Reactions of Fluorinated Alkenes and Arenes via a Palladium Fluoride Key Intermediate

(2012) Masato Ohashi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

From Olefination to Alkylation: In-Situ Halogenation of Julia–Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds

(2012) Yanchuan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation

(2011) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A simple, rapid procedure for nucleophilic radiosynthesis of aliphatic [18F]trifluoromethyl groups

(2011) Patrick J. Riss et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Cyclization of Difluoro-Substituted 1,6-Enynes with Organozinc Reagents through the Stereoselective Activation of CF Bonds: Synthesis of Bicyclo[3.2.0]heptene Derivatives

(2010) Manabu Takachi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of 2,2-Diaryl-1,1-difluoroethenes via Consecutive Cross-Coupling Reactions of 2,2-Difluoro-1-tributylstannylethenylp-Toluenesulfonate

(2010) Seung Yeon Han et al.   ORGANIC LETTERS

Difluoromethyl 2-Pyridyl Sulfone: A Newgem-Difluoroolefination Reagent for Aldehydes and Ketones

(2010) Yanchuan Zhao et al.   ORGANIC LETTERS

Synthesis of Fluoroolefins via Julia-Kocienski Olefination

(2010) Barbara Zajc et al.   SYNTHESIS-STUTTGART

1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia–Kocienski olefination

(2010) Lingui Zhu et al.   TETRAHEDRON

Chemoselectivity: The Mother of Invention in Total Synthesis

(2009) Ryan A. Shenvi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

(2009) Nicholas A. Afagh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

Efficient Helicene Synthesis: Friedel–Crafts-type Cyclization of 1,1-Difluoro-1-alkenes

(2008) Junji Ichikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION