Asymmetric aza-Henry reaction to provide oxindoles with quaternary carbon stereocenter catalyzed by a metal-templated chiral Brønsted base

Recent advances in asymmetric organocatalysis mediated by bifunctional amine–thioureas bearing multiple hydrogen-bonding donors

(2015) Xin Fang et al.   CHEMICAL COMMUNICATIONS

Merger of Visible Light Induced Oxidation and Enantioselective Alkylation with a Chiral Iridium Catalyst

(2015) Chuanyong Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Bifunctional Guanidine-Catalyzed Enantioselective Aza-Henry Reaction of Isatin-Derived Ketimines

(2015) Bing Fang et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent advances in the use of chiral metal complexes with achiral ligands for application in asymmetric catalysis

(2015) Zhong-Yan Cao et al.   Catalysis Science & Technology

Enantioselective Sulfa-Michael Addition to α,β-Unsaturated γ-Oxoesters Catalyzed by a Metal-Templated Chiral Brønsted Base

(2015) Xiaobing Ding et al.   Asian Journal of Organic Chemistry

Chiral Octahedral Complexes of Cobalt(III) as “Organic Catalysts in Disguise” for the Asymmetric Addition of a Glycine Schiff Base Ester to Activated Olefins

(2014) Victor I. Maleev et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Catalysis Mediated by the Ligand Sphere of Octahedral Chiral-at-Metal Complexes

(2014) Lei Gong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric oxa-Michael-aza-Henry Cascade Reaction of 2-Hydroxyaryl-Substituted α-Amido Sulfones and Nitroolefins Mediated by Chiral Squaramides

(2014) Bo Zheng et al.   ChemCatChem

Metal-templated enantioselective enamine/H-bonding dual activation catalysis

(2014) Haohua Huo et al.   CHEMICAL COMMUNICATIONS

Highly enantioselective aza-Henry reaction with isatin N-Boc ketimines

(2014) Melireth Holmquist et al.   CHEMICAL COMMUNICATIONS

Asymmetric Catalysis with Substitutionally Labile yet Stereochemically Stable Chiral-at-Metal Iridium(III) Complex

(2014) Haohua Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric photoredox transition-metal catalysis activated by visible light

(2014) Haohua Huo et al.   NATURE

Bis(imidazolidine)pyridine-NiCl2 Catalyst for Nitro-Mannich Reaction of Isatin-Derived N-Boc Ketimines: Asymmetric Synthesis of Chiral 3-Substituted 3-Amino-2-oxindoles

(2014) Takayoshi Arai et al.   ORGANIC LETTERS

An Organocatalytic Addition of Nitromethane to Activated Ketimines

(2014) Yu-Hui Wang et al.   Asian Journal of Organic Chemistry

Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter

(2013) Liang-An Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isatin as a Strategic Motif for Asymmetric Catalysis

(2013) Somayeh Mohammadi et al.   ChemCatChem

Nitro-Mannich Reaction

(2013) Adam Noble et al.   CHEMICAL REVIEWS

Bifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich Reaction

(2013) Marta G. Núñez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis with an Inert Chiral-at-Metal Iridium Complex

(2013) Liang-An Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional primary amine-thioureas in asymmetric organocatalysis

(2013) Olga V. Serdyuk et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions

(2013) Yuri N. Belokon et al.   ACS Catalysis

Modular Bifunctional Chiral Thioureas as Versatile Organocatalysts for Highly Enantioselective Aza-Henry Reaction and Michael Addition

(2012) Hua Li et al.   ADVANCED SYNTHESIS & CATALYSIS

The First Catalytic, Enantioselective Aza-Henry Reaction of an Unactivated Cyclic Imine

(2012) Nilupa R. Amarasinghe et al.   ADVANCED SYNTHESIS & CATALYSIS

Transfer of chirality from ligands to metal centers: recent examples

(2012) Jeanne Crassous   CHEMICAL COMMUNICATIONS

Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

(2012) Alejandro Parra et al.   CHEMICAL COMMUNICATIONS

Chiral-at-metal complexes and their catalytic applications in organic synthesis

(2012) Eike B. Bauer   CHEMICAL SOCIETY REVIEWS

Stereogenic metal centres – from Werner to supramolecular chemistry

(2012) Edwin C. Constable   CHEMICAL SOCIETY REVIEWS

Nitroolefins as a Nucleophilic Component for Highly Stereoselective Aza Henry Reaction under the Catalysis of Chiral Ammonium Betaines

(2012) Daisuke Uraguchi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Strategies for the enantioselective synthesis of spirooxindoles

(2012) Nicolas R. Ball-Jones et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic asymmetric synthesis of 3-hydroxyoxindole: a potentially bioactive molecule

(2012) Akshay Kumar et al.   RSC Advances

Asymmetric Hydrocyanation of α,β-Unsaturated Ketones into β-Cyano Ketones with the [Ru(phgly)2(binap)]/C6H5OLi Catalyst System

(2011) Nobuhito Kurono et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bifunctional Cinchona Alkaloid Thiourea Catalyzed Highly Efficient, Enantioselective Aza-Henry Reaction of Cyclic Trifluoromethyl Ketimines: Synthesis of Anti-HIV Drug DPC 083

(2011) Hexin Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Octahedral Coordination Complexes

(2011) Eric Meggers   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Highly Enantioselective Synthesis of Polysubstituted TetrahydroquinolinesviaOrganocatalytic Michael/Aza-Henry Tandem Reactions

(2011) Zhen-Xin Jia et al.   ORGANIC LETTERS

Catalytic, enantioselective synthesis of stilbene cis-diamines: A concise preparation of (−)-Nutlin-3, a potent p53/MDM2 inhibitor

(2011) Tyler A. Davis et al.   Chemical Science

Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C-3 Position

(2010) Feng Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Bifunctional Asymmetric Catalysis: Amplification of Brønsted Basicity Can Orthogonally Increase the Reactivity of a Chiral Brønsted Acid

(2010) Tyler A. Davis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective synthesis and cellular evaluation of spirooxindoles inspired by natural products

(2010) Andrey P. Antonchick et al.   Nature Chemistry

Spiroindolones, a Potent Compound Class for the Treatment of Malaria

(2010) M. Rottmann et al.   SCIENCE

Doubly Stereocontrolled Asymmetric Aza-Henry Reaction within situGeneration ofN-Boc-Imines Catalyzed by Novel Rosin-Derived Amine Thiourea Catalysts

(2009) Xianxing Jiang et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Aza-Henry Reaction with Acyclic Guanidine-Thiourea Bifunctional Organocatalyst

(2009) Keisuke Takada et al.   ADVANCED SYNTHESIS & CATALYSIS

Amide-based bifunctional organocatalysts in asymmetric reactions

(2009) Xiaohua Liu et al.   CHEMICAL COMMUNICATIONS

Chiral transfer in coordination complexes: towards molecular materials

(2009) Jeanne Crassous   CHEMICAL SOCIETY REVIEWS

Catalytic Enantioselective Aza-Henry Reactions

(2009) Eugenia Marqués-López et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bifunctional Asymmetric Catalysis: Cooperative Lewis Acid/Base Systems

(2008) Daniel H. Paull et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Novel Bis-Thiourea Organocatalyst for the Asymmetric Aza-Henry Reaction

(2008) Constantinos Rampalakos et al.   ADVANCED SYNTHESIS & CATALYSIS

[Ru(phgly)2(binap)]/Li2CO3: A Highly Active, Robust, and Enantioselective Catalyst for the Cyanosilylation of Aldehydes

(2008) Nobuhito Kurono et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of chiral bifunctional secondary amine catalysts for asymmetric enamine catalysis

(2008) Taichi Kano et al.   CHEMICAL COMMUNICATIONS

Discovery of Bifunctional Thiourea/Secondary-Amine Organocatalysts for the Highly Stereoselective Nitro-Mannich Reaction of α-Substituted Nitroacetates

(2008) Bo Han et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phase Transfer of Enantiopure Werner Cations into Organic Solvents: An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis

(2008) Carola Ganzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen-Bond-Mediated Asymmetric Catalysis

(2008) Xinhong Yu et al.   Chemistry-An Asian Journal

Enantioselective Organocatalytic Direct Michael Addition of Nitroalkanes to Nitroalkenes Promoted by a Unique Bifunctional DMAP-Thiourea

(2008) Constantinos Rabalakos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Bifunctional Chiral Thiourea Catalyzed Highly Enantioselective aza-Henry Reaction†

(2008) Chungui Wang et al.   ORGANIC LETTERS

Highly Enantioselective Aza-Henry Reaction of Ketoimines Catalyzed by ChiralN,N′-Dioxide−Copper(I) Complexes

(2008) Cheng Tan et al.   ORGANIC LETTERS

Potassium and silver chiral cobaltate(III) complexes as precatalysts for asymmetric C–C bond formation

(2008) Yuri N. Belokon et al.   TETRAHEDRON-ASYMMETRY