Article
Environmental Sciences
Edgardo Cruces, Ana C. Barrios, Yaritza P. Cahue, Brielle Januszewski, Leanne M. Gilbertson, Francois Perreault
Summary: The study compared the toxicity of oxidized multi-walled CNTs and GO in the cyanobacterium Microcystis aeruginosa. The results showed that both CNMs induced indirect toxicity through physical mechanisms associated with light shading and cell aggregation, without causing oxidative stress or membrane damage. This indirect toxicity explained why the intrinsic differences in shape, size, and surface properties between CNTs and GO did not result in differences in how they induce toxicity to cyanobacteria.
Article
Biochemistry & Molecular Biology
Antonio Cid-Samamed, Miguel Angel Correa-Duarte, Andrea Marino-Lopez, Mario S. Diniz
Summary: Carbon-based nanomaterials have become widely used in industries due to their unique properties, attracting increasing attention. However, their toxicity and environmental effects, especially on aquatic biota, require careful study. This research investigated the toxicity of oxidized multi-walled carbon nanotubes (Ox-MWCNTs) on freshwater bivalves and evaluated their impacts on antioxidant defenses. The results showed a concentration-dependent response of antioxidant enzymes in the bivalves exposed to different concentrations of Ox-MWCNTs, suggesting potential risks to aquatic ecosystems and human health if contaminated animals are ingested.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Environmental Sciences
Jinlu Hu, Ning Zhang, Balamurugan Srinivasan, Jiancheng Yang, Kaixin Tang, Lifei Zhang, Xueli Liu, Xin Zhang
Summary: Polybrominated diphenyl ether (PBDE) contamination is common and harmful in aquatic environments. This study investigates the response mechanisms of Chlorella pyrenoidosa to PBDE exposure, finding that photosynthetic damage and inhibition were caused by the binding of BDE47 to PSII and PSI complexes. However, C. pyrenoidosa showed a positive resistance and metabolic ability to PBDEs, indicating its potential as a bioremediator for wastewater-borne PBDEs.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2023)
Article
Engineering, Environmental
Xin Guo, Zhijia Sun, Hao Ge, Qin Zhao, Tingting Shang, Yang Tian, Xi-Ming Song
Summary: In this study, a series of MnOx/MWCNTs nanocomposites with different compositions and morphologies were successfully synthesized by regulating the amount of oxygen-containing functional groups on the surface of multi-walled carbon nanotubes. The nanocomposites with the highest number of Mn-O-C bonds showed the best electrochemical properties, with high capacity, outstanding rate capability, and durable long-term cyclability. The research revealed the significant impact of the amount and type of oxygen-containing functional groups in MWCNTs on the formation of Mn-O-C bonds and the composition and morphology of the nanocomposites.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Xin Guo, Hao Ge, Zhijia Sun, Qin Zhao, Yang Tian, Daliang Liu, Qiong Wu, Xi-Ming Song
Summary: In this study, an advanced nanocomposite with abundant metal-oxygen-carbon bonds was fabricated for the first time, which can enhance the intrinsic kinetics and structural stability, and promote the electrode activity. Electrochemical tests showed that the newly prepared electrode exhibited superior long-term durability and ultrafast charging/discharging capability. This work provides a scalable approach for constructing high-performance electrode materials through interfacial regulation.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Environmental Sciences
Zsuzsanna Kolbert, Arpad Molnar, Kamilla Kovacs, Sara Liptak-Lukacsik, Peter Benko, Reka Szollosi, Katalin Gemes, Laszlo Erdei, Andrea Ronavari, Zoltan Konya
Summary: This study compared the effects of different doses of multi-walled carbon nanotubes (MWCNTs) on Brassica napus and Solanum lycopersicum seedlings. It was found that higher concentrations of MWCNTs negatively affected root viability and cell proliferation, leading to oxidative stress and increased toxicity. The toxicity was more severe in Solanum lycopersicum compared to Brassica napus.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2023)
Article
Chemistry, Physical
Runzi Ding, Xiuwen He, Yi Hu, Jie Yan, Jiqing Lu, Sheldon Q. Shi, Guangping Han, Wanli Cheng
Summary: The objective of this study is to improve the interfacial bonding between oxidized bamboo fiber and epoxy resin by grafting amino-functionalized multi-walled carbon nanotubes. Results showed that the interfacial bonding between the fiber and resin was improved by 31.5% after oxidation treatment, and further improved by 106.4% after grafting 0.5 wt% amino-functionalized multi-walled carbon nanotubes.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Yasen Li, Yudong Shang, Jiangping He, Mingyue Li, Man Yang
Summary: The incorporation of oxidized multi-wall carbon nanotubes (OCNT) into waterborne polyurethane (WPU) matrix through in-situ polymerization enhances the mechanical properties and thermal stability of the composite material. The OCNT not only improves the surface activity and dispersibility, but also broadens the application range due to its superior properties.
DIAMOND AND RELATED MATERIALS
(2022)
Article
Multidisciplinary Sciences
Dingyi Li, Hong Dong, Xupeng Cao, Wangyin Wang, Can Li
Summary: This study reports the self-assembly of metal-organic frameworks (MOFs) on the surface of the green alga Chlorella pyrenoidosa, which greatly enhances photosynthetic carbon fixation. The chemical CO2 concentrating approach improves the apparent photo conversion efficiency to about 1.9 folds, reaching up to 9.8% in ambient air. The efficient carbon fixation lies in the conversion of captured CO2 to transportable HCO3- species.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
You Li, Lifei Ji, Xian Zhou, Tiantian Li, Xijie Chen, Xin Zhang, Fengchun Yang
Summary: Developing a facile hydrothermal process to prepare nanoflowers by compounding Co-Mo-S and oxidized multi-walled carbon nanotubes for efficient oxygen evolution reaction (OER) catalysts. The catalyst exhibits highly efficient electrocatalytic performances with low overpotential and Tafel slope in alkaline media, maintaining good stability even after extended testing. This work provides a new direction for boosting electrocatalytic activity through coupling bimetallic sulfides and constructing with conductive substrate.
Article
Chemistry, Multidisciplinary
Xiaoman Huang, Junjie Lin, Jiarong Liang, Erfeng Kou, Wenxiao Cai, Yinjian Zheng, Haoran Zhang, Xuejie Zhang, Yingliang Liu, Wei Li, Bingfu Lei
Summary: Carbon dots doped with pyridinic nitrogen (Lev-CDs) were synthesized by the one-pot hydrothermal method, and the structure-function relationship between functional groups on Lev-CDs and photosynthesis of Chlorella pyrenoidosa was proposed. Pyridinic nitrogen plays a key role in the positive effect on photosynthesis caused by Lev-CDs. Lev-CDs act as electron donors and supply photo-induced electrons to the photosynthetic electron transport chain, enhancing the electron transfer rate, the activity of photosystem II, and the Calvin cycle.
Article
Environmental Sciences
Jingmiao Zhang, Ao Xia, Huize Chen, Abdul-Sattar Nizami, Yun Huang, Xianqing Zhu, Xun Zhu, Qiang Liao
Summary: A green hydrothermal process was used to produce biobased nanomaterials carbon dots (CDs) using microalgae Chlorella pyrenoidosa (CP) and its main model compounds. The reaction pathway for the hydrothermal process to produce microalgae-based CDs was proposed. Interactions among carbohydrates and proteins were found to be vital intermediate reactions in the generation of CDs. The CDs emitted blue fluorescence and displayed high sensitivity in detecting Fe3+ in wastewater.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Environmental Sciences
Zipeng Qiao, Peiyong Guo, Daomao Yang, Zhenqiao Pei, Mingyuan Wang, Jianfu Liu, Qizhi Wang
Summary: The biosynthetic silver nanoparticles (AgNPs) using fungi have high catalytic efficiency and environmentally friendly characteristic. This study investigated the catalytic reduction of 4-nitrophenol (4-NP) by WZ07-AgNPs biosynthesized by Letendraea sp. WZ07. The results showed that WZ07-AgNPs had significant catalytic activity with high degradation efficiency of 4-NP. The toxic effects of WZ07-AgNPs and commercial-AgNPs on Chlorella pyrenoidosa were compared, and it was found that WZ07-AgNPs were less toxic to the algae.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Yanmei Chen, Baokun Tang, Dandan Han, Tao Zhu
Summary: By dual driving of N-doping and DES modification, the adsorption and electrochemical properties of oxidized hydrogen-substituted graphyne were enhanced; composite with multi-walled carbon nanotubes can overcome the limitations of individual carbon nanomaterial applications; the modification of DESs helps to enhance the adsorption capacity of graphyne and composite with MWCNTs can improve the specific capacitance of the materials.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Energy & Fuels
Rafael Vicentini, Willian G. Nunes, Lenon H. da Costa, Leonardo M. Da Silva, Bruno Freitas, Aline M. Pascon, Otavio Vilas-Boas, Hudson Zanin
Summary: A novel multi-walled carbon nanotubes and activated carbon composite material was reported as an electrode for electrochemical capacitors, showing low equivalent series resistance and operational stability in aqueous electrolytes. The simple, fast, and low-cost approach resulted in devices with high voltage and specific capacitance, demonstrating good cyclability and potential for environmentally friendly electrolytes.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Multidisciplinary Sciences
Yanyi He, Kun Yang, Martin Wild, Kaicun Wang, Dan Tong, Changkun Shao, Tianjun Zhou
Summary: We reduced the uncertainties in projecting surface downward solar radiation by approximately 56% using emergent constraints. Our findings reveal significant brightening in North and Southeast China, regions with high energy demand. Surface downward solar radiation is crucial for renewable solar energy and climate change mitigation, however, future projections based on climate models are highly uncertain, hindering efficient deployment. By using emergent constraints, we obtained credible and narrowed projections for future solar radiation, emphasizing the need to consider spatial changes in order to optimize solar energy infrastructure placement.
NATIONAL SCIENCE REVIEW
(2023)
Article
Engineering, Environmental
Xu Li, Huijie Lu, Kun Yang, Lizhong Zhu
Summary: The use of nanoscale zero-valent iron (NZVI) can effectively degrade tetracyclines (TCs) and reduce the potential risks of antibiotic resistance genes (ARGs) by decreasing horizontal gene transfer. NZVI's biotic degradation contributes significantly to the removal of TCs and is attributed to reduced toxicity and increased microbial biomass and enzyme activities.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Engineering, Civil
Mijun Zou, Kun Yang, Hui Lu, Yanghang Ren, Jing Sun, Han Wang, Shen Tan, Long Zhao
Summary: A new evapotranspiration model (EEOET) was developed in this study based on eco-evolutionary optimality principles, which reduced the number of plant functional type-specific parameters and improved the robustness of the model. The EEOET model requires inputs of daily land surface temperature, vegetation-related data, soil information, and routine meteorological data, and provides daily estimates of evapotranspiration. Global evaluation across 74 FLUXNET sites showed that the model performed well for all plant functional types and was comparable to existing models.
JOURNAL OF HYDROLOGY
(2023)
Article
Meteorology & Atmospheric Sciences
Changhui Zhan, Yingying Chen, Kun Yang, Lazhu, Xu Zhou, Yaozhi Jiang, Xiaoyan Ling, Jiaxin Tian, Yan Wang, Xin Li, Hua Yang
Summary: This study evaluates the performance of four Global Precipitation Measurement (GPM)-Era precipitation products on the western Tibetan Plateau (WTP). The results show that the calibration of satellite products has a significant effect on their performance. The GSMaP-Gauge, calibrated with daily data, outperforms the IMERG-C, calibrated with monthly data, on both monthly and daily scales. However, the calibration does not improve the reproduction of precipitation amount on the WTP, and none of the four products can accurately capture the hourly precipitation frequency-intensity structure.
ATMOSPHERIC RESEARCH
(2023)
Article
Oncology
Jinsong Yang, Ai Huang, Kunyu Yang, Ke Jiang
Summary: This study aims to investigate whether the addition of immunotherapy to neoadjuvant chemoradiotherapy can improve the pathologic complete response rate in esophageal carcinoma. Patients will receive neoadjuvant chemoradiotherapy followed by surgery. The primary endpoint is the pathologic complete response rate after neoadjuvant chemoradiotherapy plus immunotherapy.
Article
Meteorology & Atmospheric Sciences
Yanyi He, Kun Yang, Yanghang Ren, Mijun Zou, Xu Yuan, Wenjun Tang
BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY
(2023)
Article
Engineering, Electrical & Electronic
Da Lu, Rui Duan, Kunde Yang
Summary: This paper presents a constrained CPD-based algorithm for DOA estimation using a highly structured uniform linear AVSA. The algorithm incorporates prior structured information to improve the accuracy of DOA estimation. Numerical simulations verify the effectiveness and superior performance of the algorithm.
CIRCUITS SYSTEMS AND SIGNAL PROCESSING
(2023)
Article
Geosciences, Multidisciplinary
Jiayue Zhou, Hui Lu, Kun Yang, Ruijie Jiang, Yuan Yang, Wei Wang, Xuejun Zhang
Summary: This study investigates future multibasin hydrological changes in China using CMIP6 models and high-resolution China Meteorological Forcing Dataset. The findings show that the VIC model accurately simulates runoff in major Chinese basins, and the model data accuracy improves after downscaling bias correction. Future projections under SSP2-4.5 and SSP5-8.5 scenarios indicate increases in multiyear average annual precipitation, annual evapotranspiration, and total annual runoff depth for the Chinese mainland and each basin.
SCIENCE CHINA-EARTH SCIENCES
(2023)
Article
Cell Biology
Guojie Xu, Lei Zhao, Qingling Hua, Lanqing Wang, Hongli Liu, Zhenyu Lin, Min Jin, Jing Wang, Pengfei Zhou, Kunyu Yang, Gang Wu, Dandan Yu, Dejun Zhang, Tao Zhang
Summary: In this study, it was found that CEMIP interacts with GRAF1, and the combination of high CEMIP and low GRAF1 predicts poor survival of patients. It was also revealed that CEMIP promotes CRC metastasis by negatively regulating the stability of GRAF1 and by bridging MIB1 and GRAF1. Furthermore, it was demonstrated that CEMIP activates the CDC42/MAPK pathway-regulated EMT, which is essential for CEMIP-mediated migration and invasion of CRC cells. It was concluded that CDC42 inhibitor could be a potential therapeutic strategy for CEMIP-mediated CRC metastasis.
CELL DEATH & DISEASE
(2023)
Article
Oncology
Qi Zhang, Jinglei Li, Zihan Chen, Ke Jiang, Kunyu Yang, Fang Huang, Ai Huang, Xiaodong Zhang, Jinxiang Zhang, Hui Wang
Summary: In this study, it was found that the deubiquitinase OTUD1 is downregulated in lung adenocarcinoma (LUAD) and inhibits the progression of LUAD by deubiquitinating and stabilizing FHL1. Furthermore, the drug VE-822 was identified as a candidate agonist for OTUD1 and showed inhibitory effects on the proliferation of LUAD both in vitro and in vivo.
Article
Chemistry, Multidisciplinary
Zhenjie Li, Zhongyuan Guo, Xinyue Wu, Xunheng Jiang, Hao Li, Jiang Xu, Kun Yang, Daohui Lin
Summary: This study finds that supported palladium ensembles consisting of a few zero-valent Pd atoms exhibit exceptional reactivity in formic acid dehydrogenation and 4-chlorophenol dechlorination reactions. The reactivity is significantly higher than that of supported Pd single-atom catalysts. The findings highlight the important role of the structure and valence state of Pd ensembles in catalytic reductive reactions.
Article
Environmental Sciences
Linbo Qian, Hangyu Li, Zifei Wei, Cong Liang, Xinzhu Dong, Daohui Lin, Mengfang Chen
Summary: The aim of this study is to determine whether sulfur- and biochar-modified zero-valent iron (ZVI-BC-S) can enhance the removal of cis-1,2-dichloroethene (cDCE) and vinyl chloride (VC) from groundwater. Results show that biochar and sulfur facilitate the milling of ZVI-BC-S into micro- and nanoscale particles and increase FeS formation. Treatment with ZVI-BC-S harnesses the benefits of biochar and sulfur to significantly enhance the cDCE and VC removal rates.
ENVIRONMENTAL POLLUTION
(2023)
Article
Engineering, Environmental
Yi Liu, Wenhua Dong, Xunheng Jiang, Jiang Xu, Kun Yang, Lizhong Zhu, Daohui Lin
Summary: In this study, it was found that erythrosine (ERY), an edible dye, can efficiently degrade intracellular antibiotic resistance genes (iARGs) by generating abundant O-1(2) under visible light. The degradation of 6 log iARGs was achieved within 40 minutes. The unique indirect oxidation of iARGs induced by O-1(2) resulted in a 3.2-fold faster degradation of intracellular ARGs compared to extracellular ARGs. Additionally, other photosensitizers with high O-1(2) yields, such as Rose Bengal and Phloxine B, also demonstrated efficient iARG degradation.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Shuyi Shen, Kun Yang, Daohui Lin
Summary: This study investigated the biomolecular responses of bacteria to Ti3C2Tx nanosheets by using FTIR analysis and other techniques. The results showed that the nanosheets had a significant impact on Gram-positive bacteria by causing oxidative damage and inactivation. Gram-negative bacteria, on the other hand, showed increased resistance to the nanosheets due to their bilayer membrane structure. Surface modification of the nanosheets affected their toxicity and affinity to bacterial phospholipids, leading to severe cell membrane lipid peroxidation and bacterial inactivation.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Du Chen, Xiaohong Hu, Chaohuang Chen, Daohui Lin, Jiang Xu
Summary: This article presents the design principles and characterization techniques of lattice-doped nFe(0) from the perspective of microenvironment chemistry. The effects of doping elements on the local coordination environment of nFe(0) crystals are discussed, which determine their structure-property-activity relationships. The trade-off between reactivity and selectivity can be altered by controlling the amounts, types, and speciation of doping elements. The challenges and future outlook of using lattice-doped nFe(0) materials in real applications are also discussed.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)