Article
Chemistry, Physical
Myeong-Geun Kim, Jinwoo Park, Youngjo Choi, Ho Chang Song, Seung-Hoon Kim, Kyeong-Mi Bang, Hyung Chul Ham, Nak-Kyoon Kim, Da Hye Won, Byoung Koun Min, Sung Jong Yoo, Woong Kim
Summary: Recent advances in electrocatalysts for CO2 reduction have shown promise in the large-scale production of low-carbon fuels. The production of multicarbon chemicals, such as C-4, has been a challenge due to low production rates and efficiency. This study demonstrates the use of CuxIr1-x alloy nanoparticles as efficient electrocatalysts for converting CO2 into t-BuOH with significantly improved production rates and efficiency. The findings propose a mechanism for C-4 formation based on electronic interactions and surface properties, opening possibilities for Ir-based alloys in CO2 reduction and the production of C-4 chemicals.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Libing Zhang, Jiaqi Feng, Limin Wu, Xiaodong Ma, Xinning Song, Shunhan Jia, Xingxing Tan, Xiangyuan Jin, Qinggong Zhu, Xinchen Kang, Jun Ma, Qingli Qian, Lirong Zheng, Xiaofu Sun, Buxing Han
Summary: Regulating the adsorption of oxygen-associated active species on copper by introducing an oxophilic metal can improve the selectivity of C2+ alcohols. Experimental results showed that the Al-doped Cu catalyst exhibited outstanding stability and high selectivity towards ethanol.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Junbo Chen, Haibo Yu, Davin Tan, Richmond Lee
Summary: The feasibility of various guanidine-based compounds as biomimetic hydride was assessed using Density Functional Theory (DFT). The results suggested that tricyclic pentanidine hydrides could be potential candidates for reducing CO2 to HCOO- and can be regenerated electrochemically, demonstrating a recyclable and sustainable method for metal-free electrochemical reduction of CO2.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Lei Gong, Baotong Chen, Ying Gao, Baoqiu Yu, Yinhai Wang, Bin Han, Chenxiang Lin, Yongzhong Bian, Dongdong Qi, Jianzhuang Jiang
Summary: We have developed a 2D COF based on tetraphenyl-p-phenylenediamine and metalloporphyrin for electrocatalytic CO2 reduction. The COF shows high reaction efficiency and current density.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Multidisciplinary
Christoph J. Bondue, Matthias Graf, Akansha Goyal, Marc T. M. Koper
Summary: The study focuses on the electrochemical reduction of CO2 at gold electrodes under mildly acidic conditions. Increasing the CO2 partial pressure enhances the rate of CO2 reduction and suppresses hydrogen evolution, leading to high Faradaic efficiencies close to 100%. By suppressing hydrogen evolution and using protons for water formation, the study derived a general design principle for acid CO2 electrolyzers to match the mass transfer of protons to the electrode surface.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Ludovic Zaza, Kevin Rossi, Raffaella Buonsanti
Summary: This Perspective discusses the current and future contributions of well-defined nanocatalysts to improving the selectivity of the electrochemical CO2 reduction reaction towards C2 products. The shape and size selectivity dependence of single metal copper nanocrystals is reviewed and linked to single-crystal studies. The importance of the composition and distribution of metals for selectivity is highlighted through representative studies on Cu-based bimetallic nanocrystals. Finally, a vision on design strategies for the next generation CO2RR nanocatalysts is proposed.
ACS ENERGY LETTERS
(2022)
Review
Chemistry, Multidisciplinary
Domenico Grammatico, Andrew J. Bagnall, Ludovico Riccardi, Marc Fontecave, Bao-Lian Su, Laurent Billon
Summary: This review discusses the state of the art of different catalyst-support systems for CO2RR and proposes necessary steps for future developments. The article emphasizes the need for standard benchmarking for comparison of these support systems and the development of advanced techniques to aid rational design principles.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Engineering, Chemical
Guo-Cui Mao, Xiao-Tian Kan, Ming-Xiu Xiao, Wen-Long Liu, Bao-Xia Dong, Yun-Lei Teng
Summary: It has been discovered that alkaline earth metals can catalyze the hydrogenation of CO2 captured by CaO to produce CH4 under room temperature conditions. The addition of different catalysts can increase the yield of CH4, with metal hydrides playing a key role in the methanation process. This work provides a novel method to convert metal oxide-captured CO2 to CH4 at room temperature.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Analytical
Silvia Mena, Esteve Ribas, Clara Richart, Iluminada Gallardo, Jordi Faraudo, Scott K. Shaw, Gonzalo Guirado
Summary: The paper focuses on the role of carbon dioxide in controlling the Earth's temperature and the environmental problems caused by its increased concentration in the atmosphere. It discusses the use of ionic liquids for efficient CO2 capture and conversion, utilizing electrochemical, spectroscopic, and molecular dynamics techniques to understand the reduction mechanism under various conditions. The research opens up possibilities for theoretical-experimental approaches to determine the CO2 reduction mechanism and the dependency of product formation on the electrode material and solvent used.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Jing Zhao, Peng Zhang, Tenghui Yuan, Dongfang Cheng, Shiyu Zhen, Hui Gao, Tuo Wang, Zhi-Jian Zhao, Jinlong Gong
Summary: This paper presents a controllable electrodeposition approach to alloying Cu with an oxophilic metal to steer the CO2 reduction reaction towards methane production. The optimized La5Cu95 electrocatalyst exhibits a high CH4 Faradaic efficiency of 64.5%, with a partial current density of 193.5 mA cm-2. The introduction of oxophilic La assists in lowering the energy barrier for *CO hydrogenation and promotes the formation of CH4.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Xianghua Yang, Shiqing Wu, Qian Zhang, Songbai Qiu, Yuan Wang, Junjun Tan, Liang Ma, Tiejun Wang, Yongde Xia
Summary: This study reports a simple liquid synthesis approach to synthesize highly uniformed PdAg alloys with tunable morphologies and electrocatalytic performance. By modulating the composition of the alloy, the efficiency and stability of the CO2 reduction reaction can be improved. This finding provides a new pathway for the rational design and synthesis of high-stability alloy catalysts for clean energy storage and conversion.
Article
Chemistry, Multidisciplinary
Carter S. Gerke, Yuting Xu, Yuwei Yang, Gregory D. Foley, Briana Zhang, Ethan Shi, Nicholas M. Bedford, Fanglin Che, V. Sara Thoi
Summary: This study reports the coupling reaction between CO2RR and NO3RR using molecular copper boron-imidazolate cages, resulting in high selectivity and activity for urea production. The mechanism involves tandem reactions at separate copper sites and condensation between *CO and NH2OH to produce urea.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Tenghui Yuan, Tuo Wang, Gong Zhang, Wanyu Deng, Dongfang Cheng, Hui Gao, Jing Zhao, Jia Yu, Peng Zhang, Jinlong Gong
Summary: This study presents a facile method to immobilize the morphology of Cu-based catalysts during CO2RR, which reveals the specific adsorption mechanism of halide ions and provides a theoretical basis for the selectivity of multi-carbon products for Cu-based catalysts.
Article
Chemistry, Physical
Yan Wang, Shuai Xia, Jianfang Zhang, Zhengyuan Li, Rui Cai, Cuiping Yu, Yong Zhang, Jingjie Wu, Yucheng Wu
Summary: Researchers have developed a Cu/ZnO stacked tandem gas-diffusion electrode for selective urea synthesis from electrocatalytic CO2 and nitrate reduction reactions. The electrode promotes the conversion of NO3(-) to *NH2 by providing a high CO concentration, resulting in accelerated C-N coupling for urea synthesis. Experimental results demonstrate the high efficiency of urea synthesis under ambient conditions using the optimized ZnO/Cu electrode.
ACS ENERGY LETTERS
(2023)
Review
Materials Science, Multidisciplinary
Yue Wang, Chen Zhang, Xinjian Li, Tian Gao, Xue-Bin Wang
Summary: This paper focuses on the application of carbon nanomaterials in the field of electrocatalysis, discussing the doping effects of single elements (N, S, B, O, P) and double elements in carbon-based nonmetallic electrocatalysts, with a particular emphasis on their impact on reductions of nitrogen and carbon dioxide. Challenges and future prospects are also addressed.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Chemistry, Analytical
Estelle Lebegue, Hassiba Smida, Thomas Flinois, Veronique Vie, Corinne Lagrost, Frederic Barriere
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2018)
Editorial Material
Biochemistry & Molecular Biology
Nicole Jaffrezic-Renault, Estelle Lebegue
BIOELECTROCHEMISTRY
(2019)
Correction
Biochemistry & Molecular Biology
Hassiba Smida, Estelle Lebegue, Meritxell Cortes, Jean-Francois Bergamini, Frederic Barriere, Corinne Lagrost
BIOELECTROCHEMISTRY
(2019)
Article
Electrochemistry
Thomas Flinois, Estelle Lebegue, Frederic Barriere
ELECTROCHIMICA ACTA
(2019)
Article
Chemistry, Analytical
Estelle Lebegue, Nazua L. Costa, Bruno M. Fonseca, Ricardo O. Louro, Frederic Barriere
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2019)
Article
Chemistry, Analytical
Estelle Lebegue, Frederic Barriere, Allen J. Bard
ANALYTICAL CHEMISTRY
(2020)
Article
Biophysics
T. Flinois, E. Lebegue, A. Zebda, J-P Alcaraz, D. K. Martin, F. Barriere
COLLOIDS AND SURFACES B-BIOINTERFACES
(2020)
Article
Biochemistry & Molecular Biology
I. B. Trindade, G. Hernandez, E. Lebegue, F. Barriere, T. Cordeiro, M. Piccioli, R. O. Louro
Summary: Iron is crucial for all forms of life, and microbes utilize siderophores to scavenge iron. FhuF, the first and only isolated FSR protein, shares similarities with SIP proteins in binding to ferrichrome and exhibiting a redox-Bohr effect. Despite structural differences, mechanistic similarities exist between FSR and SIP proteins.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Justine Luy, Dorine Ameline, Christine Thobie-Gautier, Mohammed Boujtita, Estelle Lebegue
Summary: The detection and diagnosis of the virulence factor Rhamnolipid produced by the pathogen Pseudomonas aeruginosa can be quickly and sensitively achieved using the redox liposome single impact electrochemistry method.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Biophysics
Nazua L. Costa, Germaine Olorounto, Estelle Lebegue, Frederic Barriere
Summary: By using the optimized grafted anthraquinone electrode as a pH monitoring probe, the pH change at the biofilm-electrode interface can be accurately monitored. The study found that during the biofilm colonization period, the interface pH decreased to 5.3, while the anolyte only acidified to pH 6.2.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2022)
Editorial Material
Electrochemistry
Hassiba Smida, Francois-Xavier Lefevre, Christine Thobie-Gautier, Mohammed Boujtita, Catarina M. Paquete, Estelle Lebegue
Article
Electrochemistry
Hassiba Smida, Francois-Xavier Lefevre, Christine Thobie-Gautier, Mohammed Boujtita, Catarina M. Paquete, Estelle Lebegue
Summary: Single electrochemical impacts of Shewanella oneidensis MR-1 Gram-negative electroactive bacteria onto ultramicroelectrode surfaces were studied. Chronoamperometry measurements showed electrostatic attraction of living bacteria onto the polarized ultramicroelectrode surface. Analysis of single current step events and atomic force microscopy experiments confirmed the adsorption of living bacteria on the ultramicroelectrode surface.
Review
Chemistry, Physical
Hassiba Smida, Christine Thobie-Gautier, Mohammed Boujtita, Estelle Lebegue
Summary: Single liposome electrochemistry is a sensitive and versatile tool for understanding biological processes and mechanisms at the lipid membrane/electrode interface. It offers the opportunity to detect various biotargets with high sensitivity in a short time, but it also has limitations.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Biochemical Research Methods
Hassiba Smida, Arthur Langlard, Dorine Ameline, Christine Thobie-Gautier, Mohammed Boujtita, Estelle Lebegue
Summary: Single-impact electrochemistry is a powerful technique for analyzing bacteria at the single-cell scale. Its sensitivity has been demonstrated through chronoamperometric measurements at a polarized ultramicroelectrode. Recent studies have shown improved selectivity in identifying different bacterial strains by employing strategies like the use of redox mediators. The review discusses blocking electrochemical impacts method, electrochemical collisions, and a novel sensing strategy for virulence factors from pathogenic bacteria.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Electrochemistry
Estelle Lebegue, Nazua L. Costa, Ricardo O. Louro, Frederic Barriere
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2020)