Article
Chemistry, Multidisciplinary
So Dam Kim, Joon Ho Park, Hyokyum Ahn, Jeeho Lee, Chan-Ho Shin, Woo-Dong Jang, Byung-Kwon Kim, Hyun S. Ahn
Summary: This study extends the single-entity analysis to Pickering emulsions for the first time, revealing their similar hydrodynamic behavior to other nano-objects and elucidating the electron-transport mechanism. This research contributes to electrochemical nanomaterial synthesis.
Article
Chemistry, Multidisciplinary
Reem Khan, Daniel Andreescu, Mohamed H. Hassan, Jingyun Ye, Silvana Andreescu
Summary: Nanoelectrochemistry enables the investigation of PFAS interaction with AgNPs, providing insights into their binding behavior on nanoscale surfaces. Understanding these interactions is essential for designing highly sensitive detection methods and predicting their behavior in the environment.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Cheng Liu, Yamin Ma, Zhidan Xu, Yongtao You, Silan Bai, Junmin Nan, Lishi Wang
Summary: A new subtype of nano-impacts by emulsion droplets via reorganization of the electric double layer (EDL) at the liquid/ liquid interface (LLI) is reported. This subtype shows anodic, bipolar, and cathodic transient currents with a potential of zero charge (PZC) dependence, revealing the non-faradic characteristic of single fusion impacts. In addition, the absolute integrated mean charge is proportional to the Galvani potential at the ITIES, indicating that the EDL at the LLI may obey the discrete Helmholtz model. The exact PZC point is interpolated from the fitting curve, and the droplet size distribution is estimated from the integrated charge distribution. Moreover, the different values of Epzc between single fusion impacts of MgCl2 droplets and pure water droplets is due to the specific absorption between Mg2+ and antagonistic anion in the organic phase. The influence of the concentration of the supporting electrolyte is also investigated. The above work gives physicochemical insights into the EDL at the micropipette-supported LLI and provides potential application to measure micro/nanoscale heterogeneous media without catalytic, reactive, or charge-transfer activity via impact experiments at LLI.
JOURNAL OF PHYSICAL CHEMISTRY B
(2022)
Article
Chemistry, Physical
Javier Lorca-Ponce, Esteban Urzua, Fabian Avila-Salas, Andres M. Ramirez, Manuel Ahumada
Summary: This study synthesized silver nanoparticles (AgNPs) by photochemical means and modified their morphology through light irradiation process. The results showed that AgNPs with a lower available surface area exhibited higher catalytic activity towards methylene blue (MB) degradation. It was also demonstrated that the proper selection of morphology allowed for lower detection limit of MB and distinguishing molecular processes occurring at the interface level. This research sheds new light on the electrochemical relevance of morphology and surface area of AgNPs, although further work is required to fine-tune a sensor based on AgNPs.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Jeanette L. Voelz, Kathryn K. Hobart, Kaelyn A. Stahovich, Haleigh E. Ziebol, Nathan A. Harper, Joshua M. Feinberg, William A. Arnold, R. Lee Penn
Summary: The reactivity of ultrafine mineral particles during the oxidation process of adsorbed Fe(II) is influenced by the addition of organic carbon, leading to changes in the formation and morphology of goethite and hematite.
ACS EARTH AND SPACE CHEMISTRY
(2022)
Article
Chemistry, Physical
T. Ashwini, Reema Narayan, Padmaja A. Shenoy, Usha Y. Nayak
Summary: The nanoparticle delivery system is a promising nanotechnology application for efficient drug delivery. Computational simulation modeling tools play a crucial role in nanoparticle formulation development, aiding in understanding the complex phenomena involved.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Jianwei Zong, Wenjie Wu, Lanqun Mao, Ping Yu
Summary: Using stochastic collision electrochemistry as a method, the active sites of electrocatalysts can be identified more effectively. Experimental results demonstrate that different active sites play dominant roles in different reactions.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Jianwei Zong, Wenjie Wu, Lanqun Mao, Ping Yu
Summary: Identifying the active sites of electrocatalysts is crucial for catalyst design, but remains challenging. This study demonstrates a simple and efficient method using stochastic collision electrochemistry to identify the active sites of electrocatalysts, overcoming the limitations of traditional methods caused by the large geometric area and limited exposure of active sites. This work enriches the methodology for identifying active sites.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Analytical
Ya Ma, Xiaojuan Zhao, Qin Wang, Lishi Wang
Summary: Fourier transform large-amplitude sinusoidal voltammetry (FTSV) is used to investigate the impact of single nanoparticle transitions at the micro-liquid/liquid interface. The study demonstrates the separation of the current response signal into time and frequency domains, revealing the single-period sinusoidal voltammetry curve and the first harmonic phase angle. The results indicate that the first harmonic phase angle of the current response signal does not have a clear relationship with particle size, but varies with the particle zeta potential. Additionally, the study examines the collision signals of platinum and gold nanoparticles, finding that their first harmonic phase angles are distributed in different regions.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Review
Chemistry, Physical
Ji Young Lee, Joon ho Park, Hyun S. Ahn, Byung-Kwon Kim
Summary: Droplet nanoelectrochemistry serves as a reaction system that provides fundamental information regarding chemical/electrochemical reactions with various materials and interfaces, and the resulting applications. It offers the potential for fine tuning of metal nanoparticle synthesis to obtain high catalytic activity, and can be combined with an optical methodology for real-time imaging and analysis of single-droplet collisions and chemical/electrochemical reactions.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Chemistry, Analytical
Taghi Moazzenzade, Tieme Walstra, Xiaojun Yang, Jurriaan Huskens, Serge G. Lemay
Summary: In current-blockade impact electrochemistry, insulating particles are detected by measuring the decrease in the faradaic current caused by a redox mediator when they come into contact with a micro- or nanoelectrode. A limitation of this method is that analytes of a certain size exhibit a broad distribution of response amplitudes due to the unevenness of the mediator flux at the electrode surface. To overcome this limitation, microfabricated ring-shaped electrodes with a smaller width than the target particles are introduced, resulting in a slightly larger relative step size and a narrower distribution compared to conventional ultramicroelectrodes of equal diameter.
ANALYTICAL CHEMISTRY
(2022)
Article
Engineering, Environmental
Salah Alden Alklaf, Songhe Zhang, Jianzhong Zhu, Benjamin Manirakiza, Felix Gyawu Addo, Shaozhuang Guo, Fawze Alnadari
Summary: This study investigates the response of Vallisneria natans plants to titanium dioxide nanoparticles and their impact on nitrogen species removal in wetlands. It suggests that the nanoparticles have toxic effects on the plants and epiphytic microbial communities, leading to a decline in nitrogen concentrations.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Turki Al Hagbani, Hemant Yadav, Afrasim Moin, Amr Selim Abu Lila, Khalid Mehmood, Farhan Alshammari, Salman Khan, El-Sayed Khafagy, Talib Hussain, Syed Mohd Danish Rizvi, Marwa H. Abdallah
Summary: This study demonstrates the use of vancomycin-functionalized gold nanoparticles (V-GNPs) to combat pathogenic bacterial strains. The results indicate that V-GNPs exhibit stronger antibacterial activity against pathogenic bacteria, even at lower concentrations, compared to pure vancomycin.
Article
Chemistry, Multidisciplinary
Hoduk Cho, Ivan A. Moreno-Hernandez, Vida Jamali, Myoung Hwan Oh, A. Paul Alivisatos
Summary: The study uses liquid-phase transmission electron microscopy and electron beam lithography to investigate interactions between nanorods in a predefined potential energy landscape. By changing starting spatial arrangements, the self-assembly behavior of nanorods following lift-off can be tuned.
Article
Chemistry, Physical
Kotaro Oshima, Natsuki Sato, Kentaro Nakamura, Haixin Guo, Richard Lee Smith
Summary: This study examines the settling characteristics of nanoparticles in water and cyclohexane through simulation and visualization methods. The model used in this study accurately represents the settling behavior of SiO2 nanoparticles in water, but the settling of C10CeO2 nanoparticles in cyclohexane is more complex.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Analytical
Henry T. H. Chan, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2017)
Article
Chemistry, Analytical
Yuki Uchida, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2017)
Article
Chemistry, Physical
Eser Metin Akinoglu, Enno Katelhon, Jonas Pampel, Zhiyong Ban, Markus Antonietti, Richard G. Compton, Michael Giersig
Article
Chemistry, Analytical
Yuki Uchida, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2018)
Article
Chemistry, Analytical
Hatem M. A. Amin, Yuki Uchida, Christopher Batchelor-McAuley, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2018)
Article
Chemistry, Analytical
Yuki Uchida, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2018)
Article
Chemistry, Analytical
Yuki Uchida, Enno Katelhon, Richard G. Compton
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2018)
Article
Chemistry, Physical
Chuhong Lin, Lior Sepunaru, Enno Katelhon, Richard G. Compton
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2018)
Article
Chemistry, Physical
Christopher A. Little, Ruochen Xie, Christopher Batchelor-McAuley, Enno Kaetelhoen, Xiuting Li, Neil P. Young, Richard G. Compton
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2018)
Article
Chemistry, Physical
Xue Jiao, Christopher Batchelor-McAuley, Chuhong Lin, Enno Katelhon, Eden E. L. Tanner, Neil P. Young, Richard G. Compton
Article
Chemistry, Multidisciplinary
Haiying Yang, Xiuting Li, Christopher Batchelor-McAuley, Stanislav V. Sokolov, Enno Katelhon, Richard G. Compton
CHEMISTRY-A EUROPEAN JOURNAL
(2017)
Article
Chemistry, Analytical
Kenichi Shimizu, Stanislav V. Sokolov, Enno Katelhon, Jennifer Holter, Neil P. Young, Richard G. Compton
Article
Chemistry, Analytical
Minjun Yang, Christopher Batchelor-McAuley, Enno Katelhon, Richard G. Compton
ANALYTICAL CHEMISTRY
(2017)
Article
Chemistry, Multidisciplinary
Kay J. Krause, Fabian Brings, Jan Schnitker, Enno Katelhon, Philipp Rinklin, Dirk Mayer, Richard G. Compton, Serge G. Lemay, Andreas Offenhaeusser, Bernhard Wolfrum
CHEMISTRY-A EUROPEAN JOURNAL
(2017)
Article
Chemistry, Multidisciplinary
Crystal Chan, Enno Katelhon, Richard G. Compton