Article
Chemistry, Applied
Vahide Nuran Mutlu, Selahattin Yilmaz
Summary: The glycosidation of glucose with n-butanol was studied using sulphated Zr and tungstophosphoric acid incorporated SBA-15 catalysts, showing improved acidity and higher yields of butyl glucoside. The TPA-SBA-15 catalyst demonstrated the highest activity and selectivity, with stable and reusable performance. Further studies on reaction temperature and catalyst amount were conducted to optimize the reaction parameters.
Article
Green & Sustainable Science & Technology
Pingbo Zhang, Peng Liu, Mingming Fan, Pingping Jiang, Agus Haryono
Summary: Magnetic mesoporous solid acid catalysts, modified by two different methods, exhibited ordered mesoporous structure and excellent paramagnetic properties, leading to high catalytic activity in the transesterification of palm oil with methanol for biodiesel production. Particularly, the catalyst prepared by the grafting method showed excellent reusability with over 80% biodiesel yield after 6 cycles, demonstrating promising industrial application prospects.
Article
Chemistry, Applied
Mani Durai, Sakthivel Kumaravel, Arivanandhan Mukannan, Balu Krishnakumar, Sivakumar Thiripuranthagan, Young-Ho Ahn
Summary: The study aims to synthesize ethyl valerate (EV) as a fuel additive by esterifying valeric acid with ethanol using Al-SB and x% PTA/Al-SB catalysts. Among the catalysts, the 30% PTA/Al-SB catalyst exhibited the highest catalytic activity with 96% conversion of valeric acid and 100% selectivity towards ethyl valerate. Additionally, the recyclability of the prepared catalyst was found to be excellent.
JOURNAL OF POROUS MATERIALS
(2021)
Article
Chemistry, Applied
Edgar Tututi-Rios, Horacio Gonzalez, Denis A. Cabrera-Munguia, Aida Gutierrez-Alejandre, Jose L. Rico
Summary: Through the sol-gel method, Sn-SBA-15 catalysts modified with -PrSO3H groups were synthesized, which significantly improved the acid properties of the catalysts and increased the conversion rate of the esterification reaction between oleic acid and methanol.
Article
Chemistry, Multidisciplinary
Tzong-Horng Liou, Guan-Wei Chen, Shang Yang
Summary: Amino-functionalized nanoporous SBA-15 materials were studied for the adsorption of tannic acid (TA). The prepared composites exhibited high adsorption capacity and ultrafast removal of TA under various conditions including solution temperature, solution pH, agitation speed, adsorbent dosage, and initial TA concentration.
Article
Engineering, Environmental
Xi Cheng, Qingge Feng, Dachao Ma, Hongcheng Chen, Xu Zeng, Feifan Xing, Jiayang Teng
Summary: By improving the synthesis process of the catalyst and characterizing the structure of materials, the catalytic activity and stability of CH3-SBA-15-SO3H material in converting glucose to levulinic acid were examined. The results showed that CH3-SBA-15-SO3H exhibited good recyclability and hydrothermal stability, indicating its potential in the development and utilization of biomass resources.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Binxiong Guang, Wei Zhang, Yuefeng Wu, Yahui Xiao, Miaojun Su, Yong Liu
Summary: In this study, dual sulfonic acid functionalized heteropolyacid-based ionic liquids were synthesized and used as solid acid catalysts for selective esterification of glycerol with acetic acid. The catalyst showed excellent catalytic activity and selectivity to triacetylglycerol (TAG), attributed to its medium acidity of dual-SO3H groups and carbon chain length. The effects of reaction conditions and catalyst reusability were also investigated.
Article
Energy & Fuels
Yibo Zhang, Wei Wang, Chunlai Liu, Peihang Shen, Zelong Liu, Jianglei Hu, Fengwei Shi
Summary: In this study, a novel composite material (HPW@MOF-199/SBA-15C, PMS-15C) was successfully synthesized, in which HPW catalyst encapsulated in MOF-199 was confined in carboxy-functionalized SBA-15C. The physicochemical properties of the composite PMS-15C were extensively characterized. The results showed that HPW@MOF-199 was successfully synthesized and embedded into the SBA-15C pores. The composites PMS-15C exhibited high activity and excellent reuse properties in the esterification reaction, without any evidence of aggregation, leaching, or inactivation of HPW@MOF-199 during repeated use.
Article
Chemistry, Physical
M. A. Maquirriain, L. G. Tonutti, C. A. Querini, B. O. Dalla Costa, M. L. Pisarello
Summary: This article investigates the use of mesoporous silica (SBA-15) functionalized with different concentrations of sulfonic groups in the esterification of glycerine with fatty acids. The effects of temperature, free fatty acids/glycerine ratio, and catalyst concentration on the reaction yield and by-products are analyzed. The hydrophobic/hydrophilic behavior of the catalysts plays a crucial role in both the activity and selectivity of the desired products. The results highlight the importance of designing catalysts with amphiphilic properties for this system.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Engineering, Chemical
Tianlin Ma, Daojun Liu, Zheng Liu, Jinfeng Xu, Yao Dong, Gangling Chen, Zhi Yun
Summary: A novel series of HPW@UiO-66 materials with different HPW loadings were successfully prepared, among which 30HPW@UiO-66 exhibited the highest activity due to its good dispersion and catalytic performance, showing great potential in the esterification process of acetic acid with n-butanol.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Chemistry, Multidisciplinary
Zhixin Nie, Pingping Jiang, Pingbo Zhang, Dekai Liu, Agus Haryono, Minzhong Zhao, Huihang Zhao
Summary: The solid acid catalysts xHPW/Fe-Z synthesized by immobilizing HPW on magnetic zirconia showed good thermal and chemical stability with considerable magnetization. Among them, 30HPW/Fe-Z was identified as the most efficient catalyst in the esterification reaction.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2021)
Article
Chemistry, Applied
Wesley Eul, Antonio Marcelo Silva Lopes, Sibele B. C. Pergher, Tiago Pinheiro Braga
Summary: The synthesis and characterization of cobalt ferrite supported on mesoporous SBA-15 were investigated for the glycerol conversion reaction in the presence of ethanol. Characterization techniques confirmed the successful synthesis of SBA-15 and dispersed CoFe2O4 phase. The redox property and acid-base characteristics of the catalyst were evaluated, showing promising catalytic performance with ethanol as a co-reagent.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Chemistry, Applied
J. E. Castanheiro, J. Vital, I. M. Fonseca, A. M. Ramos
Summary: The acetalization of glycerol with hexanal was studied using sulfonic acid-functionalized mesoporous silica, showing optimal activity when the amount of sulfonic acid groups was moderate. Activity increased with the number of sulfonic acid groups until reaching a maximum, after which a decrease was observed. The catalytic stability of the [SO3H](3)-SBA-15 catalyst was evaluated through consecutive batch runs, demonstrating good stability.
Article
Green & Sustainable Science & Technology
Himmat Singh, Amjad Ali
Summary: A heterogeneous catalyst of K+ impregnated tungstophosphoric acid supported on graphene oxide was used for one pot esterification and transesterification of waste oil (WO). The catalyst structure was characterized by XRD, and its composition was confirmed by XPS analysis. TPD technique showed the presence of acidic and basic sites on the catalyst surface. Under optimized conditions, >98.5% biodiesel was produced within 1.5 h using a catalyst loading of 10 wt% (concerning oil), methanol: oil molar ratio of 9:1, and a reaction temperature of 65 degrees C. The catalyst could be recycled six times with metal levels in the reaction mixture below 2 ppm, and it showed activity even in the presence of free fatty acid and moisture contents.
Article
Chemistry, Multidisciplinary
Fereshte Hassanzadeh-Afruzi, Zeinab Amiri-Khamakani, Mahdi Saeidirad, Mohammad Mehdi Salehi, Reza Taheri-Ledari, Ali Maleki
Summary: A novel environmentally friendly silica-based nanocomposite named Alg@SBA-15/Fe3O4 was fabricated as a multifunctional catalytic system for the synthesis of pyrazolopyridine derivatives. The nanocomposite exhibited high catalytic efficiency and good magnetic properties, allowing for convenient separation from the reaction mixture. Overall, the Alg@SBA-15/Fe3O4 nanocomposite has great potential due to its non-toxicity, ease of preparation, recyclability, and high catalytic efficiency.
Article
Chemistry, Physical
C. V. Paz, M. Fereidooni, P. Praserthdam, A. A. Santiago, S. Praserthdam, V. Marquez
Summary: This study investigated the behavior of a photocatalytic CO2 reduction using an amorphous-TiO2 modified with silica (SiO2) catalyst. The analysis showed that surfaces with superficial SiO2 groups are more affine to some target molecules, promoting faster adsorption and reaction, but contributing to obstruction in the mechanizing reaction. Additionally, the presence of second-order links between affine target molecules and catalytic surfaces can lead to molecular blocking and catalyst deactivation, ultimately affecting the production of CO.
APPLIED SURFACE SCIENCE
(2022)
Article
Energy & Fuels
Adisak Guntida, Bunjerd Jongsomjit, Supareak Praserthdam, Piyasan Praserthdam
Summary: The deactivation of titanium catalysts supported by different preparation methods was studied during the epoxidation reaction. Wet impregnation (WI)-based catalysts showed better stability compared to those prepared by incipient wetness impreganation (IWI), and SBA-15 as a support showed higher stability than SiO2. Strong metal-support interactions in the 4Ti/SBA-15WI catalyst were found to reduce the catalyst deactivation caused by surface oxygen vacancies.
Article
Energy & Fuels
Navajsharif S. Shaikh, Sawanta S. Mali, Jyoti Patil, Ajij Mujawar, Jasmin S. Shaikh, Sumayya C. Pathan, Supareak Praserthdam, Chang Kook Hong, Pongsakorn Kanjanaboos
Summary: Researchers have developed a high-performance hybrid supercapacitor using aqueous magnesium-ion-based electrodes, which exhibit excellent specific capacitance and cycling stability. The use of magnesium ions as a replacement for commercial electrochemical supercapacitors overcomes issues such as high cost, toxicity, and inadequate energy density at high power density.
JOURNAL OF ENERGY STORAGE
(2022)
Review
Environmental Sciences
Phuet Prasertcharoensuk, Athitaya Promtongkaew, Makamas Tawatchai, Victor Marquez, Bunjerd Jongsomjit, Muhammad Tahir, Supareak Praserthdam, Piyasan Praserthdam
Summary: Hydrogen sulfide is a critical issue in biogas applications, and selective catalytic oxidation is considered a green technology for its elimination. Metal oxide-based and carbon-based catalysts are commonly used for selective oxidation, with differences in their sensitivity to operating parameters.
Article
Energy & Fuels
Nichakorn Buasuk, Meena Rittiruam, Kanokpon Maungthong, Siriwimol Somdee, Tinnakorn Saelee, Phakaorn Aphichoksiri, Chinanang Ngamlaor, Supareak Praserthdam, Piyasan Praserthdam
Summary: This study investigates the deactivation of the gamma-Al2O3 catalyst in a low-temperature methyl oleate epoxidation reaction. It reveals that soft coke and refractory coke contribute to the deactivation, with refractory coke blocking the formation of the key reaction site. Therefore, controlling coke formation is crucial for the overall performance of the catalyst.
Article
Engineering, Chemical
Chaowat Autthanit, Supachai Jadsadajerm, Oswaldo Nunez, Purim Kusonsakul, Jittima Amie Luckanagul, Visarut Buranasudja, Bunjerd Jongsomjit, Supareak Praserthdam, Piyasan Praserthdam
Summary: In this study, PET film surface was chemically modified with P25 using silicate as a binder, resulting in improved catalyst performance. The modified samples exhibited reduced band gaps and enhanced catalytic activity under visible light. The coated films showed high adsorption capacity for methylene blue and Phi-X 174 virus, with the best performances observed under fluorescent light.
BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS
(2022)
Article
Environmental Sciences
Malathi Arumugam, Kamala-Kannan Seralathan, Supareak Praserthdam, Muhammad Tahir, Piyasan Praserthdam
Summary: In this study, a novel graphene aerogel/bismuth oxyiodide (GA/BiOI) composite photocatalyst was successfully synthesized and tested for the efficient removal of methyl orange (MO) from wastewater under visible light. The composite exhibited enhanced photocatalytic activity, stability, and potential as an eco-friendly photocatalyst.
Review
Engineering, Environmental
Mohan Gopalakrishnan, Sunantha Ganesan, Mai Thanh Nguyen, Tetsu Yonezawa, Supareak Praserthdam, Rojana Pornprasertsuk, Soorathep Kheawhom
Summary: Rechargeable aqueous zinc-ion batteries (AZIBs) have gained much interest due to their high energy density, safety, and low cost. However, issues such as anode side reactions, passivation, corrosion, hydrogen evolution, and Zn dendrite growth continue to hinder their widespread application. This review presents metal-organic frameworks (MOFs) as potential solutions to these problems by enhancing the performance of Zn anode materials, electrolytes, and electrolyte additives through their porous structure and active sites. The review also proposes directions for the rational design of MOF-based Zn anodes and understanding the mechanisms affecting Zn2+ solvation in high-performance AZIBs, aiming to extend the cycling lifetime and promote the commercialization of AZIBs.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Tinnakorn Saelee, Suphawich Boonchuay, Attachai Sriwattana, Meena Rittiruam, Patcharaporn Khajondetchairit, Supareak Praserthdam, Annop Ektarawong, Bjorn Alling, Piyasan Praserthdam
Summary: Electricity production from clean energy sources has gained attention, but many power plants still use coal and natural gas, which produce toxic gases. Converting CO into a useful precursor before supplying it to chemical processes is effective, using a highly effective catalyst such as PtPdRhFeCo HEA(1 1 1) surface. This surface has unique electronic properties that weaken CO interaction and strengthen CO2 interaction, preventing CO poisoning and trapping CO2 after WGSR.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Jakapob Noppakhun, Meena Rittiruam, Tinnakorn Saelee, Jasmin Shamshoddin Shaikh, Patcharaporn Khajondetchairit, Supareak Praserthdam, Piyasan Praserthdam
Summary: The integrated carbon capture and conversion (ICCC) is a promising catalytic process to produce syngas from CO2 and CH4. The Ratings concept based on density functional theory (DFT) is applied to overcome the problems caused by inconsistent feed ratio. Catalyst identification and optimization are carried out to improve performance and account for deactivation over time. Temperature change has a greater impact on catalysts compared to feed ratio.
Article
Multidisciplinary Sciences
Meena Rittiruam, Sorawee Setasuban, Jakapob Noppakhun, Tinnakorn Saelee, Annop Ektarawong, Nuttanon Aumnongpho, Suphawich Boonchuay, Patcharaporn Khajondetchairit, Supareak Praserthdam, Bjorn Alling, Piyasan Praserthdam
Summary: The PtPd-based high-entropy alloy (HEA) catalysts are investigated for water-gas shift reaction (WGSR). Density functional theory (DFT) and Gaussian process regression are used to study the electronic properties of HEA surfaces. The strong H2O-active-site interaction with highly negative adsorption energy (E-ads) is considered as a criterion to explore potential PtPd-based WGSR catalyst candidates, such as PtPdRhAgCo, PtPdRuAgCo, PtPdRhAgFe, and PtPdRuAgFe.
ADVANCED THEORY AND SIMULATIONS
(2023)
Article
Chemistry, Physical
Patcharaporn Khajondetchairit, Meena Rittiruam, Tinnakorn Saelee, Pussana Hirunsit, Supareak Praserthdam, Suwit Suthirakun
Summary: This work studied the improved hydrogen storage kinetics on VH/Mg2NiH4(101) using density functional theory. It was found that molecular hydrogen desorption improved on this system and hydrogen vacancy sites (HV) were formed at the interfacial sites. The investigation provided insights into the desorption and diffusion processes at the active site, which can guide the design of high-performance Mg-based hydrogen storage materials.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Amruta Koli, Abhishek Kumar, Akshata Pattanshetti, Amit Supale, Kalyanrao Garadkar, Jian Shen, Jasmin Shaikh, Supareak Praserthdam, Radha Kishan Motkuri, Sandip Sabale
Summary: This work presents an efficient method for synthesizing hierarchically porous carbon using wheat bran waste. The obtained carbon material shows high CO2 capture capacity, rapid dye removal capacity, and superior electrocatalytic activity.
Article
Multidisciplinary Sciences
Chanthip Wangphon, Tinnakorn Saelee, Meena Rittiruam, Patcharaporn Khajondetchairit, Supareak Praserthdam, Annop Ektarawong, Bjoern Alling, Piyasan Praserthdam
Summary: Density functional theory is used to compare the catalytic performance of high entropy alloy (HEA) and conventional catalysts in the passive NH3-SCR process. It is found that HEA has stronger NO adsorption and more spontaneous reaction processes, but NH3 production is more difficult.
ADVANCED THEORY AND SIMULATIONS
(2023)
Article
Multidisciplinary Sciences
Meena Rittiruam, Pisit Khamloet, Potipak Tantitumrongwut, Tinnakorn Saelee, Patcharaporn Khajondetchairit, Jakapob Noppakhun, Annop Ektarawong, Bjorn Alling, Supareak Praserthdam, Piyasan Praserthdam
Summary: This study investigates the impact of host elements on the electronic properties of active sites in high-entropy-alloy (HEA) catalysts using density functional theory (DFT). The selection of appropriate host elements significantly affects the surface structures, electronic, and catalytic properties of the system. Parameters such as adsorption energy, d-band center, Bader charge, Zero-point energy, and entropy are used for accuracy verification compared to the original surface. A novel guideline for active-site model construction is proposed, demonstrated by PtPdFeCoNi high-entropy alloys. The host element selection is crucial for the electronic structure and electrocatalytic properties of active-site models.
ADVANCED THEORY AND SIMULATIONS
(2023)