4.8 Article

Solar diode sensor: Sensing mechanism and applications

Journal

NANO ENERGY
Volume 2, Issue 4, Pages 514-522

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2012.12.003

Keywords

Gas sensing; Nano heterostructures; Solar activated; Donor density

Funding

  1. Federal Ministry of Education and Research (BMBF)
  2. HR-TEM measurement
  3. DAAD
  4. FP7 grants
  5. German-Egyptian long term scholarship (GERLS)

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Herein we report a solar diode sensor (SDS) based on new designed CdS@n-ZnO/p-Si nanoelements which unify gas sensing (CdS@n-ZnO) and solar energy harvesting (n-ZnO/p-Si diode) functionalities in a singular material unit and device. A novel The SDS sensing mechanism (change of open circuit voltage, Delta V-oc), in comparison to the well-known conductometric sensors (change of resistance, Delta R), is systematically studied and explained in terms of gas-material surface interactions and the subsequent changes in the doping level (ND) of n-ZnO, which is manifested in the variation of V-oc in CdS@n-ZnO/p-Si. The fabricated SDS was capable of quantitatively detecting oxidising and reducing gases with reproducible response at room temperature and without the need of any other energy sources except solar illumination to deliver a self-sustained gas sensor. (C) 2013 Published by Elsevier Ltd.

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