Article
Chemistry, Multidisciplinary
Junjie Wang, Qingrui Luan, Pengchao Wang, Chenyu Han, Fuzhen Bi, Chunming Yang, Yonghai Li, Xichang Bao
Summary: Although NFREAs have lower synthetic costs, achieving high efficiencies in organic solar cells (OSCs) requires complex and expensive pre- or/and post-treatments. This study introduces phenylalkyl side groups (CnPh) to construct new NFREAs called BOR-CnPh without the need for additional treatments. The modified alkyl spacers of CnPh side groups control the acceptor's aggregation and regulate the interactions between donor (D) and acceptor (A). The optimization of the blend delivers efficient networks with a face-on orientation, resulting in the highest efficiency among as-cast OSCs based on NFREAs.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Adam Marks, Xingxing Chen, Ruiheng Wu, Reem B. Rashid, Wenlong Jin, Bryan D. Paulsen, Maximilian Moser, Xudong Ji, Sophie Griggs, Dilara Meli, Xiaocui Wu, Helen Bristow, Joseph Strzalka, Nicola Gasparini, Giovanni Costantini, Simone Fabiano, Jonathan Rivnay, Iain McCulloch
Summary: A series of fully fused lactam polymers with increased alkyl side chain content were synthesized via an inexpensive and non-toxic method. These polymers showed state-of-the-art n-type performance in organic electrochemical transistors (OECTs) and high thermoelectric performance when solution-doped.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Jingyi Li, Zhenyu Zhang, Guangliu Ran, Xiaoyun Xu, Cai'e Zhang, Wenlong Liu, Xinming Zheng, Dawei Li, Xinjun Xu, Yahui Liu, Zheng Tang, Wenkai Zhang, Zhishan Bo
Summary: Motivated by simplifying the synthesis of nonfullerene acceptor and establishing the relation between molecular structure and photovoltaic performance, this study designed and synthesized two isomeric nonfused ring electron acceptors with different side chains. The results showed that the acceptor with V-shaped side chain exhibited better solubility, ordered packing, and charge transport, leading to a higher power conversion efficiency compared to the acceptor with a linear side chain.
Article
Nanoscience & Nanotechnology
Zi Li, Huifeng Yao, Wenxuan Wang, Chang Eun Song, Du Hyeon Ryu, Yang Xiao, Jingwen Wang, Lijiao Ma, Tao Zhang, Junzhen Ren, Cunbin An, Won Suk Shin, Jianhui Hou
Summary: Designing efficient non-fused ring electron acceptors is crucial for reducing the material cost of organic photovoltaic cells. In this study, two non-fused electron acceptors based on bithieno[3,2-b]thiophene units were designed, and the impact of steric hindrance on molecular planarity was investigated. The results showed that enhanced steric hindrance improved the planarity of the molecules, leading to higher optical absorption and charge transport properties. This research highlights the importance of controlling molecular planarity through modulation of steric hindrance for achieving excellent photovoltaic performance of low-cost non-fused electron acceptors.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Review
Chemistry, Multidisciplinary
Youdi Zhang, Yutong Ji, Yingyue Zhang, Wenqiang Zhang, Helong Bai, Mengzhen Du, Han Wu, Qing Guo, Erjun Zhou
Summary: This paper reviews the recent progress of Y6-derived asymmetric conjugated molecules, with a focus on the relationship between molecular structure, optoelectronic properties, and device performance. It provides a reference for the future design direction and challenges of this type of photovoltaic materials.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Tian-Jiao Wen, Zhi-Xi Liu, Zeng Chen, Jiadong Zhou, Ziqiu Shen, Yiqun Xiao, Xinhui Lu, Zengqi Xie, Haiming Zhu, Chang-Zhi Li, Hongzheng Chen
Summary: Despite recent progress, organic photovoltaics (OPVs) still need to work on balancing efficiency, stability, and cost. This study developed two non-fused electron acceptors which, when blended with a specific polymer, achieved the highest reported efficiency for fully unfused electron acceptors.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Energy & Fuels
Zemin Wang, Guilong Cai, Jiayu Wang, Mengyang Li, Boyu Jia, Peiyao Xue, Xinhui Lu, Zheng Tang, Guojie Wang, Xiaowei Zhan
Summary: Molecular symmetry has slight effects on the absorption spectra, energy levels, and bandgaps, but notable effects on crystallinity, molecular packing, film morphology, and device performance. F7TC-1- and F7TC-2-based organic solar cells show significantly different power conversion efficiencies, mainly due to differences in molecular packing and film morphology.
Article
Chemistry, Multidisciplinary
Xin Zhang, Congqi Li, Linqing Qin, Hao Chen, Jianwei Yu, Yanan Wei, Xingzheng Liu, Jianqi Zhang, Zhixiang Wei, Feng Gao, Qian Peng, Hui Huang
Summary: Side-chain engineering is an effective strategy for regulating solubility and packing behavior of organic materials. The introduction of terminal side-chains in a new noncovalently fused-ring electron acceptor has shown to enhance molecular rigidity and intermolecular pi-pi stacking, resulting in record power conversion efficiency for organic solar cells.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Nanoscience & Nanotechnology
Chao Li, Guangkai Lu, Hwa Sook Ryu, Xiaobo Sun, Han Young Woo, Yanming Sun
Summary: In this study, the effect of the electron-withdrawing abilities of terminal groups on the properties of fused-ring electron acceptors (FREAs) was investigated. It was found that rational selection of terminal groups with different electron-withdrawing capabilities is desirable for designing high-performance asymmetric FREAs.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Applied
Yang Liu, Yong Zhao, Shujing Lu, Kun Zhu, Quanliang Wang, Xiao Kang, Liangmin Yu, Shuixing Dai, Mingliang Sun
Summary: The newly synthesized fused-ring electron acceptors based on indacenodithieno[3,2-b] thiophene core unit and bromine-substituted end-capped unit show improved photovoltaic performance compared to traditional compounds, with the number and position of bromine atoms significantly affecting their properties, highlighting the vital role of bromination in enhancing photovoltaic performance.
Article
Chemistry, Applied
Tian-Jiao Wen, Jiale Xiang, Nakul Jain, Zhi-Xi Liu, Zeng Chen, Xinxin Xia, Xinhui Lu, Haiming Zhu, Feng Gao, Chang-Zhi Li
Summary: Medium bandgap electron acceptors with fully non-fused structures and planar/rigid conformations have been developed for organic photovoltaics, achieving high power conversion efficiency and low non-radiative loss.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Applied
Hai Jiang, Leyi Tang, Jiang Wu, Qing Guo, Qiang Guo, Yanfang Geng, Erjun Zhou
Summary: Designing fitted acceptors for P3HT has been a hot topic in the research field of organic solar cells. In this study, two non-fused acceptors containing benzotriazole unit were prepared and one of them showed a high power conversion efficiency.
Review
Chemistry, Physical
Dou Luo, Christoph J. Brabec, Aung Ko Ko Kyaw
Summary: In recent years, the development of non-fullerene acceptors (NFAs) has significantly advanced organic solar cells (OSCs), achieving power conversion efficiency (PCE) higher than 19%. However, the complex molecular architectures of fused ring electron acceptors limit their mass synthesis and hinder the commercialization of OSCs. Non-fused ring electron acceptors (NFREAs), on the other hand, offer advantages like easy synthesis, simple modifications, and tunability in optical properties. This review analyzes the structure-property relationship of NFREAs, compares their stability and performance with traditional fused ring electron acceptors, and explores the challenges and prospects for high-performance and low-cost manufacturing of devices.
Article
Materials Science, Multidisciplinary
Lu Cheng, Zhengkun Ju, Xingyu Ji, Yaonan Ma, Jianan Fan, Po Sun, Shifan Wang, Liming Dong, Hua Sun, Jing Zhang
Summary: The development of well-conjugated building blocks is crucial for organic electronics and particularly for A-DA ' D-A-type organic semiconductors. This study presents a new A-DA ' D-A-type small molecule, TIIC, with a completely new DA ' D fused core. A concise and efficient synthetic procedure resulted in over 50% total yield. TIIC exhibits strong light absorption due to extended pi-conjugation and strong intramolecular charge transfer. Its n-type semiconductor property was confirmed by the organic field-effect transistor performance with a unipolar electron mobility of 3.51 x 10^-4 cm^2 V^-1 s^-1.
Review
Chemistry, Multidisciplinary
Xiaobin Gu, Xin Zhang, Hui Huang
Summary: Organic solar cells (OSCs) have been extensively studied, and oligomerized fused-ring electron acceptors (OFREAs) have recently emerged as a promising alternative. OFREAs have unique advantages such as well-defined structures, batch reproducibility, and excellent stability. In this Minireview, we provide a systematic summary of the recent research progress of OFREAs, including their structural diversity, synthesis approach, molecular conformation and packing, and long-term stability. We also discuss future perspectives and potential research directions to encourage the development of novel OFREAs for OSC applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Zhengkai Li, Zheng'ao Xu, Shanshan Chen, Jia Yao, Hongyuan Fu, Ming Zhang, Yang Bai, Haiqiao Wang, Zitong Liu, Zhi-Guo Zhang
Summary: By alternating the substituted position of trifluorobenzene (Ar3F) in the terminal end group, two asymmetric nonfullerene acceptor (NFA) isomers, namely BTP-gamma-Ar3F and BTP-beta-Ar3F, were designed and their photophysical and photovoltaic properties were compared. It was found that BTP-gamma-Ar3F exhibited better planarity, leading to stronger crystallization and favorable phase separation with the PM6 donor polymer, resulting in higher power conversion efficiency (17.42%) and open circuit voltage (0.90 V) in PM6:BTP-gamma-Ar3F-based organic solar cells. This established structure-property relationship provides a rational design principle for asymmetric NFAs towards high photovoltaic performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Hongyuan Fu, Ming Zhang, Youdi Zhang, Qingyuan Wang, Zheng'ao Xu, Qiuju Zhou, Zhengkai Li, Yang Bai, Yongfang Li, Zhi-Guo Zhang
Summary: In this study, a simple and cost-effective solution to the challenge of synthesizing giant molecule acceptors (GMAs) for stable polymer solar cells was presented. The Lewis acid-catalyzed Knoevenagel condensation with boron trifluoride etherate (BF3 center dot OEt2) as catalyst allowed for the efficient synthesis of GMAs, resulting in a high device efficiency of over 18%.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Xiangxi Wu, Xin Jiang, Xiaojun Li, Jinyuan Zhang, Kan Ding, Hongmei Zhuo, Jing Guo, Jing Li, Lei Meng, Harald Ade, Yongfang Li
Summary: By introducing a phenyl end group in the inner side chains, the morphology and photovoltaic performance of organic solar cells processed by nonhalogenated solvents can be improved.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Qian Li, Rui Wang, Tao Yu, Xiaoyong Wang, Zhi-Guo Zhang, Yuan Zhang, Min Xiao, Chunfeng Zhang
Summary: Researchers have identified a new charge separation channel in model copolymer/NFA blends, which allows for long-range charge separation and direct release of free charges. This mechanism, in conjunction with the short-range pathway that involves interfacial charge-transfer excitons, holds potential for optimizing OPVs with diverse device structures.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Akash Singh, Yongshin Kim, Reece Henry, Harald Ade, David B. Mitzi
Summary: This study reports the glass formation and kinetic properties of low-melting-temperature 1-MeHa(2)PbI(4) perovskite. The slight loss of organic and hydrogen iodide components helps stabilize the glassy state, and the fast crystal growth rate shows potential for extended applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Polymer Science
Wei Liu, Xiang Xu, Siqing He, Rui Sun, Qi Chen, Jie Min, Zhiguo Zhang, Jun Yuan, Yongfang Li, Yingping Zou
Summary: This study reports a new three-arm star-shaped quasi-macromolecule acceptor TBT and compares it with the traditional linear molecule acceptor DBT. The results show that TBT has advantages in light-absorption capability, tendency to aggregate, and packing behavior. In the organic solar cell blended with PM6, TBT achieves a higher power conversion efficiency (18.04%), which is one of the highest values obtained by star-shaped acceptors in binary organic solar cells.
Article
Chemistry, Multidisciplinary
Zhengxing Peng, Harald Ade
Summary: It has been reported that conjugated polymer:small molecule systems may exhibit complex phase behavior, but it was unclear if the observations were reflecting equilibrium. To study this, the liquidus and binodal for the same systems were presented, and it was found that the observed trends of the binodal were consistent with the liquidus, suggesting a thermodynamic cause behind the complex phase behavior. Additionally, a linear relationship between the composition difference (Delta phi) and the binodal composition (phi(b,polymer)) was discovered, providing a new approach for obtaining the crystalline-amorphous interaction parameter.
MATERIALS HORIZONS
(2023)
Article
Multidisciplinary Sciences
Hongmei Zhuo, Xiaojun Li, Jinyuan Zhang, Can Zhu, Haozhe He, Kan Ding, Jing Li, Lei Meng, Harald Ade, Yongfang Li
Summary: This study synthesizes giant molecule acceptors with different numbers of subunits using a stepwise synthetic method and investigates the influence of subunit numbers on their photovoltaic performance. The results show that the subunit number has a significant impact on the charge transfer state yield, lifetime, and power conversion efficiency of the acceptors-based devices.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Zhen Wang, Zhengxing Peng, Nrup Balar, Harald Ade
Summary: This study reveals the rapid degradation and aging issue of inks prepared via thermal and mechanical agitation at room temperature and develops an approach to slow down the aging process by adding high miscibility additives. The additives act as co-solvents to prevent the pre-aggregation of polymers and maintain electron percolation, benefiting charge creation and collection. This synergistic approach promotes the scale-up of ink-processed organic solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Zhifang Du, Hoang Mai Luong, Sina Sabury, Pattarawadee Therdkatanyuphong, Sangmin Chae, Claire Welton, Austin L. Jones, Junxiang Zhang, Zhengxing Peng, Ziyue Zhu, Sadisha Nanayakkara, Veaceslav Coropceanu, Dylan G. Choi, Steven Xiao, Ahra Yi, Hyo Jung Kim, Jean-Luc Bredas, Harald Ade, G. N. Manjunatha Reddy, Seth R. Marder, John R. Reynolds, Thuc-Quyen Nguyen
Summary: We investigate the use of molecular acceptors and donor polymers processed with a biomass-derived solvent to achieve high power conversion efficiency in bulk heterojunction organic photovoltaics. Our results demonstrate that the favorable intermixing of the donor and acceptor materials in the best performing BHJ film leads to improved charge generation and extraction, while also limiting trap-assisted recombination. This research provides valuable insights for the development of efficient organic photovoltaic devices.
MATERIALS HORIZONS
(2023)
Article
Chemistry, Physical
Liang Zeng, Ming Zhang, Mengyuan Gao, Lingwei Xue, Haiqiao Wang, Zhi-Guo Zhang, Long Ye
Summary: The deuterium isotope effect plays a significant role in organic reactions and semiconductors. However, its application in organic solar cells has not been fully explored. In this study, two non-fullerene acceptors were designed and synthesized to investigate the effect of deuterium isotope on their optoelectronic and photovoltaic properties. The deuterated acceptor showed higher power conversion efficiency and fill factor compared to the control acceptor.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Ho Ming Ng, Chung Hang Kwok, Zhenyu Qi, Zhen Wang, Li Chen, Wei Liu, Wenchao Zhao, Harald Ade, Chen Zhang, He Yan, Han Yu
Summary: In this study, a novel Y-series small molecule acceptor was developed by adopting benzoselenadiazole as the central core and introducing alkoxy side chains on the beta-position of thiophene moieties. The introduction of alkoxy side chains led to upshifted energy levels and optimized morphology, leading to improved power conversion efficiency.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)