4.6 Article

High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic polymer

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 2, Pages 299-302

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta12999c

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Funding

  1. DOE [DE-FG02-08ER15967]
  2. Dow Chemical Company
  3. NSF [DGE-0824162]

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A porous organic polymer decorated with high densities of copper(catecholate) groups was prepared and characterized. Single-component propylene and propane isotherms measured at ambient temperatures and ideal adsorption solution theory (IAST) calculations revealed increasing propylene/propane selectivities with increasing pressures.

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