Article
Chemistry, Analytical
Wanpeng Tian, Jiecheng Li, Zilong Liang, Xiaoxin Lin, Guangying Zhou, Qiong Hou, Suilian Luo, Yuhai Wang, Guang Shi, Ronghua Zeng
Summary: This paper presents an isophthalic acid-functionalized peryleneimide (PI-COOH) anode active material for lithium-ion batteries. The capacity storage mechanisms, cycling performance, and rate capability of PI-COOH electrodes are investigated. The results indicate that PI-COOH shows good cycling stability and rate capability, making it a potential anode material for Li-ion batteries.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Fangyuan Kang, Yilin Lin, Shiwei Zhang, Zicong Tan, Xiang Wang, Jinglun Yang, Yung-Kang Peng, Wenjun Zhang, Chun-Sing Lee, Weiwei Huang, Qichun Zhang
Summary: Organic radical batteries (ORBs) with radical-branched polymers as cathode materials are considered as a promising solution for energy storage. A chemically stable polynitrosoarene (tris(4-nitrosophenyl)amine) is designed as an efficient cathode for ORBs, which exhibits remarkable reversible charge/discharge capability and high capacity. It can achieve a capacity of up to 300 mA h g(-1) (93% theoretical capacity) after 100 cycles at 100 mA g(-1) within a wide potential window. The material also shows outstanding cycle life with 85% capacity retention after 1000 cycles at 1000 mA g(-1), making it the best-reported organic radical cathode material for lithium-ion batteries.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Energy & Fuels
Jianhang Yang, Rizwan Ur Rehman Sagar, Tauseef Anwar, Xiaocheng Li, Zhang Qian, Tongxiang Liang
Summary: The study focuses on the synthesis of graphene foam as anode material using the CVD method, and its stable performance in coin-cell lithium-ion batteries with a high specific capacity at 0.1 C. The research shows that the GF-anode exhibits stable performance in charge-discharge cycles with high specific capacity.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Physical
Xiao Li, Qian Chu, Mingqi Song, Chunhua Chen, Yulin Li, Xiaodong Tian, Yuming Cui, Deyang Zhao
Summary: Porous CoO/Co3O4 nanoribbons were fabricated using a hydrothermal and annealing method. The nanoribbons have self-assembled ultra-thin structure with mesoporous/macroporous characteristics and oxygen vacancy, which contribute to buffering volume change, enlarging contact area, improving cycling life, and enhancing specific capacity. Additionally, the oxygen vacancies and three-dimensional network promote internal conductivity and accelerate the diffusion of electrons/ions, resulting in excellent rate performance.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Jun Wang, Hongyan Yao, Chunya Du, Shaowei Guan
Summary: The novel polyimide NBI-PI, with extended pi-conjugated naphthalene ring and Schiff-base structure, shows promising reversible capacity, rate performance, and capacity retention as an organic anode material for lithium-ion batteries.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Zhaolin Li, Hailei Zhao, Xin Tao, Yaozong Yang, Jie Wang, Zhao Yang
Summary: In this study, a graphene-modified lithium silicate (LS) nanodots decorated SiOx-C material was prepared using a sol-gel approach and subsequent heat treatment. The material exhibited fast Li-ion and electron transport, enhancing the electrode reaction kinetics of SiOx. The highly-conductive network of graphene also mitigated the structural stress of SiOx, resulting in excellent structural durability. The electrode showed a reversible capacity of 400 mAh g-1 at 0.5 A g-1 for 200 cycles without obvious capacity degradation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Chengwei Li, Yun Huang, Jiapin Liu, Jiepeng Chen, Xing Li, Mingshan Wang, Bingshu Guo, Yuanhua Lin
Summary: This research reports the use of Li(2)PA as an organic anode active material for lithium-ion batteries, which exhibits high capacity and good cycling stability. The storage mechanism and specific reaction process of Li(2)PA are explored, contributing to the development of organic anodes.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Shuling Liu, Chao Luo, Chao Liu
Summary: The development and design of anode materials for high-performance Lithium ion batteries (LIBs) is currently a research hotspot. The Sn4P3/MWCNTs composite shows excellent cycling performance and capacity retention due to the synergistic effect between multi-walled carbon nanotubes (MWCNTs) and Sn4P3. MWCNTs enhance conductivity and disperse Sn4P3 nanoparticles, while Sn4P3 contributes to high specific capacity, making the composite a promising anode material for LIBs.
APPLIED SURFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Haili Cai, Lining Fan, Wei Chen, Hui Zheng, Xiaoxiao Guo, Peng Zheng, Liang Zheng, Yang Zhang
Summary: Iron carbide-functionalized porous carbon nano-composites are potential anode materials for lithium-ion batteries due to their good electrocatalytic performance, stable chemical properties, and reasonable cost-effectiveness. In this study, a Fe3C-functionalized 3D nitrogen-doped porous graphene nanocomposite (Fe3C/NPG) was synthesized using silk fibroin coordination with Fe ions. The Fe3C/NPG composite exhibited a distinct 3D porous structure, high doping levels of nitrogen atoms (approximately 10%), and well-dispersed Fe3C nanoparticles with strong interfacial bonding. It showed excellent cycling stability and rate performance as a LIB anode material at certain heating temperature and Fe ion concentration.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Yan Yang, Zhe Ma, Qing Wang, Zhenxiao Lu, Tiantian Jia, Guangyin Liu, Yiyang Liu, Zhizheng Yang, Suran Wang, Xiaodi Liu
Summary: A 3D hierarchical structure of urchin-like MoNb12O33 microspheres with radially oriented nanorods was synthesized, which demonstrated fast ion/electron transport kinetics, structural stability, and high tap density, significantly improving the Li+ storage properties. As an anode material for LIBs, the U-MoNb12O33 microspheres exhibited high practical capacity, superior rate capability, and excellent cyclability. Evaluation: 9 out of 10.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Shengnan Zhang, Kai Zhu, Yinyi Gao, Tianzeng Bao, Hongbin Wu, Dianxue Cao
Summary: Polyimide, as a promising electrode material for lithium-ion batteries, has easy synthesis, customizable structure, and structural stability. The benzene ring structure of polyimide exhibits strong lithium storage capacity as a negative electrode material. We designed and synthesized a polyimide organic polymer (PBPAQ) with a unique spherical flower structure, which enhances the interaction between the electrode material and the electrolyte. The PBPAQ anode shows a specific discharge capacity of 738 mAh g(-1) after 100 cycles at 0.1 A g(-1), laying a foundation for future research on LIB anodes.
CHEMISTRY-AN ASIAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Han Wang, Lu Zhao, Xuxu Tang, Li-Ping Lv, Weiwei Sun, Yong Wang
Summary: Covalent organic framework (COF), modified by graphitic quantum dots (GQDs), shows enhanced lithium-storage performance as an anode for rechargeable Li-ion batteries. The modification leads to improved long-term cycling stability, increased reversible capacities, and shortened activation process. These improvements are attributed to the activation of more active sites and fast lithium-ion transportation provided by carboxyl GQDs, as well as the decreased interphase resistance and enhanced electronic conductivity resulting from the addition of GQDs.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Physical
Wen Ding, Xiaozhong Wu, Yanyan Li, Shuo Wang, Zhichao Miao, Pengfei Zhou, Jin Zhou, Shuping Zhuo
Summary: A novel three-dimensional graphene-wrapped Co0.85Se@C composite was prepared through a capillary evaporation-induced drying method, resulting in a compact material with strong covalent interaction. The composite showed high volumetric capacity, good cycling stability, and rate performance, making it a promising electrode material for lithium-ion batteries.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Pei-Min Ting, Jun-Ying Huang, Rasu Muruganantham, Wei-Ren Liu
Summary: This study proposes two different nitrogen doping approaches to investigate the electrochemical behavior of few-layer graphene as anode materials for Li-ion batteries. The results show that nitrogen doping can significantly improve the electrochemical performance of few-layer graphene.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Weiqiang Kong, Luzheng Zhao, Jiancong Guo, Haoyuan Zhu, Wenruo Li, Xu Han, Shun Liu, Wenhao Yu, Liying Cui, Zhongsheng Wen
Summary: This study presents a rational strategy to improve the lithium storage performance of carbon derived from metal organic frameworks (MOFs) by decorating it with red phosphorus. The decorated carbon material not only provides more active sites for lithium storage, but also facilitates the performance of red phosphorus sites. The results show excellent cyclic stability and charge transfer kinetics of the decorated carbon material.
Article
Materials Science, Multidisciplinary
Jinghao Yang, Yingying Zheng, Shengjie Wang, Bin Liu, Huaqiang Gong, Ningning Yu, Yahui Zhang, Mengyuan Li, Lili Sun, Wenyu Chen, Heyuan Liu, Yunhao Wang, Lubing Bai, Jinyi Lin, Wei Huang
Summary: This study proposes an alternating copolymerization strategy to control the secondary conformational behavior of light-emitting polymers and achieve deep-blue emission with narrowband and stable color purity. By optimizing the hierarchical structure, deep-blue polymer light-emitting diodes (PLEDs) with stable electroluminescence, high brightness, and high current efficiency are successfully fabricated on a large scale. This strategy improves the performance and stability of deep-blue PLEDs.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Zong-Qiong Lin, Guangheng Fan, Tao Zhang, Fengwei Huo, Qiao Xi, Jie Wang, Tiantian She, Xinwei Zeng, Jiena Weng, Wei Huang
Summary: A robust aqueous solid-electrolyte interphase (SEI) is successfully constructed by introducing a ladderized heterocyclic polymer electrode into a water-in-salt electrolyte, enabling ultra-stable dual-ion storage with long-term calendar life. The sophisticated SEI composed of fluorinated/oxygenated species is formed through a proton co-intercalation process, consuming water in the solvation shell of Li+ ions to trigger the decomposition of organic anions. This new SEI formation path is expected to broaden the applications of aqueous SEI and facilitate the design of versatile electrode materials for advanced aqueous Li-ion batteries (ALIBs).
ADVANCED ENERGY MATERIALS
(2023)
Review
Materials Science, Multidisciplinary
Zixing Zhou, Xiaoyu Xie, Zhonglie Sun, Xiao Wang, Zhongfu An, Wei Huang
Summary: Metal-free room temperature phosphorescence (RTP) emitters have gained attention as promising materials for phosphorescent organic light-emitting diodes (PhOLEDs) due to their high exciton utilization. This review highlights recent advances in the mechanisms and material systems of RTP emitters for PhOLEDs, including molecular design principles and optoelectronic behaviors. The review also presents a series of reported phosphorescent materials with high phosphorescence quantum efficiency and short phosphorescent lifetime, which have potential application prospects in the field.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Engineering, Biomedical
Wei Du, Shubo Du, Xiao Dong, Hua Bai, Jiamin Jiang, Shiping Hao, Fen Yang, Qicai Xiao, Bei Zhang, Jingyan Ge, Liqian Gao, Lin Li, Shao Q. Yao, Wei Huang
Summary: This study presents a convenient and highly efficient method for delivering native proteins/antibodies to the cell nucleus using biodegradable silica nanocapsules (BSNPs) modified with nuclear localization signals (NLS) peptides.
Article
Engineering, Environmental
Shaokun Chong, Shuangyan Qiao, Lingling Yuan, Qianwen Zhou, Ting Li, Shihong Dong, Yikun Wang, Meng Ma, Wei Huang
Summary: Nanoplate-structured Sb2Te3 anchored on graphene and N-doped C (Sb2Te3@rGO@NC) is used as an anode material for potassium-ion batteries, exhibiting a dual encapsulation effect that can effectively restrain large volume expansion and enhance electronic transfer and ion adsorption. The resulting Sb2Te3@rGO@NC electrode delivers high charge capacity, rate capability, and long-term lifetime, demonstrating the potential of Sb2Te3-based anodes for potassium-ion batteries and providing insights into the K-ion storage mechanism.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Chemistry, Multidisciplinary
Wei Liu, Xin Li, Ting Wang, Fei Xiong, Changrui Sun, Xikuang Yao, Wei Huang
Summary: Platinum (Pt) drugs are widely used in cancer therapy, but their efficacy is compromised by side effects and drug resistance. Precise delivery and release of Pt drugs have become important with the development of immunotherapy and imaging-guided therapy. Targeted delivery of Pt drugs increases accumulation at tumor sites and enhances antitumor efficacy. Combining Pt drugs with other theranostic agents in nanosystems achieves synergistic therapy and real-time monitoring.
Article
Chemistry, Multidisciplinary
Lei Liu, Zhuzhu Du, Jinmeng Sun, Song He, Ke Wang, Mengjun Li, Linghai Xie, Wei Ai
Summary: A molecular design strategy is employed to synthesize high-density Zn single atoms with asymmetric Zn-N3S coordination embedded in nitrogen/sulfur codoped carbon (Zn-N3S-NSC). The resulting material exhibits ultrahigh reactivity, efficient electron transfer, and decreased ion diffusion barriers, leading to impressive energy and power densities as well as excellent cycling stability.
Article
Chemistry, Analytical
Dong Wang, Zheng Gong, Wei Huang, Jun Zhao, Junlong Geng, Zhengjie Liu, Ruilong Zhang, Guangmei Han, Zhongping Zhang
Summary: Viscosity is crucial in biological systems for physiological processes like signal transduction and substance and energy metabolisms. Abnormal viscosity is a key feature of many diseases, making real-time monitoring of viscosities in cells and in vivo significant for diagnosis and therapy.
Article
Materials Science, Multidisciplinary
Man Xu, Chuanxin Wei, Shengjie Wang, Jingrui Zhang, Jingyao Ma, Ning Sun, Lili Sun, Yamin Han, Lubing Bai, Jinyi Lin, Jiawei Qiao, Xiatao Hao, Wei Xue, Linghai Xie, Wei Huang
Summary: Large-area narrow-band deep-blue polymer light-emitting diodes (PLEDs) with efficient emission and excellent printing capability were fabricated via brush coating, resulting in uniform deep-blue emission and higher external quantum efficiency compared to spin-coated films.
ADVANCED OPTICAL MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Fang Tang, Aixiang Ding, Yao Xu, Yingsong Ye, Lin Li, Rongjun Xie, Wei Huang
Summary: The integration of gene therapy and photothermal therapy offers a promising approach for cancer treatment, providing rapid response and improved effectiveness. Recent advancements in this field have resulted in notable achievements and progress towards potential clinical applications. However, challenges and future developments still need to be addressed. This comprehensive review explores the synergistic mechanisms, material systems, imaging-guided therapy, and anticancer applications of gene therapy and photothermal therapy integration, aiming to inspire further research in this promising area.
Article
Optics
Qianbo Lu, Qingxiong Xiao, Chengxiu Liu, Yinan Wang, Qixuan Zhu, ManZhang Xu, Xuewen Wang, Xiaoxu Wang, Wei Huang
Summary: Optical cavity is crucial for a wide range of applications. This paper presents a novel inverse design methodology that combines various optimization algorithms. The method allows for arbitrary response adjustment and provides an analytical characterization of the optical response. Experimental results confirm the validity of the method and demonstrate different light-displacement responses. The proposed inverse design opens up possibilities for universal optical cavity design and nanophotonic devices.
OPTO-ELECTRONIC ADVANCES
(2023)
Article
Nanoscience & Nanotechnology
Cuibing Bai, Jie Zhang, Wen Ma, Junxiong Yao, Qian Meng, Zhenni Xia, Dashuo Chen, Shuping He, Lin Zhang, Changqing Qu, Rui Qiao, Zhen Yang, Wei Huang
Summary: In this study, a new CN--activatable fluorescent probe, AHMM, was designed with a large Stokes shift and molecular structural reversible detection, overcoming the limitations of other fluorescent probes for CN- detection. AHMM exhibits excellent selectivity for CN- without interference from other anions in an aqueous DMSO system. Moreover, AHMM can quantitatively recognize CN- in tap water and visualize CN- in food samples and biological samples through fluorescence imaging.
Review
Chemistry, Physical
Guowei Gao, Xiaochen Yang, Jingxuan Bi, Wanqing Guan, Zhuzhu Du, Wei Ai
Summary: In this review, the potential of lithium-sulfur batteries (LSBs) and the challenges they face are discussed. Various strategies for improving the performance of LSBs, focusing on Li2S engineering, host materials, and additives, are systematically explored. Additionally, the review provides a detailed analysis of the redox process of Li2S cathode and proposes future research directions.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Yuhang Liu, Wanqing Guan, Siyu Li, Jingxuan Bi, Xiaoqi Hu, Zhuzhu Du, Hongfang Du, Wei Ai, Wei Huang
Summary: A sustainable dual-layered interface (SDI) is developed for protecting lithium metal anodes, which not only normalizes Li-ion flux and reduces electrode volume expansion through polyacrylonitrile (PAN) nanofibers, but also aids in constructing alloy interphase in situ with the continuous release of lithiophilic metal ions. The SDI films ensure efficient control of the electrolyte-anode interface and prolonged stabilization of lithium metal anodes.
ADVANCED ENERGY MATERIALS
(2023)
Correction
Chemistry, Multidisciplinary
Pingping Liang, Qianyun Tang, Yu Cai, Gongyuan Liu, Weili Si, Jinjun Shao, Wei Huang, Qi Zhang, Xiaochen Dong
Summary: This study provides a correction for the self-quenched ferrocenyl diketopyrrolopyrrole organic nanoparticles and their amplifying photothermal effect for cancer therapy, which serves as a reference for further research.
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)