Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 42, Pages 17815-17819Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta03818e
Keywords
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Funding
- National Natural Science Foundation of China [50972125, 51272226]
- Natural Science Foundation of Hebei Province, China [E2012203112, E2011203126]
- Key Basic Research Program of Hebei Province of China [14961106D]
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Ti-modified Si3N4 (Ti/Si3N4) whiskers were modified with titanium by a one-pot deposition method in a vacuum. Pt electrocatalysts supported on Ti/Si3N4 (Pt-Ti/Si3N4) were fabricated using a microwave-assisted reduction method. A Ti coating was formed on the surface of Si3N4 and strongly bonded with Si3N4 with the assistance of TiNx and Ti5Si3. In this paper, the Pt-Ti/Si3N4 electrocatalysts demonstrated outstanding electrochemical stability and excellent electrocatalytic activity toward the methanol oxidation and oxygen reduction reactions compared to the Pt supported on pristine Si3N4.
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