4.6 Article

In situ growth of ultrafine tin oxide nanocrystals embedded in graphitized carbon nanosheets for use in high-performance lithium-ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 2, Issue 19, Pages 6960-6965

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00021h

Keywords

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Funding

  1. National Basic Research Program of China [2013CB934102, 2014CB932102]
  2. National Natural Science Foundation of China

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A crystal-facet-induced formation method has been developed for the fabrication of graphitized carbon nanosheets (CNS) embedded with ultrafine SnO2 nanocrystals grown in situ upon calcination under a N-2 atmosphere. The obtained SnO2-CNS composite exhibits superior electrochemical performance when used as the anode material for lithium-ion batteries. Cycled at high current densities of 0.5, 1.0 and 10.0 A g(-1) for 50 cycles, the composite material delivers large discharge capacities of 826, 728, and 400 mA h g(-1), respectively. The graphitized carbon nanosheets facilitate both ion and electron transportation and act as an efficient buffer to accommodate the volume changes generated upon Li-ion insertion-extraction. The ultrafine SnO2 nanocrystals significantly shorten the diffusion distances of the lithium ions and also provide a large contact area for the interface reaction between the anode material and lithium-ions during lithiation or delithiation, leading to a remarkably high specific capacity and good cycling stability.

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