Journal
CHEMISTRYOPEN
Volume 7, Issue 11, Pages 850-857Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.201800131
Keywords
atmospheric plasma; conductive copper; copper precursors; inkjet printing; plasma-assisted inkjet printing
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Funding
- UK EPSRC
- EPSRC [EP/N509577/1]
- Ramsay Memorial Trust
- Luxembourg National Research Fund [INTER/MOBILITY/ 17/11595373]
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Bidentate diamine and amino-alcohol ligands have been used to form solid, water-soluble, and air-stable monomeric copper complexes of the type [Cu(NH2CH2CH(R)Y)(2)(NO3)(2)] (1, R=H, Y=NH2; 2, R=H, Y=OH; 3, R=Me, Y=OH). The complexes were characterized by elemental analysis, mass spectrometry, infrared spectroscopy, thermal gravimetric analysis, and single-crystal X-ray diffraction. Irrespective of their decomposition temperature, precursors 1-3 yield highly conductive copper features [1.5x10(-6) omega m (+/- 5x10(-7) omega m)] upon atmospheric-pressure plasma-enhanced sintering.
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