Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters

Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates

(2012) Toshiaki Iida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent

(2012) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system

(2012) Cheng-Pan Zhang et al.   CHEMICAL SOCIETY REVIEWS

The New Age of Electrophilic Perfluoro­alk­ylation Reactions

(2012) Yohan Macé et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes

(2012) Pär G. Janson et al.   ORGANIC LETTERS

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

A New Synthetic Approach to Efavirenz through Enantioselective Trifluoromethylation by Using the Ruppert-Prakash Reagent

(2011) Hiroyuki Kawai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

N,N-Dimethyl-S-difluoromethyl-S-phenylsulfoximinium tetrafluoroborate: A versatile electrophilic difluoromethylating reagent

(2011) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Ionic liquids as new media for electrophilic trifluoromethylation reactions

(2011) Bruce Pégot et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic Trifluoromethylation ofS-Hydrogen Phosphorothioates

(2011) Nico Santschi et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in Enantioselective Trifluoromethylation Reactions

(2011) Norio Shibata et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Organocatalyzed Regio- and Enantioselective Allylic Trifluoromethylation of Morita–Baylis–Hillman Adducts Using Ruppert–Prakash Reagent

(2011) Tatsuya Furukawa et al.   ORGANIC LETTERS

Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents

(2011) Hiroyuki Kawai et al.   ORGANIC LETTERS

Enantioselective Synthesis of Trifluoromethyl-Substituted 2-Isoxazolines: Asymmetric Hydroxylamine/Enone Cascade Reaction

(2010) Kazutaka Matoba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inherent Oxygen Preference in Enolate Monofluoromethylation and a Synthetic Entry to Monofluoromethyl Ethers

(2010) Yoshinori Nomura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Ritter-Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine Reagents

(2010) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective

(2010) Norio Shibata et al.   Beilstein Journal of Organic Chemistry

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes

(2010) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cinchona Alkaloid-Catalyzed Asymmetric Trifluoromethylation of Alkynyl Ketones with Trimethylsilyl Trifluoromethane

(2010) Hiroyuki Kawai et al.   ORGANIC LETTERS

Asymmetric Synthesis of Both Mirror Images of 3′-Fluorothalidomide by Enantiodivergent Fluorination Using a Single, Cinchona Alkaloid

(2010) Takeshi Yamamoto et al.   ORGANIC LETTERS

Mechanistical insight into ‘electrophilic’ trifluoromethylation with S-(trifluoromethyl)dibenzothiophenium salts

(2010) Yohan Macé et al.   TETRAHEDRON LETTERS

Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents

(2009) Raffael Koller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Access to Extended Yagupolskii-Umemoto-Type Reagents: Triflic Acid Catalyzed Intramolecular Cyclization of ortho-Ethynylaryltrifluoromethylsulfanes

(2009) Andrej Matsnev et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

Diethyl bromodifluoromethylphosphonate: a highly efficient and environmentally benign difluorocarbene precursor

(2009) Yossi Zafrani et al.   TETRAHEDRON

Recent advances in enantioselective trifluoromethylation reactions

(2009) Norio Shibata et al.   TETRAHEDRON-ASYMMETRY

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS

Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles

(2008) Shun Noritake et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Electrophilic Monofluoromethylation

(2008) G. K. Surya Prakash et al.   ORGANIC LETTERS

Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent

(2008) Wei Zhang et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS