4.5 Article

Direct Assembly of Benzo[a] carbazole-5-carboxylates via a Diels-Alder Reaction with Arynes and 3-Alkenylindoles

Journal

ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 3, Issue 12, Pages 1292-1301

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201402152

Keywords

arynes; carbazoles; Diels-Alder reaction; indoles; synthetic methods

Funding

  1. National Natural Science Foundation of China [21242007, 21102043]
  2. Fundamental Research Funds for the Central Universities

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A concise and direct synthetic strategy for the construction of benzo[a] carbazole-5-carboxylates has been disclosed via the Diels-Alder reaction of arynes and 3-alkenylindoles. The reaction is highly selective and affords the benzo[a] carbazole-5-carboxylates in good-to-excellent yields.

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