Article
Biochemistry & Molecular Biology
Mirko Maturi, Chiara Spanu, Andrea Baschieri, Mauro Comes Franchini, Erica Locatelli, Letizia Sambri
Summary: This paper presents a method to covalently link a luminescent Ir-complex onto the surface of MCC, which represents the first incorporation of an organometallic luminescent probe in this biomaterial. The method is easy and sustainable, using a Bronsted-acid ionic liquid as a catalyst. The obtained luminescent cellulose microcrystals exhibit high and stable emissions and maintain their luminescent properties in dry and wet matrices.
Article
Chemistry, Physical
Francesca Scarpelli, Loredana Ricciardi, Massimo La Deda, Elvira Brunelli, Alessandra Crispini, Mauro Ghedini, Nicolas Godbert, Iolinda Aiello
Summary: This study describes the synthesis and properties of a novel water-soluble Ir(III) complex, which forms highly ordered supramolecular gels in water and exhibits luminescent properties. X-ray diffraction revealed the structure of the lyotropic mesophase, showing a high degree of order.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Environmental
Li Song, Guangrong Kuang, Gui Zhang, Jiang Guo, Yingzi Fu
Summary: A new nanoflower-like iridium(III) J-aggregate (T-Ir) was prepared and used as a luminophore with good electrochemiluminescence (ECL) activity. Through a sandwich immunoreaction, detection of carcinoembryonic antigen (CEA) was achieved by utilizing T-Ir as the energy donor and gold nanoparticles capped cuprous oxide nanocubes (Cu2O@Au) as the energy acceptor. The proposed immunosensor exhibited excellent sensitivity, selectivity, reproducibility, and practicability, indicating its potential in disease diagnosis.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Nesrine Benamara, Mayoro Diop, Cedric Leuvrey, Marc Lenertz, Pierre Gilliot, Mathieu Gallart, Helene Bolvin, Fatima Setifi, Guillaume Rogez, Pierre Rabu, Emilie Delahaye
Summary: A mononuclear compound [BiCNIm](3)[DyCl6] was synthesized using solvothermal conditions from a nitrile-functionalized imidazolium ionic liquid [BiCNIm][Cl] and DyCl3 · 6H2O in acetonitrile. The Dy3+ ions are found in a quasi-regular octahedral environment formed by six chloride anions, displaying Single Ion Magnet behavior. The magnetic study compared this behavior to other mononuclear compounds containing Dy3+ ions in different octahedral environments.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Polymer Science
Timothy P. Lodge, Claire L. Seitzinger
Summary: By incorporating a photoactive moiety into a block polymer, the phase behavior of the polymer solution can be controlled with light. The positioning of the pendant azobenzene groups along the polymer backbone significantly affects the order-disorder transition of the polymer in the ionic liquid. Adjusting the location of the azobenzene units within the thermo-and photoresponsive polymer solution changes the overall behavior of the solutions and the ability to control that behavior with light and temperature.
Article
Materials Science, Multidisciplinary
Xinxue Tang, Yuk-Tong Cheng, Junda Shen, Jia-Hua Liu, Zhibo Zhang, Zhiqin Deng, Fucong Lyu, Yong Yang, Guangyu Zhu, Zhengtao Xu, Jian Lu, Yang Yang Li
Summary: This article introduces a novel, safe, and generic method for etching, gelatinating, and processing solid ceramics. It involves using multiple ionic solutions to convert calcite into a multi-ionic amorphous gel with moderate flowability, allowing for convenient collection, storage, transfer, and molding.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Antoine Groue, Eve Montier-Sorkine, Yaping Cheng, Marie Noelle Rager, Marion Jean, Nicolas Vanthuyne, Jeanne Crassous, Amalia C. Lopez, Alejandra Saavedra Moncada, Andrea Barbieri, Andrew L. Cooksy, Hani Amouri
Summary: This study describes a series of chiral cyclometalated iridium complexes and fully characterizes them. Enantiomers of the complexes were successfully resolved using chiral column chromatography techniques and their stereochemistry was analyzed using vibrational circular dichroism and TD-DFT calculations.
DALTON TRANSACTIONS
(2022)
Review
Chemistry, Physical
Bilash Chandra Roy, Tufan Singha Mahapatra
Summary: Recently, there has been a focus on the development of metallogels as novel luminescent materials, particularly using gelators with lanthanide ions like europium (Eu(iii)) and terbium (Tb(iii)). Lanthanide-based metallogels possess useful properties and find applications in advanced materials, electronics, and bio-technologies. These metallogels can tune their optical properties over the visible spectrum and respond to external stimuli due to the dynamic nature of the lanthanide-ligand coordination bond. This review discusses recent examples of luminescent supramolecular metallogels based on Eu(iii) and Tb(iii) ions with potential applications in optoelectronic devices, self-healing, and sensors.
Article
Chemistry, Inorganic & Nuclear
Guangfu Li, Shaoqing Shi, Ying Gao, Dongxia Zhu, Zhongmin Su
Summary: Two new near-infrared emissive iridium complexes were designed and synthesized in this study, both showing mechanochromic luminescent behavior attributed to physical phase transformations from amorphization to crystallization.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Chenggang Jiang, Louise M. Canada, Ngoc Bao Nguyen, Thomas S. Teets
Summary: This work describes the synthesis and characterization of a series of neutral Chugaev-type chelating dicarbene iridium complexes with different cyclometalating ligands. The effects of these ligands on the emission properties of the complexes are evaluated, and it is found that the complexes exhibit blue-shifted phosphorescence compared to previously described analogues. The study also investigates the electrochemical properties of the compounds and determines the dependence of HOMO and LUMO energies on the cyclometalating ligands.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Analytical
Zongbing Li, Seyin Zou, Shujie Wu, Xiangmin Miao, Dik-Lung Ma
Summary: A label-free fluorescent sensor using a G-quadruplex selective iridium(III) complex was developed for ultrasensitive detection of HBV DNA. The sensor showed a linear detection range of 3.0 fM to 800 pM, with a detection limit of 1.6 fM, and successfully detected HBV DNA in serum samples, demonstrating potential for biomolecular analysis.
Article
Chemistry, Inorganic & Nuclear
Jing Tu, Daniele Veclani, Filippo Monti, Andrea Mazzanti, Letizia Sambri, Nicola Armaroli, Andrea Baschieri
Summary: A new synthetic method has been developed for the preparation of unexpected emissive iridium(iii) complexes (A and B). The structures and reaction mechanisms of these complexes were characterized and analyzed. The findings of higher photoluminescence quantum yield in complex A compared to known analogues provide a potential pathway for the direct synthesis of luminescent complexes.
DALTON TRANSACTIONS
(2023)
Review
Chemistry, Multidisciplinary
Shunxin Gu, Qin Jiang, Pengfei Shi
Summary: This review highlights the importance of iridium (III) complexes in the field of luminescent materials and antitumor drugs. The unique structure and properties of iridium (III) complexes contribute to their excellent luminescence and antitumor activity, and also show great potential in areas such as biological imaging, probes and sensors, and antitumor therapy.
PROGRESS IN CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Hugo Sesolis, Geoffrey Gontard, Marie Noelle Rager, Elisa Bandini, Alejandra Saavedra Moncada, Andrea Barbieri, Hani Amouri
Summary: Heteroleptic cyclometalated iridium (III) complexes containing di-pyridylamine motifs were prepared stepwise, with the di-pyridylamine ligands tuning their electronic and optical properties to generate room temperature blue phosphorescent emitters. Single and dinuclear iridium complexes were synthesized and found to exhibit blue phosphorescent emissions, while the dinuclear rhodium complex only emitted at low temperature. The x-ray molecular structure of complex 2 confirmed the target molecule formation.
Article
Materials Science, Multidisciplinary
Kunal Kumar, Guanping Li, Olaf Stefanczyk, Szymon Chorazy, Koji Nakabayashi, Shin-ichi Ohkoshi
Summary: Coordination network-based magnets composed of uncommon Kramers ions (Nd(iii) and Sm(iii)) exhibit emissive properties and may realize diverse magneto-optical applications. The cyanide-bridged robust networks possessing lanthanide ions exhibit tricapped trigonal prism coordination geometry and single-molecule magnet (SMM) properties. The compounds also show visible emissions and SmAu displays the highest relative thermal sensitivity among Sm(iii)-containing SMMs in a 3D framework, making it suitable for thermal sensing applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Senthil Kumar Kuppusamy, Eufemio Moreno-Pineda, Aline M. Nonat, Benoit Heinrich, Lydia Karmazin, Loic J. Charbonniere, Mario Ruben
Summary: This study reports on the luminescent and/or single-molecule magnet characteristics of two new lanthanide complexes. These complexes have potential applications in molecule-based spintronics, memory, and quantum information processing.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Long Lin, Xiaogang Peng, Emilie Voirin, Bertrand Donnio, Mircea V. V. Rastei, Bertrand Vileno, Jean-Louis Gallani
Summary: By comparing the behavior of single-crystalline and multi-twinned silver nanoparticles, the influence of core crystallinity on magnetic properties was investigated. The results show that single-crystalline nanoparticles exhibit classical paramagnetic behavior, while multi-twinned nanoparticles show a combination of para- and ferromagnetic behaviors. Our hypothesis is that lattice defects within the core carry magnetic moments which couple through conduction electrons, with dipolar interactions also playing a local and macroscopic role.
HELVETICA CHIMICA ACTA
(2023)
Article
Biochemistry & Molecular Biology
Maria Francesca Colella, Nadia Marino, Cesare Oliviero Rossi, Lucia Seta, Paolino Caputo, Giuseppina De Luca
Summary: The food industry has been researching vegetable fats and oils with specific mechanical properties and lipidic composition to ensure healthy products for consumers. This study demonstrates that the regiosomerism of fatty acids within TriAcylGlycerols (TAG) moieties significantly affects their properties and human digestion. By manipulating the distribution of fatty acids in natural cocoa butter, the obtained vegetable fats show improved chemical-physical features. Experimental investigations including DSC, rheological testing, PXRD, and NMR spectroscopy were conducted to understand the factors responsible for these characteristics.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Benoit Heinrich, Patrick Kekicheff, Arnaud Hemmerle, Philippe Fontaine, David Martel
Summary: The aligned titanium oxide nanowires with anisotropic optical-electronic properties were studied using grazing incidence wide angle X-ray scattering measurements. The chemical composition was identified as H2Ti3O7 · nH(2)O with n approximately equal to 1, and the crystallographic data revealed a monoclinic cell with a lamellar substructure. Despite the doubling of the lattice in the layer plane, the cell parameters were similar to those of H2Ti3O7. Comparisons of the band gap energy values and electronic transition modes between the two polymorphs showed differences that could be attributed to the structural variation.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Veronica Conejo-Rodriguez, Bertrand Donnio, Benoit Heinrich, Roberto Termine, Attilio Golemme, Pablo Espinet
Summary: Rh-I complexes with different isocyanide ligands were synthesized and their self-assembly, aggregation, and nanostructure were studied. Alkoxy-functionalized triphenylene-arylisocyanides exhibited mesogenic behavior and showed high hole mobility in the columnar mesophases. These findings provide valuable insights into the design of supramolecular materials with improved electronic properties.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Biochemistry & Molecular Biology
Martina Gagliano, Giuseppina De Luca, Carmela Conidi, Alfredo Cassano
Summary: This study uses Nuclear Magnetic Resonance (NMR) imaging to characterize the metabolic composition of Tacle juice, which is closely related to its quality. Polar and apolar solvent systems were used to identify a significant fraction of the Tacle metabolome. UV-Visible spectroscopy was used to investigate the antioxidant capacity and total content of flavonoids, polyphenols, and beta-carotene in the juice. Ultrafiltration (UF) and nanofiltration (NF) membranes were used to clarify and fractionate the juice for recovery and purification of its bioactive principles. The impact of UF and NF processes on the metabolic profile of the juice was explored using spectrophotometric assays and H-1-NMR spectra coupled with PCA data analysis.
Article
Biochemistry & Molecular Biology
Qing Zeng, Shuai Liu, Hang Lin, Ke-Xiao Zhao, Xiao-Yan Bai, Ke-Qing Zhao, Ping Hu, Bi-Qin Wang, Bertrand Donnio
Summary: The synthesis of two sets of pi-extended pyrene compounds was reported, which exhibited remarkable luminescent and semiconducting properties. These compounds self-assembled into hexagonal columnar mesophases and could be controlled to edge-on alignment through mechanical shearing. They showed potential applications in photoelectronic devices.
Article
Biochemistry & Molecular Biology
Janah Shaya, Jean-Charles Ribierre, Gabriel Correia, Yannick J. Dappe, Fabrice Mathevet, Loic Mager, Benoit Heinrich, Stephane Mery
Summary: By introducing short dimethylsiloxane chains, the crystalline state of CBP can be suppressed, leading to different types of organization, including a soft crystal, a fluid liquid crystal mesophase, and a liquid state. X-ray scattering analysis shows that all organizations exhibit a layered configuration with alternating CBP cores and siloxane. The different organizations of CBP primarily differ in their molecular packing regularity, which modifies the interactions between neighboring conjugated cores. Consequently, the thin film absorption and emission properties of the materials vary, correlating with their chemical architectures and molecular organizations.
Article
Materials Science, Multidisciplinary
Zhao Feng, Xuelong Liu, Kentaro Imaoka, Tomohiro Ishii, Ganbaatar Tumen-Ulzii, Xun Tang, George F. Harrington, Benoit Heinrich, Jean-Charles Ribierre, Lise-Marie Chamoreau, Lydia Sosa Vargas, David Kreher, Kenichi Goushi, Toshinori Matsushima, Guijiang Zhou, Fabrice Mathevet, Chihaya Adachi
Summary: A rare example of 2D organic-inorganic perovskite incorporating strong acceptors, such as naphthalene diimide (NDI), between inorganic sheets is presented. This hybrid architecture forms highly air-stable thin films and exhibits a rare type II heterojunction, allowing efficient exciton dissociation and easy confinement of holes and electrons in the inorganic and organic sublayers, respectively. The resulting p-n heterojunction shows significantly improved photoconduction properties compared to a similar 2D perovskite structure containing optically and electrically inert alkyl chains as organic components.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ming-Mei Zhou, Jiao He, Hui-Min Pan, Qing Zeng, Hang Lin, Ke-Qing Zhao, Ping Hu, Bi-Qin Wang, Bertrand Donnio
Summary: This study describes a efficient transition-metal-free arene-fluorine nucleophilic substitution reaction for the straightforward synthesis of several Fluorinated Polycyclic Aromatic Hydrocarbons, and reports the investigation of their liquid crystalline and optical properties.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Carmen Cretu, Evelyn Popa, Giuseppe Di Maio, Angela Candreva, Ildiko Buta, Alexandru Visan, Massimo La Deda, Bertrand Donnio, Elisabeta I. Szerb
Summary: Hetero-bimetallic liquid crystalline materials, based on structurally-related Cu(ii) and Zn(ii) metallomesogens, were obtained through simple chemical blending. The properties of these materials, including mesomorphous and optical properties, can be modulated by adjusting their relative proportions. This study highlights the potential for fabricating new multifunctional polymetallic materials and controlling their properties through supramolecular interactions and synergistic effects between metal centers.
CHEMICAL COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Fabien Ceugniet, Amina Labiod, Denis Jacquemin, Benoit Heinrich, Fanny Richard, Patrick Leveque, Gilles Ulrich, Nicolas Leclerc
Summary: Thanks to the rise of efficient push-pull non-fullerene acceptors (NFAs), the power conversion efficiency of bulk-heterojunction organic solar cells has reached over 18% for binary active layers. In this study, a new series of NFAs called BTTs were designed and synthesized, utilizing the uncommon BODIPY unit as the central electron accepting unit. These BTT molecules exhibited low optical bandgaps, high extinction coefficients, and suitable energy levels for efficient electron-donor molecules. Despite the unfavorable orientation, the most efficient derivative achieved a PCE of around 6%, one of the best results for a BODIPY-based NFA.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Physical
Kosuke Kaneko, Atsuhiko Mandai, Benoit Heinrich, Bertrand Donnio, Tomonori Hanasaki
Summary: Novel hybrid silsesquioxane-based liquid crystalline derivatives with varied lengths of spacers and tails have been synthesized and their thermal behavior and liquid crystal phase structures have been investigated. The results showed that the choice of side-on attachments plays a crucial role in the formation of liquid crystal phases.
Article
Materials Science, Multidisciplinary
Hui-Min Pan, Jiao He, Wen-Hao Yu, Ping Hu, Bi-Qin Wang, Ke-Qing Zhao, Bertrand Donnio
Summary: Non-covalent interactions between arene and fluoroarene play an important role in the construction of complex supramolecular assemblies and the design of liquid crystals. By synthesizing a series of fluorine-containing triphenylene derivatives with different alkyl chain lengths, it was found that aromatic fluorination is essential for the induction and stabilization of liquid crystal phases, and the arene-fluoroarene supramolecular interactions are predominant in the face-to-face stacking of aromatic rings. The study also demonstrated the potential applications of these fluorinated molecules in photoluminescence and hole transport.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)