4.6 Article

Ultraviolet Curable Coatings of Modified Lignin

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 11, Pages 14685-14694

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b03252

Keywords

Lignin; Photopolymer; UV curing Coating; Methacrylation

Funding

  1. University of Western Ontario
  2. Natural Sciences and Engineering Research Council of Canada (NSERC)
  3. Ontario Ministry of Research and Innovation
  4. Canadian Foundation for Innovation
  5. Solvay-Cytec

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Kraft lignin (KL) was converted to methacrylated lignin through an esterification reaction using meth acrylic anhydride. It was determined that up to 70% of the hydroxyl functional groups contained within the structure of lignin were converted into corresponding methacrylate. The methacrylated lignin (ML) was incorporated into ultraviolet (UV)-curable formulations, where the formulations were applied to a surface and cured under UV light to give robust, lignin-rich coatings with loadings as high as 31 wt % of methacrylated lignin.

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