Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 2, Issue 2, Pages 173-180Publisher
AMER CHEMICAL SOC
DOI: 10.1021/sc4003714
Keywords
5-Hydroxymethylfurfural; 1,2,6-Hexanetriol; Mixed metal oxide catalyst; NiO; CoO; Furan derivatives
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Funding
- Natural Science Foundation of China [21273260]
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The conversion of biomass-derived 5-hydroxymethylfurfural (HMF) was examined over Ni Co Al mixed oxide catalysts derived from corresponding hydrotalcite-like compounds (HTlcs). 1,2,6-Hexanetriol (1,2,6-HT) was obtained in 64.5% yield under mild reaction conditions. The catalysts were characterized by X-ray. powder diffraction (XRD), CO2 temperature-programthed desorption (CO2 TPD), N2 physical adsorption, and H2 temperatureprogrammed reduction (H2 TPR), and the reaction product distribution was correlated with the catalyst composition and reaction conditions. The reaction pathway was proposed based on the results. In all cases, the conversion of HMF proceeds according to a pathway that begins with the aldehyde group being hydrogenated to form 2,5-dihydroxymethylfuran (2,5-DHF). This product then undergoes a ring-opening reaction to form 1,2,6-HT. A synergetic effect between Ni and Co was observed, which significantly promoted catalytic activity and selectivity.
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