4.7 Article

The Role of Superabsorbent Polymer on Strength and Microstructure Development in Cemented Dredged Clay with High Water Content

Journal

POLYMERS
Volume 10, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/polym10101069

Keywords

superabsorbent polymer; cemented clay; microstructure; SEM; high water content

Funding

  1. China Postdoctoral Science Foundation [2016M600396, 2017T100355] Funding Source: Medline
  2. Fundamental Research Funds for the Central Universities of China [2018B13514] Funding Source: Medline
  3. Natural Science Foundation of Jiangsu Province [BK20150819] Funding Source: Medline

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This paper presents the role of superabsorbent polymer (SAP) on strength and microstructure development in cemented clays with notably high water content. A series of unconfined compressive strength (UCS), scanning electron microscope (SEM) and X-ray diffraction (XRD) tests were performed to identify strength behavior and microstructure. Results showed that SAP significantly influenced the mechanical behavior of cemented clays with notably high water content, characterized by an increase in the unconfined compressive strength and a decrease in the after-curing water content with SAP content. This revealed that the strength increase due to SAP was directly related to the water absorption by SAP. Meanwhile, XRD results showed that the hydration products were controlled by cement and lime content, regardless of SAP content. That meant there was no chemical reaction between SAP particles used in this study and cement or lime. The microstructure analysis by SEM revealed that SAP played an important role in the microstructure of cemented clays. With an increase in SAP content, the water absorbed by SAP increased significantly, leading to a decrease in the pore volume and a denser soil fabric. This behavior indicated that the primary role of SAP on strength increase was to absorb and fix water in cemented clays. Consequently, the clay-cement cluster distance decreased with an increase in solid mass (soil particles and swollen SAP particles) and a decrease in pore water. The corresponding tighter flocculated fabric due to SAP eventually led to the strength increase.

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