Journal
ACS MACRO LETTERS
Volume 3, Issue 3, Pages 240-243Publisher
AMER CHEMICAL SOC
DOI: 10.1021/mz400644y
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Funding
- MEXT, Japan [24108739, 24225003, 25107733, 25288056]
- Grants-in-Aid for Scientific Research [26620108, 24108739, 25620179, 25107733, 25288056] Funding Source: KAKEN
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Anionic polymerization of 4-methacryloyloxy-TEMPO (TEMPO = 2,2,6,6-tetramethylpiperidin-1-oxyl) was successfully carried out using methyl methacrylate-capped 1,1-diphenylhexyllithium (DPHLi/MMA), of which nucleophilicity is moderate enough to suppress the side reaction between the nitroxide radical of TEMPO moiety and the carbanion of DPHLi, to yield the radical polymer with well-controlled molecular weight, narrow polydispersity index (PDI < 1.10), high yield (>95%), and almost 1.0 radicals per monomer unit.
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