Mechanisms of branch formation in metal-catalyzed ethene polymerization

Remarkable Reactions and Intermediates in Titanocene(IV) Chemistry: Migratory Insertion Reactions of 2,2-Disubstituted-1-alkenes, Intramolecular 1,5-σ Bond Metathesis via ε-Agostic Interactions, and a Rare Example of a β-Agostic Alkyltitanocene Complex

(2010) Francoise Sauriol et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alternative View of Long Chain Branch Formation by Metallocene Catalysts

(2010) Qing Yang et al.   MACROMOLECULES

Thermorheological Behavior of Various Short- and Long-Chain Branched Polyethylenes and Their Correlations with the Molecular Structure

(2010) Ute Kessner et al.   MACROMOLECULES

Comparative Theoretical Study on Homopolymerization of α-Olefins by Bis(cyclopentadienyl) Zirconocene and Hafnocene: Elemental Propagation and Termination Reactions between Monomers and Metals

(2010) Anniina Laine et al.   ORGANOMETALLICS

Structures and Properties of Nonchelated, d0Alkyl Alkene Complexes of the Type [Cp2ZrMe(alkene)]+: Elusive Intermediates during Ziegler-Natta Polymerizations of Alkenes

(2009) Francoise Sauriol et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

DFT investigation of the ‘quasi-living’ propene polymerisation with Cp*TiMe3/B(C6F5)3: the ‘naked cation’ approach

(2009) Jörg Saßmannshausen   DALTON TRANSACTIONS

Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine−Sulfonate Complexes: Experiment and Theoretical Studies

(2009) Shusuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactive Intermediates Formed During Olefin Polymerization by Methylalumoxane-Activatedansa-Zirconocene Catalysts: Identification of a Chain-Carrying Intermediate by NMR Methods

(2009) Dmitrii E. Babushkin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry and Mechanism of Alkene Polymerization Reactions with Metallocene Catalysts

(2009) Yury V. Kissin et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

In Silico Design ofC1- andCs-Symmetric Fluorenyl-Based Metallocene Catalysts for the Synthesis of High-Molecular-Weight Polymers from Ethylene/Propylene Copolymerization

(2009) Tebikie Wondimagegn et al.   ORGANOMETALLICS

On the First Insertion of α-Olefins in Hafnium Pyridyl-Amido Polymerization Catalysts

(2009) Cristiano Zuccaccia et al.   ORGANOMETALLICS

Chemical modification of PP architecture: Strategies for introducing long-chain branching

(2009) Khalil El Mabrouk et al.   POLYMER

Chain walking copolymerization of ethylene with cyclopentene – Effect of ring incorporation on polymer chain topology

(2009) Shawn Morgan et al.   POLYMER

Copolymerization of ethylene and cyclopentene with the Phillips CrOx/SiO2catalyst in the presence of an aluminum alkyl cocatalyst

(2008) Wei Xia et al.   JOURNAL OF APPLIED POLYMER SCIENCE

Influence of the ligand structure of hafnocene polymerization catalysts: A theoretical study on chain termination reactions in ethene polymerization

(2008) Virve A. Karttunen et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The influence of porosity on the Phillips Cr/silica catalyst 2. Polyethylene elasticity

(2008) M. P. McDaniel et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Production of Long-Chain Branched Polyolefins with Two Single-Site Catalysts: Comparing CSTR and Semi-Batch Performance

(2008) Saeid Mehdiabadi et al.   Macromolecular Reaction Engineering

Highly Branched Polyethylene from Ethylene Alone via a Single Zirconium-Based Catalyst

(2008) Eric D. Schwerdtfeger et al.   MACROMOLECULES

Computational Design ofC2-Symmetric Metallocene-Based Catalysts for the Synthesis of High Molecular Weight Polymers from Ethylene/Propylene Copolymerization

(2008) Tebikie Wondimagegn et al.   ORGANOMETALLICS

Variability of Chain Transfer to Monomer Step in Olefin Polymerization

(2008) Giovanni Talarico et al.   ORGANOMETALLICS

Influence of the Ligand Structure of Hafnocene Polymerization Catalysts: A Theoretical Study on Ethene Insertion and Chain Propagation

(2008) Virve A. Karttunen et al.   ORGANOMETALLICS

Kinetics of propylene and ethylene polymerization reactions with heterogeneous ziegler-natta catalysts: Recent results

(2008) Y. V. Kissin et al.   POLYMER SCIENCE SERIES A

Detection of an η1-Alkene Intermediate of the Type [Cp2Zr(Me)(η1-alkene)]+:  The Role of Such Species in Metallocene Catalyst Deactivation to Allylic Species

(2007) Mihaela Vatamanu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY