Article
Engineering, Chemical
Kugalur Shanmugam Ranjith, Zehra Irem Yildiz, Mohammad Aref Khalily, Yun Suk Huh, Young-Kyu Han, Tamer Uyar
Summary: In this study, a nanofiber membrane with selective adsorption and photocatalytic degradation functions was developed for treating pollutants in wastewater. By coating ZnO nanograins on a poly-cyclodextrin nanofiber membrane, the membrane exhibited high adsorption capacity for cationic impurities and effectively degraded adsorbed contaminants using reactive oxygen species produced by photoirradiation. The nanofiber membrane showed higher removal efficiency and mass transfer rate in a flow-through filtration system.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Physical
Xiaomeng Yang, Yajiao Cui, Yingyu Qi, Luyan Fu, Armin Rezayan, Chunbao Charles Xu, Jianshe Wang, Dong Sui, Yongsheng Zhang
Summary: In this work, NiO nanoparticles supported on activated carbon nanofibers (NiO/ACNFs) were synthesized by atomic layer deposition technique and used directly as self-supporting binder-free electrodes for supercapacitors. The NiO/ACNFs electrodes showed high specific capacitance and good rate capability. The excellent electrochemical capacitance performance of NiO/ACNFs can be attributed to the high conductivity and large specific surface area of ACNFs, as well as the high capacity, small size, and even dispersion of NiO.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Abdolkhaled Mohammadi, Arthur Hagopian, Syreina Sayegh, Mikhael Bechelany, Jean-Sebastien Filhol, Reza Younesi, Lorenzo Stievano, Laure Monconduit
Summary: This study investigates the detailed mechanism of lithium deposition behavior in lithium metal batteries and finds that zinc oxide coating can induce homogeneous lithium plating, leading to improved electrochemical performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Biochemistry & Molecular Biology
Elina Kylmaoja, Jani Holopainen, Faleh Abushahba, Mikko Ritala, Juha Tuukkanen
Summary: Hydroxyapatite (HA) coatings prepared using atomic layer deposition (ALD) show good biocompatibility in terms of cell adhesion and viability, opening up new possibilities for developing improved implant coatings.
Article
Medicine, Research & Experimental
Dana E. Moseson, Emily G. Benson, Ziyi Cao, Shradha Bhalla, Fei Wang, Miaojun Wang, Kai Zheng, Pravin K. Narwankar, Garth J. Simpson, Lynne S. Taylor
Summary: This study evaluates the drug release behavior from ALC-coated ASDs and develops a mechanistic framework. The results show that coating thickness and defect density impact water sorption kinetics, but have little effect on rapid drug release. Under slower releasing conditions, the coating reduces matrix crystallization and enables greater drug release. Water sorption kinetics are highlighted as a potential tool for predicting coating quality and its impact on dissolution performance.
MOLECULAR PHARMACEUTICS
(2023)
Article
Engineering, Environmental
Jong Seon Park, Beom Joon Kim, Beum Geun Seo, Gwon Deok Han, Kang-Hee Park, Junmo Koo, Hee-Deung Park, Joon Hyung Shim
Summary: In this study, the performance of zinc oxide nanowires decorated with palladium nanoparticles as a photocatalyst for sustainable water treatment was evaluated. The Pd-decorated ZnO nanowires exhibited enhanced photocatalytic performance compared to untreated ZnO NWs.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Chemistry, Applied
Seunghwan Choy, Hoang Tran Bui, Do Van Lam, Seung-Mo Lee, Wooyul Kim, Dong Soo Hwang
Summary: The combination of chitin nanofiber carrier and atomic layer deposition enables effective photocatalytic decomposition of TiO2, showing potential degradation performance for pollutants. Additionally, chitin is able to stably wedged TiO2, allowing the catalyst to undergo multiple cycles of photocatalytic reactions.
CARBOHYDRATE POLYMERS
(2021)
Article
Chemistry, Analytical
William H. Skinner, Michael Chung, Stephen Mitchell, Asli Akidil, Kristin Fabre, Richard Goodwin, Adam A. Stokes, Norbert Radacsi, Colin J. Campbell
Summary: Extracellular pH is an essential chemical factor in cellular processes and diseases. A novel gold-coated polymer mesh was fabricated for real-time measurement of pH, demonstrating its application in monitoring metabolically induced pH changes in carcinoma-derived cells. Functionalizing gold-coated polyurethane electrospun nanofibers with a pH-responsive reporter resulted in an accurate pH sensor, allowing the observation of subtle pH shifts in tumor cells.
ANALYTICAL CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Anton M. Manakhov, Natalya A. Sitnikova, Alphiya R. Tsygankova, Alexander Yu. Alekseev, Lyubov S. Adamenko, Elizaveta Permyakova, Victor S. Baidyshev, Zakhar I. Popov, Lucie Blahova, Marek Elias, Lenka Zajickova, Anastasiya O. Solovieva
Summary: The study shows the deposition of copper onto nanofibers using magnetron sputtering, thorough characterization, and testing as antibacterial agents, demonstrating its potential value for treatment of bacterial infections.
Article
Engineering, Environmental
W. Wilson McNeary, Jacob H. Miller, Sean A. Tacey, Jonathan Travis, Gabriella D. Lahti, Michael B. Griffin, Katherine L. Jungjohann, Glenn Teeter, Tugce Eralp Erden, Carrie A. Farberow, Luke Tuxworth, Michael J. Watson, Arrelaine A. Dameron, Derek R. Vardon
Summary: The conversion of wet waste-derived volatile fatty acids into jet fuel-range hydrocarbons is a promising route for increasing sustainable aviation fuel production. However, the cost and moderate alkane selectivity of Pt-based hydrodeoxygenation catalysts pose challenges for commercialization. To address this, atomic layer deposition (ALD) was used to apply TiO2 overcoats to Pt/Al2O3 catalysts, resulting in significantly increased selectivity and yield of desirable n-alkane products.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Coatings & Films
Serdar Tort, Daewoo Han, Eric Frantz, Andrew J. Steckl
Summary: Electrospun nanofibers are potential drug delivery systems for transdermal applications, with the ability to control release rate. Coating nanofibers with Parylene N or C can successfully prevent drug burst release and prolong drug release time. The Parylene coating process offers the possibility of long-term controlled release kinetics for hydrophilic drugs.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Polymer Science
Pamela M. Johnson, Katherine L. Meinhold, Nathan R. Ohl, Justin M. Lehtinen, Jennifer L. Robinson
Summary: Emulsion electrospinning is a versatile technique that can generate nonwoven fibrous meshes. The addition of surfactants can modify the final fiber characteristics and wettability of the mesh. The study found that Polyglycerol polyricenoleate (PGPR) demonstrated the highest emulsion stability, while other surfactants decreased fiber diameter. The molecular properties of surfactants can be used to predict their location and dictate fiber properties in electrospinning systems.
Review
Biochemistry & Molecular Biology
Katarina Valachova, Mahmoud Atya El Meligy, Ladislav Soltes
Summary: This review paper provides a comprehensive overview of the electrospinning of hyaluronic acid and chitosan for wound dressing applications. It summarizes the methods of preparation and challenges faced in the electrospinning process, as well as strategies to overcome these difficulties. The review also explains the biological roles and mechanisms of hyaluronic acid and chitosan in wound healing, highlighting the advantages of nanofibers and their potential for drug delivery.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Materials Science, Multidisciplinary
Chen Li, Lipei Ren, Chunhua Zhang, Weilin Xu, Xin Liu
Summary: Polypropylene (PP) membrane is widely used in water purification due to its unique structure and excellent properties, but faces challenges in oil-water separation. Superhydrophilic and underwater superoleophobic PP membranes coated with TiO2 were prepared using atomic layer deposition, showing great potential in efficient oil-water separation.
ADVANCED FIBER MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Chunlin Li, Feng Li, Jinyuan Chen, Hongmei Wu, Ying Lin, Canyu Chen, Peng Zhang, Qiugen Wang, Jing Liu, Guoying Deng
Summary: This study fabricated biomimetic cotton-like hollow Al2O3 fibers (HFs) with a unique hemostatic mechanism that can achieve safe and portable hemostasis in different situations. HFs can accelerate hemostasis compared to traditional hemostatic materials, and exhibit superior hemostatic efficacy, biocompatibility, and thermal stability.
MATERIALS & DESIGN
(2022)
Article
Materials Science, Biomaterials
Ria D. Corder, Robert B. Vachieri, Megan E. Martin, Darlene K. Taylor, Jodie M. Fleming, Saad A. Khan
Summary: It has been found that reducing the rigidity of the extracellular matrix (ECM) can slow down breast cancer development. In this study, the effects of injecting liberase enzyme on the rheology of mammary tumors were examined. The results showed that injecting liberase enzyme can decrease tumor volume and tissue modulus without affecting tissue viscoelasticity. Multiple injections of liberase enzyme resulted in smaller but stiffer tumors. Large amplitude oscillatory shear (LAOS) experiments were also performed to analyze the nonlinear rheological behavior of the tumors.
BIOMATERIALS SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yosra Kotb, Christopher M. M. Serfass, Alain Cagnard, Katelyn R. R. Houston, Saad A. A. Khan, Lilian C. C. Hsiao, Orlin D. D. Velev
Summary: This study aims to reveal the corrosion protection mechanisms of intact thermosetting epoxy coatings on metal substrates. The structure-property relationships and the effect of metal surface passivation on the coatings are investigated. The results show that the corrosion resistance of the coatings is mainly determined by the density of the crosslinked molecular network, and the densely crosslinked network also provides higher toughness to withstand pressure from underlying corrosion products.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Hwan Oh, Jung-Sik Kim, Hannah R. M. Margavio, Gregory N. Parsons
Summary: In this work, the researchers successfully achieved multi-material ASD by sequentially combining two intrinsic ASD processes. They also found that the properties of PEDOT and W ASD materials are affected by the ASD sequence. Additionally, they demonstrated the feasibility of orthogonal ASD at the nanoscale and showed that the PEDOT layer can control the lateral growth of W onto the non-growth surface.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Rachel A. Nye, Kaat Van Dongen, Danilo De Simone, Hironori Oka, Gregory N. Parsons, Annelies Delabie
Summary: Extreme ultraviolet (EUV) lithography is crucial for next-generation technology, but the low etch resistance of conventional organic EUV resists leads to poor resolution. This study combines area-selective deposition (ASD) with EUV resists to create resist hardening or tone inverting layers for improved resolution. Different scenarios for selective deposition are achieved by tuning the polymer structure and functionality. Results show promise for tone inversion using cyclohexyl protecting group and resist hardening using tert-butyl protecting group. Inhibitors are also integrated to further broaden applications. This work establishes an important baseline for using ASD on organic resists to improve EUV pattern resolution.
CHEMISTRY OF MATERIALS
(2023)
Article
Physics, Applied
H. Alex Hsain, Younghwan Lee, Patrick D. Lomenzo, Ruben Alcala, Bohan Xu, Thomas Mikolajick, Uwe Schroeder, Gregory N. Parsons, Jacob L. Jones
Summary: Ferroelectric hafnium-zirconium oxide (HZO) is a promising material for low-power non-volatile memory applications due to its ferroelectricity at the nanoscale and compatibility with silicon-based technologies. The interface between HZO and its electrode is crucial for device performance. In this study, the effect of breaking vacuum during the sequential deposition steps is investigated. The results show that breaking vacuum after bottom electrode deposition leads to interfacial oxidation and increased carbon contamination, which affect the ferroelectric properties.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Niklas D. Keller, Pierpaolo Vecchi, David C. Grills, Dmitry E. Polyansky, Gabriella P. Bein, Jillian L. Dempsey, James F. Cahoon, Gregory N. Parsons, Renato N. Sampaio, Gerald J. Meyer
Summary: Photovoltages for hydrogen-terminated p-Si(111) in an acetonitrile electrolyte were quantified using MV2+ and [Ru(bpy)3](PF6)2. The reduction potentials of MV2+ occurred within the forbidden bandgap, while those of [Ru(bpy)3]2+ occurred within the conduction band states. The study reveals that the most optimal photovoltage, electron-hole pair lifetime, and surface electron concentration occur when the reduction potentials lie energetically within the unfilled conduction band states with an inversion layer.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Materials Science, Coatings & Films
Jan-Willem J. Clerix, Golnaz Dianat, Annelies Delabie, Gregory N. Parsons
Summary: This study investigates the adsorption of DMATMS on SiO2 and the subsequent reactions during TiCl4/H2O ALD. It is found that DMATMS selectively reacts with -OH groups on SiO2 and inhibits the reaction with TiCl4. Additionally, DMATMS can also react with residual -OH groups and reduce nucleation. The effectiveness of DMATMS passivation on SiO2 and H-terminated Si is quantified using Rutherford backscattering spectrometry.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2023)
Article
Materials Science, Coatings & Films
Holger Saare, Wenyi Xie, Gregory N. Parsons
Summary: Recent advances in the semiconductor industry have led to the demand for conformal deposition and etching processes in three-dimensional devices. This study investigates thermal atomic layer etching (ALE) of TiO2 and ZrO2 using different co-reactants. The results show that the choice of co-reactant affects the saturation and etch rates at different temperatures. The study expands the understanding of co-etchants' role in thermal ALE and increases the range of reactants for vapor etching of metal oxides.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2023)
Article
Materials Science, Multidisciplinary
Vahid Rahmanian, Tahira Pirzada, Eduardo Barbieri, Sherafghan Iftikhar, Fanxing Li, Saad A. Khan
Summary: We have developed a robust method for creating polyvinylpyrrolidone (PVP)-titania (TiO2) nanofibrous aerogels (NFA) with multifunctional and triggered performances. These 3D self-supported aerogels have low density and high porosity, and are fabricated through solid templating of sol-gel electrospun PVP-TiO2 hybrid nanofibers. The aerogels exhibit photocatalytic activity, antibacterial properties, ability to sorb volatile organic compounds (VOCs) and oils, as well as excellent thermal insulation and mechanical flexibility.
APPLIED MATERIALS TODAY
(2023)
Article
Engineering, Chemical
Sarah E. E. Morgan, Carwynn D. D. Rivera, Morgan L. L. Willis, Gregory W. W. Peterson, John J. J. Mahle, Laura Mundy, Gregory N. N. Parsons
Summary: Metal-organic framework (MOF) fabric composites combine important MOF chemistry with flexible, strong fabric substrates and have various applications. This study investigates the relationship between process parameters, MOF properties, and MOF performance for UiO-66-NH2 fabric composites. It was found that the number of SVS cycles significantly impacted the performance of the MOF-fabrics.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
Prottasha Sarker, Pallav K. Jani, Lilian C. Hsiao, Orlando J. Rojas, Saad A. Khan
Summary: The interactions between collagen and TA particles under different pH conditions are investigated. It is found that TA particles provide stronger mechanical reinforcement to collagen at acidic pH due to electrostatic interaction and hydrogen bonding. The study is conducted using rheology, isothermal titration calorimetry, turbidimetric analysis and quartz crystal microbalance with dissipation monitoring.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Sipan Liu, Chenxi Sui, Myers Harbinson, Michael Pudlo, Himendra Perera, Zhenzhen Zhang, Ruguan Liu, Zahyun Ku, Md Didarul Islam, Yuxuan Liu, Ronghui Wu, Yong Zhu, Jan Genzer, Saad A. Khan, Po-Chun Hsu, Jong Eun Ryu
Summary: We have successfully fabricated spike microstructured photonic nanocomposite coatings using a rapid, low-cost, template-free roll-to-roll method. These coatings possess high solar reflectivity (>94%) and thermal emissivity (97.0%), and can achieve subambient radiative cooling during daytime under strong direct sunlight. When facing direct sunlight in the spring of Chicago, the coatings show a radiative cooling power of 39.1 W/m(2), and have a potential energy-saving capability of 14.4%.
Article
Chemistry, Multidisciplinary
Mariam Sohail, Tahira Pirzada, Richard Guenther, Eduardo Barbieri, Tim Sit, Stefano Menegatti, Nathan Crook, Charles H. Opperman, Saad A. Khan
Summary: This study reports the use of cellulose acetate nanoparticles to produce stable oil in water Pickering emulsions. The nanoparticles form interconnected networks between droplets, resulting in double yielding behavior. The emulsions show promise as agricultural formulations, with sustained release of agrochemicals and higher viability of plant-growth-promoting microbes compared to controls.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Scott McGuigan, Stephen J. Tereniak, Carrie L. Donley, Avery Smith, Sungho Jeon, Fengyi Zhao, Renato N. Sampaio, Magnus Pauly, Landon Keller, Leonard Collins, Gregory N. Parsons, Tianquan Lian, Eric A. Stach, Paul A. Maggard
Summary: This study presents a functional hybrid photocatalyst system using a crystalline carbon nitride semiconductor, poly(triazine imide) lithium chloride (PTI-LiCl), and a CoCl2(qpy-Ph-COOH) catalyst for CO2 reduction. The optimized catalyst loading achieved high rates and selectivity for CO production, which were further improved by increasing the incident irradiance. Higher surface loadings were found to extend the lifetime of the molecular catalysts.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Vahid Rahmanian, Muhammed Ziauddin Ahmad Ebrahim, Seyedamin Razavi, Mai Abdelmigeed, Eduardo Barbieri, Stefano Menegatti, Gregory N. Parsons, Fanxing Li, Tahira Pirzada, Saad A. Khan
Summary: This study presents a novel method for synthesizing metal-organic frameworks (MOFs) on 3D-structured nanofibrous aerogels (NFAs). The resulting hybrid aerogels exhibit promising applications in CO2 adsorption, heavy metal removal, and antibacterial properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)