Article
Materials Science, Multidisciplinary
Nianlong Zhang, Feifei Chen, Xian Zhao
Summary: Nd3+ doped Bi2ZnB2O7 crystals were grown via the Kyropoulos method and their crystal structure and optical properties were evaluated. The results suggest that Nd:BZBO crystals could potentially serve as a laser matrix.
Article
Materials Science, Multidisciplinary
Geng Zhao, Min Xu, Yilun Yang, Chengchun Zhao, Yin Hang
Summary: A 1.5 at.% Nd3+ and 0.5 at.% Ho3+ co-doped CeF3 single crystal was successfully grown and its absorption and fluorescence characteristics were evaluated. The spectroscopic properties of the crystal were investigated based on the Judd-Ofelt theory, and the fluorescence lifetimes of Nd3+ and Ho3+ were determined. Additionally, the magneto-optical performance of the crystal was studied for the first time, and the Verdet constants at different wavelengths were measured, showing its potential applications in lasers and magneto-optical devices.
Article
Materials Science, Multidisciplinary
Jerzy Sarnecki, Dariusz Podniesinski, Magdalena Nakielska
Summary: Solid state lasers with a planar Nd,Lu,Ga:YAG/YAG waveguide structure were created using liquid phase epitaxy. The method allows for obtaining different Nd3+ ion concentrations and achieving lasing operation at room temperature. This research provides a new approach for high-efficiency and stable solid state lasers.
OPTICAL MATERIALS EXPRESS
(2022)
Review
Chemistry, Multidisciplinary
Dazhi Lu, Xiaoheng Li, Haohai Yu, Huaijin Zhang, Jiyang Wang
Summary: Passive Q-switching is an effective method for generating pulsed lasers, and Yb3+ doped borate crystals have excellent energy storage capacity for achieving moderate to high output energy. The study systematically reviews the growth, characterization, and laser generation of Yb3+:ScBO3 crystal, showing its potential for future pulsed laser applications with moderate or high energy output.
APPLIED SCIENCES-BASEL
(2021)
Article
Crystallography
Yuxi Gao, Wenpeng Liu, Shoujun Ding, Yuanzhi Chen, Qingli Zhang
Summary: The present study reveals the effects of neutron irradiation on the optical response of the Nd3+-doped Gd3Sc2Al3O12 (Nd:GSAG) single crystal in real-time and in-situ. The crystal showed transient and permanent transmittance reduction induced by neutron radiation, and the reduction mechanisms were analyzed. XRD characterization method confirmed the constant crystal structure before and after neutron irradiation. The generation of oxygen vacancies in the crystal caused a permanent reduction in transmittance after irradiation with neutrons.
Article
Chemistry, Physical
Xiaochen Niu, Hongling Chen, Peixiong Zhang, Hao Yin, Yin Hang, Zhen Li, Wenxiong Lin, Zhenqiang Chen
Summary: A novel laser crystal Nd: CaGd0.1Y0.9AlO4 has been successfully grown by Czochralski method. The crystal with Gd3+ ions exhibits a more disorder structure compared to Nd: CaYAlO4 crystal. The crystal shows wider emission spectra and maintained wide absorption spectra. Through the as-grown crystal, dual-wavelength continuous-wave laser operation at 1358.4 nm and 1374 nm was achieved for the first time. These findings suggest that Nd: CaGd0.1Y0.9AlO4 crystal is a promising disordered laser host for longer wavelength solid laser operation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Optics
Yunyun Liu, Fei Pan, Ju Gao, Chaoyang Tu
Summary: A new disordered crystal of Nd3+-doped CaLaGa3O7 (Nd: CLGO) was successfully grown and characterized. The crystal exhibited excellent laser processing efficiency and pumping efficiency, making it suitable for generating ultrashort pulse lasers.
JOURNAL OF LUMINESCENCE
(2022)
Article
Crystallography
Yun Dai, Zhonghan Zhang, Xibin Wang, Zhuowei Lu, Huamin Kou, Liangbi Su, Anhua Wu
Summary: Ce:LuAG SCFs with a diameter of 1 mm were grown using laser-heated pedestal growth method with transparent ceramic as the source rod. The SCFs maintained excellent scintillation performance and optical properties, making them a potential candidate material for detectors.
Article
Crystallography
Ying Yang, Peng Zhu, Liu Yang, Jinjin Liu, Yongkai Li, Zhiwei Wang
Summary: In this study, the crystal growth, characterization, and electronic properties of HfSiS, ZrGeS, and ZrGeSe were investigated. All samples showed metallic behavior in temperature-dependent resistivity measurements, and HfSiS exhibited a large magnetoresistance and obvious SdH oscillation.
Article
Chemistry, Inorganic & Nuclear
David M. Smiadak, Sviatoslav Baranets, Megan Rylko, Mack Marshall, Mario Calderon-Cueva, Svilen Bobev, Alex Zevalkink
Summary: Complex Zintl phases have led to the discovery of a new thermoelectric material Ca-9()(Zn1-xInx)(4)Sb-9 (x ~ 0.9), with a structure characterized by TSb4 tetrahedra and ZnSb3 triangular units forming [T4Sb9](18-) polyanions. The heavily-disordered structure exhibits semiconducting behavior, confirmed by single crystal electrical conductivity and Seebeck coefficient measurements which suggest degenerate p-type semiconductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Roberta Silva Pugina, Eloisa Garibalde Hilario, Euzane Gomes da Rocha, Manoel L. da Silva-Neto, Avishek Das, Jose Mauricio Almeida Caiut, Anderson S. L. Gomes
Summary: Nd3+:YAG crystals have been widely used in photonic devices since the 1960s due to their unique properties. This study reports the synthesis of dense Nd3+:YAG particles using spray pyrolysis, which could be scaled up for industrial production. The high Nd3+ concentration in the particles was exploited for random laser applications.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
Lei Geng, Shuo Han, Wencai Yi, Shoubao Zhang, Chuanying Shen, Hongyan Lu
Summary: A new Nd3+ ions-doped NIR laser crystal of Na5Lu(MoO4)4 was successfully grown in a 4Na2O-5MoO3 flux through the TSSG technique, exhibiting high activator doping capabilities. Through optical absorption spectrum and photoluminescence measurements, the potential applications of this crystal in infrared laser technology were demonstrated.
Article
Optics
A. K. Varshney, Mainuddin Mainuddin, Sanjeev Kumar, V. K. Singh, Veerendra Kumar, Avinash C. Verma, Ashwani Kumar, Gaurav Singhal
Summary: In this paper, a laser diode array pumped transversely circulating inorganic lasing liquid based laser is demonstrated. The lasing liquid, consisting of 0.3 mol/l trivalent neodymium (Nd3+) ions, is synthesized using a mixture of phosphorous oxychloride (POCl3) and tin tetrachloride (SnCl4). The laser cell is side-pumped in close-coupling configuration by vertically arranged laser diode bars in an array. The lasing liquid is circulated transversely through the laser cell at flow rates of 10-12 l/min under laminar flow regime to replenish the heated lasing liquid. The results show the power scalability of liquid laser with increased optical-optical efficiency.
OPTICS AND LASER TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Ia Gerasymov, K. Hubenko, O. Viagin, Ya Boyarintseva, A. Shaposhnyk, V Baumer, T. Gorbacheva, O. Zelenskaya, E. Galenin, D. Kurtsev, S. Tkachenko, O. Sidletskiy
Summary: Ce-doped lanthanum gadolinium pyrosilicates are efficient oxide scintillation crystals with a high light yield. The use of Czochralski method in a reducing atmosphere and post-growth annealing in an oxidizing atmosphere optimize the crystal growth and improve the scintillation characteristics.
Article
Chemistry, Inorganic & Nuclear
Galina M. Kuz'micheva, Liudmila I. Ivleva, Irina A. Kaurova, Vladimir A. Lazarenko, Andrey N. Kharlanov, Alexander Fionov
Summary: The crystal structures of CVO:Cr single crystals doped with over-stoichiometric 0.01, 0.05, and 0.1 wt% Cr2O3 grown by the Czochralski method were determined. The presence of chromium in multiple calcium sites and its coordination as octahedral Cr3+ and tetrahedral Cr4+ were revealed. The green or yellow color of CVO:Cr was found to be attributed to the valence state of chromium, Cr3+ or Cr4+. The structural behavior of transition metal ions with variable formal charge in CVO structure was summarized and analyzed.
SOLID STATE SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Guangfeng Liu, Jie Liu, Xiaoxin Zheng, Yang Liu, Dongsheng Yuan, Xixia Zhang, Zeliang Gao, Xutang Tao
Article
Crystallography
Dongsheng Yuan, Yang Li, Jun Shu, Zeliang Gao, Zhitai Jia, Zhengping Wang, Xutang Tao
JOURNAL OF CRYSTAL GROWTH
(2016)
Article
Physics, Multidisciplinary
Yu Song, Dongsheng Yuan, Xingye Lu, Zhijun Xu, Edith Bourret-Courchesne, Robert J. Birgeneau
PHYSICAL REVIEW LETTERS
(2019)
Article
Nanoscience & Nanotechnology
Dongsheng Yuan
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Crystallography
Dongsheng Yuan, Encarnacion G. Villora, Kiyoshi Shimamura
Summary: Microvoids, well-known crystal defects, were observed for the first time in apparently scattering-free CeF(3) bulk single crystals, taking on the shape of perfect regular hexagonal-prisms. These microvoids are formed by the embedding of bubbles during the crystallization process, with sizes up to 13 mu m and heights in the submicron order.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Chemistry, Inorganic & Nuclear
Dongsheng Yuan, Encarnacion G. Villora, Kiyoshi Shimamura
Summary: LYBO and LYOB both belong to the monoclinic crystal system with the same space group. Ce:LYOB crystals exhibit broad emission in the orange wavelength region due to an extraordinarily large Stokes shift.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Physics, Applied
Dongsheng Yuan, Encarnacion G. Villora, Takumi Kato, Daisuke Nakauchi, Takayuki Yanagida, Kiyoshi Shimamura
Summary: Ce:LaB3O6 (LBO) glass, doped with CeF3 and melted under a reducing atmosphere, demonstrates promising thermoluminescence dosimetry capabilities with high quantum efficiency. The optimum concentration for optimal performance is 0.1%, with an interatomic distance of approximately 4 nm. Ce:LBO shows good dose resolution and can be cyclically irradiated and read without degradation.
APPLIED PHYSICS EXPRESS
(2022)
Article
Materials Science, Multidisciplinary
Dongsheng Yuan, Encarnacion G. Villora, Satoshi Tominaka, Kiyoshi Shimamura
Summary: This study compares and discusses the photoluminescence and X-ray radioluminescence of Ce:LaB3O6 (LBO) materials in both single crystalline and glassy forms, and finds that the host structure plays an important role in the luminescence properties of Ce3+. Crystalline Ce:LBO exhibits a narrow emission band with a small Stokes shift, while glassy Ce:LBO shows a broad emission band with a large Stokes shift. The presence of defects is also found to be higher in the glassy form. These results provide new insights into the contribution of the host structure to the luminescence properties of the dopant.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Physics, Applied
Dongsheng Yuan, Encarnacion G. Villora, Noriaki Kawaguchi, Daisuke Nakauchi, Takumi Kato, Takayuki Yanagida, Kiyoshi Shimamura
Summary: This study demonstrates that a post-growth thermal treatment is crucial for enhancing the light yield of Ce:Li6Y(BO3)(3) oxide. By reducing the concentration of intrinsic defects and scattering centers, the light yield is significantly improved by approximately 600%. Further optimization of the Ce3+ concentration and annealing time can potentially achieve a light yield comparable to state-of-the-art materials for thermal neutron detection.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2023)
Article
Materials Science, Ceramics
Encarnacion G. Villora, Dongsheng Yuan, Kiyoshi Shimamura
Summary: Optical isolators (OIs) are necessary to protect laser sources from back-reflections. Single-crystalline Faraday rotators (FRs) with a large Verdet constant V, such as CeF3, are highly desired to reduce the cost and size of OIs. CeF3 has shown superior performance in terms of transmittance and figure-of-merit compared to the standard Tb3Ga5O12 (TGG), especially in the ultraviolet (UV) wavelength range.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Peng Liu, Dongsheng Yuan, Chao Dong, Gaoting Lin, Encarnacion G. Villora, Ji Qi, Xinguo Zhao, Kiyoshi Shimamura, Jie Ma, Junfeng Wang, Zhidong Zhang, Bing Li
Summary: Rare earth compound LiREF4 exhibits superior magnetocaloric performance compared to commercial GGG under small magnetic fields. This makes it an ideal working material for compact magnetic refrigeration around the liquid-helium temperature.
NPG ASIA MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Xiang Chen, Yu He, Shan Wu, Yu Song, Dongsheng Yuan, Edith Bourret-Courchesne, Jacob P. C. Ruff, Zahirul Islam, Alex Frano, Robert J. Birgeneau
Summary: The compound Ba4Ir3O10 exhibits complex structural and magnetic ground state properties, including a pronounced antiferromagnetic transition, magnetic anisotropy, and symmetry lowering due to magnetoelastic coupling. The study suggests the importance of this compound in exploring novel ground states with octahedra trimers.
Article
Materials Science, Multidisciplinary
Federico Moretti, Dongsheng Yuan, Didier Perrodin, Edith Bourret
MATERIALS ADVANCES
(2020)
Article
Chemistry, Multidisciplinary
Dongsheng Yuan, Federico Moretti, Didier Perrodin, Gregory Bizarri, Tetiana Shalapska, Christophe Dujardin, Edith Bourret
Proceedings Paper
Engineering, Electrical & Electronic
Dongsheng Yuan, Zhitai Jia, Yang Li, Baiyi Wu, Xutang Tao
SOLID STATE LASERS XXV: TECHNOLOGY AND DEVICES
(2016)