Mechanochemical Effects on the Synthesis of Copper Orthophosphate and cyclo-Tetraphosphate Bulks by the Hydrothermal Hot Pressing Method

Copper orthophosphate, Cu(3)(PO(4))(2), and cyclo-tetraphosphates, Cu(2)P(4)O(12), were synthesized using phosphoric acid and basic copper carbonate, and then treated with a planetary mill for up to 360 minutes. The un-milled and milled samples were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. SEM images, particle size distribution, specific surface area, UV-Vis reflectance spectra were also used to evaluate the materials. The un-milled and milled materials were used to fabricate copper phosphate bulks by a hydrothermal hot pressing method. The influence of powder condition on the sintering behavior of the copper phosphates was studied.