Article
Chemistry, Physical
Md Mostafizur Rahman, Md Rayhan Hossen, Iftidul Alam, Md Habibur Rahman, Omar Faruk, Macid Nurbas, Mohammed Mastabur Rahman, Mohammad Mizanur Rahman Khan
Summary: Conducting polymers based hexagonal boron nitride (h-BN) nanocomposites, including polyaniline (PANI)/h-BN and polyaniline-polypyrrole (PANI-PPy)/h-BN, were successfully fabricated using a chemical oxidative polymerization approach. The synthesized materials exhibited desirable properties such as improved thermal stability and irregular morphological structures. The PANI/h-BN nanocomposites showed the highest capacitance and capacitance retention after multiple cycles compared to other materials. Furthermore, a hybrid asymmetric supercapacitor device composed of PANI/h-BN as the positive electrode and activated carbon (AC) as the negative electrode demonstrated superior performance in terms of specific capacitance, power density, and LED lighting time.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Shatrudhan Palsaniya, Harshal B. Nemade, Ashok Kumar Dasmahapatra
Summary: The study presents the fabrication of symmetric tandem supercapacitors using PANI-RGO-ZnO nanocomposite, showing excellent electrochemical performance and capacitance retention over 5000 cycles. The device exhibited significant specific energy and power capabilities, with a steady voltage of around 6.0 V, demonstrating its potential for various applications.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Engineering, Electrical & Electronic
Hongzhi Wang, Jianrui Qiu, Shaofeng Sun, Weiguo Zhang, Suwei Yao
Summary: Ni/PANI coaxial nanowire arrays were prepared by electrochemical deposition using porous anodic alumina as a template. The samples were characterized and showed high sensitivity, low detection limit, wide linear range, good selectivity and stability for non-enzymatic glucose sensors.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Hemalatha Kuzhandaivel, Sornalatha Manickam, Suresh Kannan Balasingam, Manik Clinton Franklin, Hee-Je Kim, Karthick Sivalingam Nallathambi
Summary: Sulfur and nitrogen-doped graphene quantum dots/polyaniline (S,N-GQDP) nanocomposites were prepared using a two-step synthesis method, showing improved energy storage properties with high specific capacitance and cycling stability. The study confirmed the formation of S,N-GQDs and their interaction with PANI in the nanocomposites, validating the potential of S,N-GQDP2 composite as an efficient electroactive material for energy storage applications.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Physical
Fatima Al-Zohbi, Fouad Ghamouss, Bruno Schmaltz, Mohamed Abarbri, Mustapha Zaghrioui, Francois Tran-Van
Summary: The combination of PANI with PIL improves morphological, structural, and storage properties of PANI, especially in H2SO4 1 mol·L-1. Optimizing the PANI/GO weight ratio results in the nanocomposite material with the best performance.
Article
Materials Science, Multidisciplinary
Hasan Hamedani, Amirmohammad Khosravi Ghasemi, Meysam Seyfi Kafshgari, Yalda Zolfaghari, Leila Asadi Kafshgari
Summary: Recent years have seen a growing demand for flexible and portable high-power, high-density electronic devices. Researchers are particularly interested in flexible energy storage devices such as supercapacitors and batteries. Metal-organic frameworks (MOFs) are attractive for electrochemical applications because of their high porosity and ability to store high charges. Nanocomposite materials based on MIL-100(Fe) were synthesized using Polyaniline and Graphene (Gr) nanosheets. Multiple characterization approaches were utilized. PANI/Gr/MIL-100(Fe) was reported as a supercapacitor electrode with capacitive energy storage properties for the first time. It exhibited a maximum specific capacitance of 638 F/g at 1 A/g in acidic electrolyte, along with the lowest charge transfer resistance among the compounds produced. Furthermore, a PANI/Gr/MIL-100/Active carbon (AC) asymmetric supercapacitor showed exceptional electrochemical performance, achieving a high energy density (53 Wh/kg) and a high-power density (1225 W/kg). This outstanding performance is attributed to the facilitated electron transport structure, large surface area, and synergistic effects between the three components. It indicates a promising future for flexible next-generation supercapacitors.
Article
Energy & Fuels
Jiaming Wang, Ying Huang, Yan Gao, Jiayi Dai, Xu Sun
Summary: Carbon nanofibers (CNFs) have attracted considerable attention due to their ability to enhance the properties of materials. This paper proposes a method to enhance the electrochemical performance and flexibility of CNFs by using electrostatic self-assembly and a dipping and drying strategy. The resulting PAN@rGO@PPy electrode shows specific capacitance of 203 F g(-1) and high energy density of 15 Wh kg(-1) in a flexible supercapacitor. It also demonstrates remarkable cycling stability after 10,000 cycles. The research provides valuable insights for the development of flexible energy storage devices.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Yang Zhang, Zejia Bi, Yunxia Liang, Weiwei Zuo, Guiyin Xu, Meifang Zhu
Summary: In this study, a porous graphene/carbon nanotube/tin oxide (PP-GCS) fiber was successfully fabricated, showing excellent electrochemical performance and high line capacity. This work provides a promising method for the production of flexible power devices.
ENERGY STORAGE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Kevser Gundugar, Fatih Semerci
Summary: Metal-organic frameworks (MOFs) have attracted attention in electrochemistry for their high porosity and potential high charge storage abilities. A new nanocomposite material based on MIL-101(Fe) was synthesized with reduced graphene oxide (rGO) and polyaniline (PANI). The electrochemical properties of the composites in different electrolytes were investigated, and it was found that rGO/MIL-101(Fe) exhibited the highest specific capacitance in alkaline electrolyte.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Physical
Amirhossein Ghasemi Kenesi, Mohsen Ghorbani, Mohammad Soleimani Lashkenari
Summary: In the last decade, the production of clean and sustainable energy sources for energy storage purposes has grown significantly. Supercapacitors have been proven to be promising candidates in energy storage applications. In this study, a PANI/CdO/GO nanocomposite was prepared by coprecipitation method and its electrochemical performance was evaluated.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Electrochemistry
Ruiying Wang, Weijun Li, Lan Jiang, Qiao Liu, Lin Wang, Bin Tang, Weiyou Yang
Summary: This study reports the exploration of electrodes based on hierarchical SiC@polyaniline (SiC@PANI) core/shell nanowire arrays, which exhibit high specific capacitance, good rate performance, and high stability. The excellent electrochemical performance of the electrode is mainly attributed to the rational design and the combination of advantages from SiC and PANI.
ELECTROCHIMICA ACTA
(2022)
Article
Physics, Condensed Matter
Jnanendra Upadhyay, Trishna Moyi Das, Rajiv Borah, Kaushik Paul, Kalyan Acharjya
Summary: In this study, ternary nanocomposites consisting of reduced graphene oxide, ruthenium oxide, and polyaniline nanofiber were fabricated for use as a flexible electrode in supercapacitors. The nanocomposites exhibited an areal capacitance as high as 1.5 F cm-2, demonstrating their potential as electrode materials for supercapacitors.
SOLID STATE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Seyyed Alireza Hashemi, Hamid Reza Naderi, Seyyed Mojtaba Mousavi, Sonia Bahrani, Mohammad Arjmand, Ayrat M. Dimiev, Seeram Ramakrishna
Summary: By enhancing polymeric configurations with silver nanowires, the specific capacitance of polypyrrole and polyindole was significantly increased, with the Ag-PIN configuration demonstrating superior performance when combined with LArGO in an asymmetric supercapacitor. The resulting electrodes showed excellent specific capacitance retention, high specific capacitance, and energy density even after 5000 cycles, highlighting the great potential of the hybrid package in bridging the gap between high-performance batteries and supercapacitors.
Article
Chemistry, Inorganic & Nuclear
Suleyman Kerli, Shiva Bhardwaj, Wang Lin, Ram K. Gupta
Summary: In this study, graphene oxide was synthesized using the Hummers method and reduced graphene oxide was obtained via the hydrothermal method. Silver-doped Reduced Graphene Oxide/Polyaniline (Ag-doped rGO/PANI) composites were then synthesized. Physical and electrochemical properties of the composites were analyzed, and the material containing approximately 17% silver-doped reduced graphene oxide exhibited the best performance in terms of stability and specific capacitance.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Engineering, Electrical & Electronic
Hongyan Li, Qian Yang, Hongli Liu, Jing Li, Wenjin Yuan, Bo Zhang
Summary: This study introduced the folding and enhancement theory into the construction of graphene aerogels, achieving self-enhancement and enhanced electrochemical properties through the folding of graphene lamellae by copper ions and conversion to copper oxides. The molecular structure, surface microstructure, mechanical, and electrochemical properties of fGA/CuO were thoroughly studied using FTIR, XPS, SEM, BET, CV, GCD, and EIS techniques, demonstrating successful improvement in mechanical and electrochemical performance.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)