4.5 Article

Effect of Gd3+ doping and reaction temperature on structural and optical properties of CdS nanoparticles

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ELSEVIER
DOI: 10.1016/j.mseb.2015.06.007

Keywords

Gd:CdS NPs; Aqueous synthesis; XRD; Electron microscopy; Optical properties; Photoluminescence

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CdS and Gd3+ ions doped CdS nanoparticles have been prepared at two reaction temperatures 90 and 120 degrees C in aqueous medium in presence of cationic surfactant cetyltrimethylammonium bromide. X-ray diffraction study revealed predominant formation of zinc blend CdS and Gd:CdS at 90 degrees C, while at 120 degrees C, phase pure wurtzite CdS and Gd:CdS were formed. From EDX spectra and ICP-OES analysis, successful doping of Gd3+ ions in CdS host has been proved. Fourier transform infrared spectroscopy results show the interaction of CTAB through headgroup at the nanoparticles surface. In the transmission electron microscopy images, it has been observed that the reaction temperature and Gd3+ doping played critical role on size and shape of nanocrystals. In UV-visible absorption as well as photoluminescence emission spectra, size and shape-dependent quantum confinement effect has been observed. On Gd3+ doping, surface states related emission peak shifted to higher wavelength, while intensity of peaks increased on increasing temperature. (C) 2015 Elsevier B.V. All rights reserved.

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