Journal
ARABIAN JOURNAL OF CHEMISTRY
Volume 5, Issue 4, Pages 517-522Publisher
ELSEVIER
DOI: 10.1016/j.arabjc.2010.09.020
Keywords
Composite materials; Chemical synthesis; Electrochemical impedance; Adsorption; Corrosion
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Poly (vinyl alcohol - aniline) PVAA composite was tested for its performance in protecting mild steel MS against corrosion in 1 M HCl. The inhibitive parameters were evaluated by means of weight loss, electrochemical polarization and impedance methods. Results indicated that the addition of PVAA to the acid reduces the corrosion of the metal. Inhibition efficiency increases with increase in inhibitor concentration. The results further revealed that PVAA at a concentration of 2000 ppm furnishes a maximum of 92% inhibition efficiency. Thermodynamic parameters such as free energy of adsorption, heat of adsorption, etc., had been evaluated from temperature studies. The adsorption of PVAA followed Langmuir and Temkin adsorption isotherms. Polarization curves revealed that PVAA is a mixed inhibitor. (C) 2010 King Saud University. Production and hosting by Elsevier B. V. All rights reserved.
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