4.8 Article

Plasmon-Active Nano-Aperture Window Electrodes for Organic Photovoltaics

Journal

ADVANCED ENERGY MATERIALS
Volume 3, Issue 2, Pages 193-199

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201200502

Keywords

electrode; silver; photovoltaic; plasmon; gold; solar cell

Funding

  1. UK Engineering and Physical Sciences Research Council (EPSRC)
  2. European Regional Development Agency/Advantage West Midlands Science City Materials Initiative [2]
  3. Royal Academy of Engineering/EPSRC

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A lithography free approach to fabricating optically thin (approximate to 10 nm) noble metal electrodes with a dense array of sub-wavelength apertures is reported. These nano-structured electrodes support surface plasmon resonances which couple strongly with visible light concentrating it near to the electrode surface. They are also remarkably robust and can be fabricated on glass and plastic substrates with a sheet resistance of <15 sq1. As the window electrode in solution processed and vacuum deposited organic photovoltaics (OPV) the photocurrent is increased by as much as 28% as compared to identical devices without apertures, demonstrating that the apertures do not need to have a tight size and/or shape distribution to be effective. As a drop-in replacement for the indium-tin oxide electrode in flexible OPV these plasmon-active electrodes offer superior performance; 5.1% vs. 4.6%, demonstrating that this class of electrode is a truly viable alternative to conducting oxide window electrodes for OPV.

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