Journal
ACS CATALYSIS
Volume 3, Issue 11, Pages 2501-2504Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cs400703u
Keywords
iodine; cascade reaction; formal [3+3] cycloaddition reaction; carbolines; indolyl alcohol
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Funding
- Natural Science Foundation of China [21172162, 21372174]
- Young National Natural Science Foundation of China [21202111]
- Young Natural Science Foundation of Jiangsu Province [BK2012174]
- Key Laboratory of Organic Synthesis of Jiangsu Province [KJS1211]
- PAPD
- Soochow University
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A simple and practical method for the synthesis of spirodihydrocarboline derivatives from indolyl alcohol derivatives with enaminones via an iodine-catalyzed cascade formal [3 + 3] cycloaddition reaction has been developed. The reaction afforded the desired products under mild conditions in moderate to good yields with excellent regioselectivities.
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