4.8 Article

A miniaturized solid salt reverse electrodialysis battery: a durable and fully ionic power source

Journal

CHEMICAL SCIENCE
Volume 9, Issue 42, Pages 8071-8076

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc02954g

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Funding

  1. Nano Material Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2011-0030268]

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A novel pump-free miniaturized reverse electrodialysis (RED) system was designed to provide lasting power transduced from salinity gradients, named solid salt RED (ssRED), and this quasi-battery uses a solid salt instead of electrolyte solution for streamlined usage. It is portable, flexible, comparable in size to a universal serial bus flash drive, and easily activated with a small amount of water. It maintains a constant ionic concentration gradient through precipitation reactions between a pair of different salts. This precipitation-assisted solid salt RED (PssRED) is an unprecedented ionic power source as it can generate steady electricity in the absence of a driving pump. The PssRED was successfully coupled with bipolar electrode (BPE) microchip sensors which require stable ionic electricity and a polyelectrolyte ionic diode to realize a fully ionic circuit. It is envisioned that the range of application could be expanded to supply electromotive force to various devices through an ionic charge flow.

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