A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight

Manganese-Catalyzed Hydrofunctionalization of Alkenes

(2018) Jonathan R. Carney et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Hydrosilylation Reactions

(2018) Xiaoxu Yang et al.   Chemistry-An Asian Journal

Synthesis, Characterization, and Thermal Properties of N-alkyl β-Diketiminate Manganese Complexes

(2018) Madelyn M. Stalzer et al.   INORGANIC CHEMISTRY

Iron-Catalyzed Highly Enantioselective Hydrosilylation of Unactivated Terminal Alkenes

(2018) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

(2018) Meng-Yang Hu et al.   Nature Communications

Polymers from Bioderived Resources: Synthesis of Poly(silylether)s from Furan Derivatives Catalyzed by a Salen–Mn(V) Complex

(2018) Srikanth Vijjamarri et al.   ACS Sustainable Chemistry & Engineering

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes

(2017) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes

(2017) Yang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation

(2017) Tufan K. Mukhopadhyay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide

(2017) Jamie H. Docherty et al.   Nature Chemistry

Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands

(2017) Yuki Toya et al.   ORGANOMETALLICS

Hydrosilylation of Aldehydes and Formates Using a Dimeric Manganese Precatalyst

(2017) Tufan K. Mukhopadhyay et al.   ORGANOMETALLICS

Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

(2017) Chao Wang et al.   Nature Communications

Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

(2017) Balaram Raya et al.   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

(2016) Amy J. Challinor et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex

(2016) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Metal-Catalyzed Regiodivergent Alkene Hydrosilylations

(2016) Xiaoyong Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The cobalt(II) complex of a new tridentate Schiff-base ligand as a catalyst for hydrosilylation of olefins

(2016) Adam Gorczyński et al.   CATALYSIS COMMUNICATIONS

Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes

(2016) Venu Srinivas et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ph(i-PrO)SiH2: An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers

(2016) Carla Obradors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis

(2016) Wan-Yi Chu et al.   ORGANOMETALLICS

Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant

(2016) Balaram Raya et al.   ACS Catalysis

Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes

(2016) Christopher H. Schuster et al.   ACS Catalysis

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

(2016) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Highly active and selective catalysts for olefin hydrosilylation reactions using metalloporphyrins intercalated in natural clays

(2016) Waheed Jondi et al.   Reaction Chemistry & Engineering

Iron-Catalyzed Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

(2015) Jianhui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Iron Catalyst for Asymmetric Alkene Hydrosilylation

(2015) Georgii I. Nikonov   ChemCatChem

Phosphine-Iminopyridines as Platforms for Catalytic Hydrofunctionalization of Alkenes

(2015) Ryan Gilbert-Wilson et al.   INORGANIC CHEMISTRY

A Pentacoordinate Mn(II) Precatalyst That Exhibits Notable Aldehyde and Ketone Hydrosilylation Turnover Frequencies

(2015) Chandrani Ghosh et al.   INORGANIC CHEMISTRY

Intramolecular C–C Bond Coupling of Nitriles to a Diimine Ligand in Group 7 Metal Tricarbonyl Complexes

(2015) Veeranna Yempally et al.   INORGANIC CHEMISTRY

Hydrosilylation vs. dehydrogenative silylation of styrene catalysed by iron(0) carbonyl complexes with multivinylsilicon ligands – Mechanistic implications

(2015) Bogdan Marciniec et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of alkanes to linear alkylsilanes using an iridium–iron-catalysed tandem dehydrogenation–isomerization–hydrosilylation

(2015) Xiangqing Jia et al.   Nature Chemistry

Combinatorial Approach to the Catalytic Hydrosilylation of Styrene Derivatives: Catalyst Systems Composed of Organoiron(0) or (II) Precursors and Isocyanides

(2015) Yusuke Sunada et al.   ORGANOMETALLICS

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

(Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins

(2015) Venu Srinivas et al.   Catalysis Science & Technology

Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench-Stable Iron(II) Pre-Catalyst

(2014) Mark D. Greenhalgh et al.   ADVANCED SYNTHESIS & CATALYSIS

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts

(2014) Ryan Trovitch   SYNLETT

Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation

(2013) Dongjie Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters

(2013) Tufan K. Mukhopadhyay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(ii) complex

(2012) Michael I. Lipschutz et al.   CHEMICAL COMMUNICATIONS

Facile Metalation of Silicon and Germanium Analogues of Thiocarboxylic Acids with a Manganese(II) Hydride Precursor

(2012) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

Synthesis, Electronic Structure, and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes

(2012) Aaron M. Tondreau et al.   ORGANOMETALLICS

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

(2012) Kouji Kamata et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

Global Release Liner Industry Conference 2008

(2008) Andrew J. Holwell