Electronic and molecular structures of the active-site H-cluster in [FeFe]-hydrogenase determined by site-selective X-ray spectroscopy and quantum chemical calculations

Catalytic Hydrogen Oxidation: Dawn of a New Iron Age

(2013) Trevor R. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation

(2013) Wendy J. Shaw et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Molecular basis of [FeFe]-hydrogenase function

(2013) Martin Winkler et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT

(2013) Nils Leidel et al.   DALTON TRANSACTIONS

Rapid X-ray Photoreduction of Dimetal-Oxygen Cofactors in Ribonucleotide Reductase

(2013) Kajsa G. V. Sigfridsson et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

EPR and FTIR Analysis of the Mechanism of H2 Activation by [FeFe]-Hydrogenase HydA1 from Chlamydomonas reinhardtii

(2013) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

(2013) Julian Esselborn et al.   Nature Chemical Biology

Simultaneous Femtosecond X-ray Spectroscopy and Diffraction of Photosystem II at Room Temperature

(2013) J. Kern et al.   SCIENCE

Inaccessibility of the μ-hydride species in [FeFe] hydrogenases

(2013) Arndt R. Finkelmann et al.   Chemical Science

Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic

(2012) Stuart E. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emerging Paradigms for Complex Iron-Sulfur Cofactor Assembly and Insertion

(2012) John W. Peters et al.   Annual Review of Biochemistry

Nuclear Resonance Vibrational Spectroscopy and Electron Paramagnetic Resonance Spectroscopy of 57Fe-Enriched [FeFe] Hydrogenase Indicate Stepwise Assembly of the H-Cluster

(2012) Jon M. Kuchenreuther et al.   BIOCHEMISTRY

Site-Selective X-ray Spectroscopy on an Asymmetric Model Complex of the [FeFe] Hydrogenase Active Site

(2012) Nils Leidel et al.   INORGANIC CHEMISTRY

Pyruvate:Ferredoxin Oxidoreductase Is Coupled to Light-independent Hydrogen Production inChlamydomonas reinhardtii

(2012) Jens Noth et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Electronic Structure of an [FeFe] Hydrogenase Model Complex in Solution Revealed by X-ray Absorption Spectroscopy Using Narrow-Band Emission Detection

(2012) Nils Leidel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inhibition of [FeFe]-Hydrogenases by Formaldehyde and Wider Mechanistic Implications for Biohydrogen Activation

(2012) Carina E. Foster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogenases and oxygen

(2012) Martin Tillmann Stiebritz et al.   Chemical Science

Carbon/iron-based nanorod catalysts for hydrogen production in microbial electrolysis cells

(2012) Li Xiao et al.   Nano Energy

Noncovalent Modification of Carbon Nanotubes with Pyrene-Functionalized Nickel Complexes: Carbon Monoxide Tolerant Catalysts for Hydrogen Evolution and Uptake

(2011) Phong D. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct electrochemistry of an [FeFe]-hydrogenase on a TiO2 Electrode

(2011) Simone Morra et al.   CHEMICAL COMMUNICATIONS

Biosynthesis of complex iron–sulfur enzymes

(2011) Eric M Shepard et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Approaches to efficient molecular catalyst systems for photochemical H2 production using [FeFe]-hydrogenase active site mimics

(2011) Mei Wang et al.   DALTON TRANSACTIONS

Prediction of high-valent iron K-edge absorption spectra by time-dependent Density Functional Theory

(2011) P. Chandrasekaran et al.   DALTON TRANSACTIONS

Targeting Intermediates of [FeFe]-Hydrogenase by CO and CN Vibrational Signatures

(2011) Lian Yu et al.   INORGANIC CHEMISTRY

Manganese Kβ X-ray Emission Spectroscopy As a Probe of Metal–Ligand Interactions

(2011) Martha A. Beckwith et al.   INORGANIC CHEMISTRY

Importance of the Protein Framework for Catalytic Activity of [FeFe]-Hydrogenases

(2011) Philipp Knörzer et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

O2Reactions at the Six-iron Active Site (H-cluster) in [FeFe]-Hydrogenase

(2011) Camilla Lambertz et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Mechanism of Proton Transfer in [FeFe]-Hydrogenase fromClostridium pasteurianum

(2011) Adam J. Cornish et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

A Review on Hydrogen Production: Methods, Materials and Nanotechnology

(2011) Yizhao Lang et al.   JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY

Formaldehyde—A Rapid and Reversible Inhibitor of Hydrogen Production by [FeFe]-Hydrogenases

(2011) Annemarie F. Wait et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CO Disrupts the Reduced H-Cluster of FeFe Hydrogenase. A Combined DFT and Protein Film Voltammetry Study

(2011) Carole Baffert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselectivity of H Cluster Oxidation

(2011) Marta K. Bruska et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Merging the old with the new

(2011) Marcetta Y. Darensbourg et al.   Nature Chemistry

‘Renewable’ hydrogen: Prospects and challenges

(2011) Tasneem Abbasi et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Ironing Out Hydrogen Storage

(2011) S. Ott   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Insights into [FeFe]-Hydrogenase Structure, Mechanism, and Maturation

(2011) David W. Mulder et al.   STRUCTURE

Advanced X-ray absorption and emission spectroscopy: in situ catalytic studies

(2010) Jagdeep Singh et al.   CHEMICAL SOCIETY REVIEWS

The Hydrogen Issue

(2010) Nicola Armaroli et al.   ChemSusChem

The iron-site structure of [Fe]-hydrogenase and model systems: an X-ray absorption near edge spectroscopy study

(2010) Marco Salomone-Stagni et al.   DALTON TRANSACTIONS

The quest for a functional substrate access tunnel in FeFe hydrogenase

(2010) Thomas Lautier et al.   FARADAY DISCUSSIONS

The [FeFe]-hydrogenase maturation protein HydF contains a H-cluster like [4Fe4S]-2Fe site

(2010) Ilka Czech et al.   FEBS LETTERS

Quantum Refinement of [FeFe] Hydrogenase Indicates a Dithiomethylamine Ligand

(2010) Ulf Ryde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydride-Containing Models for the Active Site of the Nickel−Iron Hydrogenases

(2010) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy

(2010) Nicole Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stepwise [FeFe]-hydrogenase H-cluster assembly revealed in the structure of HydAΔEFG

(2010) David W. Mulder et al.   NATURE

High-Yield Expression of Heterologous [FeFe] Hydrogenases in Escherichia coli

(2010) Jon M. Kuchenreuther et al.   PLoS One

The Structure of the Active Site H-Cluster of [FeFe] Hydrogenase from the Green AlgaChlamydomonas reinhardtiiStudied by X-ray Absorption Spectroscopy

(2009) Sven Stripp et al.   BIOCHEMISTRY

Spectroelectrochemical Characterization of the Active Site of the [FeFe] Hydrogenase HydA1 fromChlamydomonas reinhardtii

(2009) Alexey Silakov et al.   BIOCHEMISTRY

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

The Role of Chemistry in the Energy Challenge

(2009) Robert Schlögl   ChemSusChem

How algae produce hydrogen—news from the photosynthetic hydrogenase

(2009) Sven T. Stripp et al.   DALTON TRANSACTIONS

Isomerization of the hydride complexes [HFe2(SR)2(PR3)x(CO)6−x]+(x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases

(2009) Bryan E. Barton et al.   DALTON TRANSACTIONS

Biomimetic Model Featuring the NH Proton and Bridging Hydride Related to a Proposed Intermediate in Enzymatic H2Production by Fe-Only Hydrogenase

(2009) Ming-Hsi Chiang et al.   INORGANIC CHEMISTRY

Preparation, Facile Deprotonation, and Rapid H/D Exchange of the μ-Hydride Diiron Model Complexes of the [FeFe]-Hydrogenase Containing a Pendant Amine in a Chelating Diphosphine Ligand

(2009) Ning Wang et al.   INORGANIC CHEMISTRY

Theoretical Study of Dioxygen Induced Inhibition of [FeFe]-Hydrogenase

(2009) Martin T. Stiebritz et al.   INORGANIC CHEMISTRY

Characterization of the Key Step for Light-driven Hydrogen Evolution in Green Algae

(2009) Martin Winkler et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Immobilization of the [FeFe]-hydrogenase CrHydA1 on a gold electrode: Design of a catalytic surface for the production of molecular hydrogen

(2009) Henning Krassen et al.   JOURNAL OF BIOTECHNOLOGY

Electrochemical Kinetic Investigations of the Reactions of [FeFe]-Hydrogenases with Carbon Monoxide and Oxygen: Comparing the Importance of Gas Tunnels and Active-Site Electronic/Redox Effects

(2009) Gabrielle Goldet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic electrochemical experiments on hydrogenases

(2009) Fraser A. Armstrong   PHOTOSYNTHESIS RESEARCH

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

How oxygen attacks [FeFe] hydrogenases from photosynthetic organisms

(2009) S. T. Stripp et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake

(2009) A. Le Goff et al.   SCIENCE

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

Structural and Electronic Properties of the [FeFe] Hydrogenase H-Cluster in Different Redox and Protonation States. A DFT Investigation

(2008) Maurizio Bruschi et al.   INORGANIC CHEMISTRY

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY

Refining the Active Site Structure of Iron−Iron Hydrogenase Using Computational Infrared Spectroscopy

(2008) Jesse W. Tye et al.   INORGANIC CHEMISTRY

Optimized over-expression of [FeFe] hydrogenases with high specific activity in Clostridium acetobutylicum

(2008) G VONABENDROTH et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Prediction of Iron K-Edge Absorption Spectra Using Time-Dependent Density Functional Theory†

(2008) Serena DeBeer George et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster

(2008) Arti S. Pandey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-to-ligand and ligand-to-metal charge transfer in thin films of Prussian blue analogues investigated by X-ray absorption spectroscopy

(2008) Sébastien Bonhommeau et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A Natural Choice for Activating Hydrogen

(2008) F. A. Armstrong et al.   SCIENCE