Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation

Enantioselective Intramolecular CH Amination Catalyzed by Engineered Cytochrome P450 Enzymes In Vitro and In Vivo

(2013) John A. McIntosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The electro-oxidation of water and alcohols at BDD in hexafluoroisopropanol

(2013) Sevda Ayata et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Secondary Coordination Sphere Influence on the Reactivity of Nonheme Iron(II) Complexes: An Experimental and DFT Approach

(2013) Sumit Sahu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions

(2013) Junying Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic Oxidation of Organic Compounds in Water by Using Ruthenium(II)-Pyridylamine Complexes as Catalysts with High Efficiency and Selectivity

(2012) Shingo Ohzu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

A Chromium(III)–Superoxo Complex in Oxygen Atom Transfer Reactions as a Chemical Model of Cysteine Dioxygenase

(2012) Jaeheung Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proximal Ligand Electron Donation and Reactivity of the Cytochrome P450 Ferric–Peroxo Anion

(2012) Santhosh Sivaramakrishnan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detection and Kinetic Characterization of a Highly Reactive Heme–Thiolate Peroxygenase Compound I

(2012) Xiaoshi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An N-bridged high-valent diiron–oxo species on a porphyrin platform that can oxidize methane

(2012) Evgeny V. Kudrik et al.   Nature Chemistry

Mechanistic insight into catalytic oxidations of organic compounds by ruthenium(iv)-oxo complexes with pyridylamine ligands

(2012) Shingo Ohzu et al.   Chemical Science

Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity

(2012) Dong Wang et al.   Chemical Science

Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex

(2011) Isaac Garcia-Bosch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand

(2011) Song Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical Study of Oxidation of Cyclohexane Diol to Adipic Anhydride by [RuIV(O)(tpa)(H2O)]2+Complex (tpa ═ Tris(2-pyridylmethyl)amine)

(2011) Yoshihito Shiota et al.   INORGANIC CHEMISTRY

Formation of a Ruthenium(IV)-Oxo Complex by Electron-Transfer Oxidation of a Coordinatively Saturated Ruthenium(II) Complex and Detection of Oxygen-Rebound Intermediates in C–H Bond Oxygenation

(2011) Takahiko Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Coupled Electron Transfer from Tyrosine: A Strong Rate Dependence on Intramolecular Proton Transfer Distance

(2011) Ming-Tian Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Reactivity of Mononuclear Iron(V)oxo Complexes

(2011) Soumen Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Mechanism of Cytochrome P450 for 5′-Hydroxylation of Nicotine: Fundamental Reaction Pathways and Stereoselectivity

(2011) Dongmei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Reactive Mononuclear Non-Heme Manganese(IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes

(2011) Xiujuan Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chromium(v)-oxo and chromium(iii)-superoxo complexes bearing a macrocyclic TMC ligand in hydrogen atom abstraction reactions

(2011) Jaeheung Cho et al.   Chemical Science

A Low-Spin Ruthenium(IV)-Oxo Complex: Does the Spin State Have an Impact on the Reactivity?

(2010) Takahiko Kojima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical predictions of a highly reactive non-heme Fe(iv)O complex with a high-spin ground state

(2010) Kyung-Bin Cho et al.   CHEMICAL COMMUNICATIONS

Proton-Coupled Electron Transfer in Cytochrome Oxidase

(2010) Ville R. I. Kaila et al.   CHEMICAL REVIEWS

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Integrating proton coupled electron transfer (PCET) and excited states

(2010) Christopher J. Gagliardi et al.   COORDINATION CHEMISTRY REVIEWS

Redox Potential and C−H Bond Cleaving Properties of a Nonheme FeIV═O Complex in Aqueous Solution

(2010) Dong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer

(2010) Shunichi Fukuzumi et al.   Nature Chemistry

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Theoretical Analysis of the Unusual Temperature Dependence of the Kinetic Isotope Effect in Quinol Oxidation

(2009) Michelle K. Ludlow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trends in Substrate Hydroxylation Reactions by Heme and Nonheme Iron(IV)-Oxo Oxidants Give Correlations between Intrinsic Properties of the Oxidant with Barrier Height

(2009) Sam P. de Visser   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium‐Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source

(2008) Yuichirou Hirai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experiment and Theory Reveal the Fundamental Difference between Two-State and Single-State Reactivity Patterns in Nonheme FeIVO versus RuIVO Oxidants

(2008) Sunder N. Dhuri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proton-Coupled Electron Transfer in Solution, Proteins, and Electrochemistry†

(2008) Sharon Hammes-Schiffer et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Tunneling in C−H Oxidation Reactions by an Oxoiron(IV) Porphyrin Radical Cation: Direct Measurements of Very Large H/D Kinetic Isotope Effects

(2008) Zhengzheng Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY