The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium(iv) and uranium(iv) alkyls

A Rare Uranyl(VI)-Alkyl Ate Complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and Its Comparison with a Homoleptic Uranium(VI)-Hexaalkyl

(2013) Lani A. Seaman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparison of the Reactivity of 2-Li-C6H4CH2NMe2with MCl4(M=Th, U): Isolation of a Thorium Aryl Complex or a Uranium Benzyne Complex

(2013) Lani A. Seaman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Molecule Magnetism in a Single-Ion Triamidoamine Uranium(V) Terminal Mono-Oxo Complex

(2013) David M. King et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in actinide–ligand multiple bonding

(2013) Trevor W. Hayton   CHEMICAL COMMUNICATIONS

The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

(2013) Oliver J. Cooper et al.   CHEMISTRY-A EUROPEAN JOURNAL

Progress in molecular uranium-nitride chemistry

(2013) David M. King et al.   COORDINATION CHEMISTRY REVIEWS

Small-Molecule Activation at Uranium(III)

(2013) Benedict M. Gardner et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Stable Uranium(VI) Methyl and Acetylide Complexes and the Elucidation of an Inverse Trans Influence Ligand Series

(2013) Andrew J. Lewis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantifying the σ and π Interactions between U(V) f Orbitals and Halide, Alkyl, Alkoxide, Amide and Ketimide Ligands

(2013) Wayne W. Lukens et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revisiting the Chemistry of the Actinocenes [(η8-C8H8)2An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η8-C8H8)2An(L)] with Thorium (L = py, 4,4′-bipy, tBuNC, R4phen)

(2013) Jean-Claude Berthet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C5H4SiMe3)3U]

(2013) Matthew R. MacDonald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tetrahalide Complexes of the [U(NR)2]2+ Ion: Synthesis, Theory, and Chlorine K-Edge X-ray Absorption Spectroscopy

(2013) Liam P. Spencer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and characterization of a uranium(VI)–nitride triple bond

(2013) David M. King et al.   Nature Chemistry

Recent Advances in Organoactinide Chemistry As Exemplified by Cyclopentadienyl Compounds

(2013) Michel Ephritikhine   ORGANOMETALLICS

σ-Bond Metathesis: A 30-Year Retrospective

(2013) Rory Waterman   ORGANOMETALLICS

Reductive assembly of cyclobutadienyl and diphosphacyclobutadienyl rings at uranium

(2013) Dipti Patel et al.   Nature Communications

Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

(2012) Matthew B. Jones et al.   CHEMICAL REVIEWS

Cyclometalative C–H bond activation in rare earth and actinide metal complexes

(2012) Kevin R. D. Johnson et al.   CHEMICAL SOCIETY REVIEWS

Covalency in f-element complexes

(2012) Michael L. Neidig et al.   COORDINATION CHEMISTRY REVIEWS

In Pursuit of Homoleptic Actinide Alkyl Complexes

(2012) Lani A. Seaman et al.   INORGANIC CHEMISTRY

Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning

(2012) Nikolas Kaltsoyannis   INORGANIC CHEMISTRY

Uranium–Ligand Multiple Bonding in Uranyl Analogues, [L═U═L]n+, and the Inverse Trans Influence

(2012) Henry S. La Pierre et al.   INORGANIC CHEMISTRY

Uranium and Thorium Hydride Complexes as Multielectron Reductants: A Combined Neutron Diffraction and Quantum Chemical Study

(2012) Daniel J. Grant et al.   INORGANIC CHEMISTRY

Carbon–Carbon Reductive Elimination from Homoleptic Uranium(IV) Alkyls Induced by Redox-Active Ligands

(2012) Steven J. Kraft et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the 5f Orbital Contribution to the Bonding in a U(V) Ketimide Complex

(2012) Lani A. Seaman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diamido-Ether Actinide Complexes as Catalysts for the Intramolecular Hydroamination of Aminoalkenes

(2012) Cassandra E. Hayes et al.   ORGANOMETALLICS

Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes

(2012) Nikolaos Tsoureas et al.   ORGANOMETALLICS

Homologation and functionalization of carbon monoxide by a recyclable uranium complex

(2012) B. M. Gardner et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Synthesis and Structure of a Terminal Uranium Nitride Complex

(2012) D. M. King et al.   SCIENCE

An Unsupported Uranium-Rhenium Complex Prepared by Alkane Elimination

(2011) Benedict M. Gardner et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Nature of Unsupported Uranium-Ruthenium Bonds: A Combined Experimental and Theoretical Study

(2011) Benedict M. Gardner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Halide, Amide, Cationic, Manganese Carbonylate, and Oxide Derivatives of Triamidosilylamine Uranium Complexes

(2011) Benedict M. Gardner et al.   INORGANIC CHEMISTRY

Facile Reduction of a Uranyl(VI) β-Ketoiminate Complex to U(IV) Upon Oxo Silylation

(2011) Jessie L. Brown et al.   INORGANIC CHEMISTRY

Synthesis of a Phosphorano-Stabilized U(IV)-Carbene via One-Electron Oxidation of a U(III)-Ylide Adduct

(2011) Skye Fortier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Valent Uranium Alkyls: Evidence for the Formation of UVI(CH2SiMe3)6

(2011) Skye Fortier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials

(2010) Thibault Cantat et al.   CHEMICAL COMMUNICATIONS

Ligand assisted cleavage of uranium oxo-clusters

(2010) Grégory Nocton et al.   CHEMICAL COMMUNICATIONS

Structural and theoretical insights into the perturbation of uranium–rhenium bonds by dative Lewis base ancillary ligands

(2010) Dipti Patel et al.   CHEMICAL COMMUNICATIONS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Are 5f Electrons Really Active in Organoactinide Reactivity? Some Insights from DFT Studies

(2010) Ludovic Castro et al.   CHEMPHYSCHEM

A DFT study of the reactivity of Cp2AnMe2 with pyridine N-oxide: Towards a predicted different reactivity of U/Pu and Np

(2010) Ludovic Castro et al.   COMPTES RENDUS CHIMIE

A DFT study of the reactivity of actinidocenes (U, Np and Pu) with pyridine and pyridine N-oxide derivatives

(2010) Ludovic Castro et al.   DALTON TRANSACTIONS

Importance of Energy Level Matching for Bonding in Th3+-Am3+Actinide Metallocene Amidinates, (C5Me5)2[iPrNC(Me)NiPr]An

(2010) Justin R. Walensky et al.   INORGANIC CHEMISTRY

Reversible C−C Coupling in a Uranium Biheterocyclic Complex

(2010) Marisa J. Monreal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inter- and Intramolecular Hydroamination with a Uranium Dialkyl Precursor

(2010) Erin M. Broderick et al.   ORGANOMETALLICS

Diamido-Ether Uranium(IV) Alkyl Complexes as Single-Component Ethylene Polymerization Catalysts

(2010) Cassandra E. Hayes et al.   ORGANOMETALLICS

σ and π Donation in an Unsupported Uranium-Gallium Bond

(2009) Stephen T. Liddle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state

(2009) Christopher R. Graves et al.   CHEMICAL COMMUNICATIONS

Synthesis and structure of [{N(CH2CH2NSiMe3)3}URe(η5-C5H5)2]: a heterobimetallic complex with an unsupported uranium–rhenium bond

(2009) Benedict M. Gardner et al.   CHEMICAL COMMUNICATIONS

Influence of steric pressure on the activation of carbon dioxide and related small molecules by uranium coordination complexes

(2009) Oanh P. Lam et al.   DALTON TRANSACTIONS

Homoleptic Uranium(IV) Alkyl Complexes: Synthesis and Characterization

(2009) Skye Fortier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh4−To Give the BPh2-Functionalized Metallocycle [U{N(CH2CH2NSiMe3)2(CH2CH2NSiMe2CHBPh2)}(THF)]

(2009) Benedict M. Gardner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

(2009) Stosh A. Kozimor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Thorium Alkyl Complexes of Rigid NON- and NNN-Donor Ligands: π-Arene Coordination as a Persistent Structural Motif

(2009) Carlos A. Cruz et al.   ORGANOMETALLICS

Is Thorium a d Transition Metal or an Actinide? An Answer from a DFT Study of the Reaction between PyridineN-Oxide and Cp2M(CH3)2with M = Zr, Th, and U

(2009) Ahmed Yahia et al.   ORGANOMETALLICS

Structural and Spectroscopic Characterization of a Charge-Separated Uranium Benzophenone Ketyl Radical Complex

(2008) Oanh P. Lam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes

(2008) Thibault Cantat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Reductive Cyclooligomerisation of CO by U(III) Mixed Sandwich Complexes; the Molecular Structure of [(U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)]2(μ-η1:η1-C2O2)

(2008) Alistair S. Frey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding

(2008) Christopher R. Graves et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards uranium catalysts

(2008) Alexander R. Fox et al.   NATURE

Theoretical Studies of the sp2versus sp3C−H Bond Activation Chemistry of 2-Picoline by (C5Me5)2An(CH3)2Complexes (An = Th, U)

(2008) Ping Yang et al.   ORGANOMETALLICS

General Preparation of (N3N)ZrX (N3N = N(CH2CH2NSiMe3)33−) Complexes from a Hydride Surrogate

(2008) Andrew J. Roering et al.   ORGANOMETALLICS

Recent advances in organothorium and organouranium catalysis

(2007) Tamer Andrea et al.   CHEMICAL SOCIETY REVIEWS

Single and Double Alkyl Abstraction from a Bis(anilido)xanthene Thorium(IV) Dibenzyl Complex: Isolation of an Organothorium Cation and a Thorium Dication

(2007) Carlos A. Cruz et al.   ORGANOMETALLICS