Journal
CHEMICAL SCIENCE
Volume 4, Issue 8, Pages 3239-3243Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc51313k
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Funding
- National Basic Research Program of China (973 Program) [2009CB825300]
- NSFC [20923005, 21025209, 21121062]
- Chinese Academy of Sciences
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The intermolecular dearomatization reaction of indoles with allylic alcohols has been realized by a Ru-complex in the presence of catalytic amount of TsOH center dot H2O. The reaction proceeded mainly via a cascade sequence including allylic dearomatization/cyclization/allylic amination reaction, enabling the introduction of an allylic substituent at both the C-3 and N-1 positions of indoles.
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