On the reactivity and selectivity of donor glycosides in glycochemistry and glycobiology: trapped covalent intermediates

The Reaction Coordinate of a Bacterial GH47 α-Mannosidase: A Combined Quantum Mechanical and Structural Approach

(2012) Andrew J. Thompson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel Activity-Based Probes for Broad-Spectrum Profiling of Retaining β-Exoglucosidases In Situ and In Vivo

(2012) Wouter W. Kallemeijn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

β-Rhamnosides from 6-thio mannosides

(2012) Alphert E. Christina et al.   CHEMICAL COMMUNICATIONS

Tuning the leaving group in 2-deoxy-2-fluoroglucoside results in improved activity-based retaining β-glucosidase probes

(2012) Marthe T. C. Walvoort et al.   CHEMICAL COMMUNICATIONS

Mechanistic Insights into the 1,3-Xylanases: Useful Enzymes for Manipulation of Algal Biomass

(2012) Ethan D. Goddard-Borger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dissecting the mechanisms of a class of chemical glycosylation using primary 13C kinetic isotope effects

(2012) Min Huang et al.   Nature Chemistry

Conformational Analyses of the Reaction Coordinate of Glycosidases

(2011) Gideon J. Davies et al.   ACCOUNTS OF CHEMICAL RESEARCH

Activity-Based Profiling of Retaining β-Glucosidases: A Comparative Study

(2011) Martin D. Witte et al.   CHEMBIOCHEM

Do Glycosyl Sulfonium Ions Engage in Neighbouring-Group Participation? A Study of Oxathiane Glycosyl Donors and the Basis for their Stereoselectivity

(2011) Martin A. Fascione et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoselective Synthesis of 2,3-Diamino-2,3-dideoxy-β-d-mannopyranosyl Uronates

(2011) Marthe T. C. Walvoort et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic evidence for a front-side, SNi-type reaction in a retaining glycosyltransferase

(2011) Seung Seo Lee et al.   Nature Chemical Biology

Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts

(2011) Laurel K. Mydock et al.   ORGANIC LETTERS

Glycosyl Sulfonium Ions as Storable Intermediates for Glycosylations

(2011) Toshiki Nokami et al.   ORGANIC LETTERS

Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

(2010) Biao Yu et al.   CHEMICAL COMMUNICATIONS

Glycosyl donors in “unusual” conformations – influence on reactivity and selectivity

(2010) Christian M. Pedersen et al.   COMPTES RENDUS CHIMIE

Trapping and characterization of covalent intermediates of mutant retaining glycosyltransferases

(2010) Naoto Soya et al.   GLYCOBIOLOGY

Mannosazide Methyl Uronate Donors. Glycosylating Properties and Use in the Construction of β-ManNAcA-Containing Oligosaccharides

(2010) Marthe T. C. Walvoort et al.   JOURNAL OF ORGANIC CHEMISTRY

The Conformational Free-Energy Landscape of β-d-Mannopyranose: Evidence for a1S5→ B2,5→OS2Catalytic Itinerary in β-Mannosidases

(2010) Albert Ardèvol et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Reaction Coordinate of α-l-Fucosidases: A Combined Structural and Quantum Mechanical Approach

(2010) Alicia Lammerts van Bueren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultrasensitive in situ visualization of active glucocerebrosidase molecules

(2010) Martin D Witte et al.   Nature Chemical Biology

Chiral-auxiliary-mediated 1,2-cis-glycosylations for the solid-supported synthesis of a biologically important branched α-glucan

(2010) Thomas J. Boltje et al.   Nature Chemistry

Stereoelectronic Effects Determine Oxacarbenium vs β-Sulfonium Ion Mediated Glycosylations

(2010) Thomas J. Boltje et al.   ORGANIC LETTERS

Approaches to labeling and identification of active site residues in glycosidases

(2010) Stephen G. Withers et al.   PROTEIN SCIENCE

Structure of the Michaelis complex of β-mannosidase, Man2A, provides insight into the conformational itinerary of mannoside hydrolysis

(2009) Wendy A. Offen et al.   CHEMICAL COMMUNICATIONS

Stereoselective glycosylation using oxathiane glycosyl donors

(2009) Martin A. Fascione et al.   CHEMICAL COMMUNICATIONS

α- and β-Glycosyl Sulfonium Ions: Generation and Reactivity

(2009) Toshiki Nokami et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Dehydrative Sialylation of C-4-Aminated Sialyl-Hemiketal Donors with Ph2SO/Tf2O

(2009) Deju Ye et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereodirecting Effect of the Pyranosyl C-5 Substituent in Glycosylation Reactions

(2009) Jasper Dinkelaar et al.   JOURNAL OF ORGANIC CHEMISTRY

Equatorial Anomeric Triflates from Mannuronic Acid Esters

(2009) Marthe T. C. Walvoort et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β-Directing Effect of Electron-Withdrawing Groups atO-3,O-4, andO-6 Positions and α-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations

(2009) Ju Yuel Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Teaching old enzymes new tricks: engineering and evolution of glycosidases and glycosyl transferases for improved glycoside synthesisThis paper is one of a selection of papers published in this Special Issue, entitled CSBMCB — Systems and Chemical Biology, and has undergone the Journal's usual peer review process.

(2008) Fathima Aidha Shaikh et al.   Biochemistry and Cell Biology

β-Mannoside hydrolysis goes by boat

(2008) Monica M Palcic   Nature Chemical Biology

Structural and biochemical evidence for a boat-like transition state in β-mannosidases

(2008) Louise E Tailford et al.   Nature Chemical Biology

The Carbohydrate-Active EnZymes database (CAZy): an expert resource for Glycogenomics

(2008) B. L. Cantarel et al.   NUCLEIC ACIDS RESEARCH

Synthesis and Use of Mechanism-Based Protein-Profiling Probes for Retaining β-d-Glucosaminidases Facilitate Identification ofPseudomonas aeruginosaNagZ

(2007) Keith A. Stubbs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY