Journal
CHEMICAL SCIENCE
Volume 4, Issue 7, Pages 2760-2766Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3sc50587a
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- Swiss National Science Foundation (SNF)
- Federal Commission for Technology and Innovation (KTI)
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Catalytically active iridacycles are formed by cyclometalation of acetophenone imines with Ir-PHOX complexes under hydrogen atmosphere. These complexes show unusually high reactivity and enantioselectivity in the hydrogenation of alkyl methyl ketimines. The structure of the cyclometalated imine has a strong effect on the conversion and enantiomeric excess.
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