Catalytic enantioselective carbon-carbon bond formation using cycloisomerization reactions

Enantioselective Cyclizations of Silyloxyenynes Catalyzed by Cationic Metal Phosphine Complexes

(2012) Jean-François Brazeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalated N-Heterocyclic Carbene-Platinum Catalysts for the Enantioselective Cycloisomerization of Nitrogen-Tethered 1,6-Enynes

(2011) Hélène Jullien et al.   ADVANCED SYNTHESIS & CATALYSIS

La/Ag Heterobimetallic Cooperative Catalysis: A Catalytic Asymmetric Conia-Ene Reaction

(2011) Akinobu Matsuzawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Asymmetric Organocatalytic Cyclization and Cycloaddition Reactions

(2011) Albert Moyano et al.   CHEMICAL REVIEWS

Enantioselective IrI-Catalyzed Carbocyclization of 1,6-Enynes by the Chiral Counterion Strategy

(2011) Marion Barbazanges et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Synthesis of the Antidepressive Drug Candidate GSK1360707 by a Highly Enantioselective Gold-Catalyzed Enyne Cycloisomerization Reaction

(2011) Henrik Teller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters

(2011) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Highly Substituted Furans by a Copper(II)-Catalyzed Cycloisomerization–Indole Addition Reaction

(2011) Vivek Rauniyar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Diels–Alder reactions using chiral ruthenium Lewis acids and application in the total synthesis of ent-ledol

(2011) Sirinporn Thamapipol et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Highly Reusable Rhodium Catalyst-Organic Framework for the Intramolecular Cycloisomerization of 1,6-Enynes

(2011) Elizabeth G. Corkum et al.   ORGANIC LETTERS

Rhodium-Catalyzed Olefin Isomerization/Enantioselective Intramolecular Alder-Ene Reaction Cascade

(2011) Ryuichi Okamoto et al.   ORGANIC LETTERS

Desymmetrization of Cyclohexadienones via Asymmetric Michael Reaction Catalyzed by Cinchonine-Derived Urea

(2011) Qing Gu et al.   ORGANIC LETTERS

Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes

(2011) Takahiro Nishimura et al.   ORGANIC LETTERS

Mechanistic Investigation of the Enantioselective Intramolecular Stetter Reaction: Proton Transfer Is the First Irreversible Step

(2011) Jennifer L. Moore et al.   ORGANIC LETTERS

Catalytic enantioselective assembly of complex molecules containing embedded quaternary stereogenic centres from simple anisidine derivatives

(2011) Rafael Leon et al.   Chemical Science

Gold(I)-Catalyzed Enantioselective Synthesis of Functionalized Indenes

(2010) Alberto Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Gold Catalysis: Opportunities Provided by Monodentate Phosphoramidite Ligands with an Acyclic TADDOL Backbone

(2010) Henrik Teller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen- and Nitrogen-Bridged 1,6-Enynes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral phosphine-squaramides as enantioselective catalysts for the intramolecular Morita–Baylis–Hillman reaction

(2010) Hong-Liang Song et al.   CHEMICAL COMMUNICATIONS

Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea

(2010) Jing-Jing Gong et al.   CHEMICAL COMMUNICATIONS

Organocatalyzed Asymmetric Friedel-Crafts Reactions

(2010) Vincent Terrasson et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Development of a Cysteine-Catalyzed Enantioselective Rauhut−Currier Reaction

(2010) Carrie E. Aroyan et al.   JOURNAL OF ORGANIC CHEMISTRY

An Enyne Cycloisomerization Approach to the Triple Reuptake Inhibitor GSK1360707F

(2010) Nicole M. Deschamps et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

(2010) Steven G. Sethofer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ortho-Acidic aromatic thiols as efficient catalysts of intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions

(2010) Philipp S. Selig et al.   TETRAHEDRON LETTERS

Enantioselective intramolecular Morita–Baylis–Hillman reaction using chiral bifunctional phosphinothiourea as an organocatalyst

(2010) Kui Yuan et al.   TETRAHEDRON-ASYMMETRY

Mechanistic Insights on the Cycloisomerization of Polyunsaturated Precursors Catalyzed by Platinum and Gold Complexes

(2009) Elena Soriano et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iridium-Catalyzed Selective Synthesis of 4-Substituted Benzofurans and IndolesviaDirected Cyclodehydration

(2009) Kyoji Tsuchikama et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Asymmetric Enyne Cycloisomerization of Terminal Alkynes and Formal Total Synthesis of (−)-Platensimycin

(2009) K. C. Nicolaou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Construction of Polycyclic Indoles through Olefin Cross-Metathesis/Intramolecular Friedel-Crafts Alkylation under Sequential Catalysis

(2009) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Catalysis Based on Cationic Oxazaborolidines

(2009) E. J. Corey   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes

(2009) Chung-Meng Chao et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

Asymmetric Gold-Catalyzed Hydroarylation/Cyclization Reactions

(2009) Chung-Meng Chao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes

(2009) Ryo Shintani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed [4C+3C] Intramolecular Cycloaddition of Allenedienes: Synthetic Potential and Mechanistic Implications

(2009) Beatriz Trillo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Intramolecular Hydroarylations of ω-Aryloxy- and Arylamino-Tethered α,β-Unsaturated Aldehydes

(2009) Hai-Hua Lu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver and Gold Catalysis for Cycloisomerization Reactions

(2009) Philippe Belmont et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rh-Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven- and Eight-Membered Heterocycles

(2009) Matthew M. Coulter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed Enantioselective Synthesis of BenzopyransviaRearrangement of Allylic Oxonium Intermediates

(2009) Minoru Uemura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Base/Lewis Acid Cooperative Catalysis in the Enantioselective Conia-Ene Reaction

(2009) Ting Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intramolecular Michael Addition of Nitronates onto Conjugated Esters: Access to Cyclic γ-Amino Acids with up to Three Stereocenters

(2009) William J. Nodes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation

(2009) Iain D. G. Watson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways

(2009) Isaac Alonso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Construction of Axial Chirality by Palladium-Catalyzed Cycloisomerization ofN-Alkenyl Arylethynylamides

(2009) Hidetomo Imase et al.   ORGANIC LETTERS

Platinum(II) Catalysts for Highly Enantioselective 1,6-Enyne Cycloisomerizations. Synthetic, Structural, and Catalytic Studies

(2009) Delphine Brissy et al.   ORGANIC LETTERS

Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation

(2009) Eugenia Marqués-López et al.   ORGANIC LETTERS

Stereoselective Synthesis of Bicyclic Tertiary Alcohols with Quaternary Stereocenters via Intramolecular Crossed Benzoin Reactions Catalyzed byN-Heterocyclic Carbenes

(2009) Tadashi Ema et al.   ORGANIC LETTERS

On the Impact of Steric and Electronic Properties of Ligands on Gold(I)-Catalyzed Cycloaddition Reactions

(2009) Diego Benitez et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

(2009) Ana Z. González et al.   ORGANIC LETTERS

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic skeletal reorganization of enynes through electrophilicactivation of alkynes: double cleavage of C–C double and triple bonds

(2008) Sang Ick Lee et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Copper-Catalyzed Diels−Alder Reactions

(2008) Sébastien Reymond et al.   CHEMICAL REVIEWS

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Enantioselective Intramolecular Hydroarylation of Alkenes via Directed C−H Bond Activation

(2008) Hitoshi Harada et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis ofd- andl-Carbocyclic Nucleosides via Rhodium-Catalyzed Asymmetric Hydroacylation as the Key Step

(2008) Patricia Marcé et al.   ORGANIC LETTERS

Catalytic Asymmetric Stetter Reaction Onto Vinylphosphine Oxides and Vinylphosphonates

(2008) Steven C. Cullen et al.   ORGANIC LETTERS

Towards the total synthesis of FD-838: modular enantioselective assembly of the core

(2007) Arturo Orellana et al.   CHEMICAL COMMUNICATIONS

An Enantioselective Organocatalytic Oxidative Dearomatization Strategy

(2007) Ngoc T. Vo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY