4.8 Article

Supramolecular approach to the formation of magneto-active physical gels

Journal

CHEMICAL SCIENCE
Volume 3, Issue 10, Pages 3007-3010

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sc00714b

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Funding

  1. Grant-in-Aid for a Scientific Research on Innovative Areas of Fusion Materials: Creative Development of Materials and Exploration of Their Function through Molecular Control [22107003]
  2. The Global COE Program Chemistry Innovation through Cooperation of Science and Engineering from the Ministry of Education, Culture, Sports, Science and Technology

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Magnetic fibers were obtained through self-assembly of a nitroxide radical gelator derived from an L-isoleucine-based scaffold. Spins in the fibers are aligned one-dimensionally due to the parallel beta-sheet conformation of the intermolecular hydrogen bonds. The spin nanowires exhibit magnetic behavior reproducible by the Bonner-Fisher model.

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