Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 3, Issue 23, Pages 12350-12356Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta02520f
Keywords
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Funding
- 863 Program [2013AA032501]
- National Natural Science Foundation of China (NSFC)
- Ministry of Education of China [20120010120010]
- Fundamental Research Funds for the Central Universities [YS1406]
- China National Funds for Distinguished Young Scientists of the NSFC
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A high performance gas barrier film was fabricated via alternate spin-coating of chitosan (CTS) and hierarchical layered double hydroxide (H-LDH). The H-LDH synthesized by a calcination-rehydration method shows a hierarchical structure with nanowalls aligned vertically on the LDH platelets, which were subsequently assembled in the CTS matrix, generating a hybrid film with excellent gas barrier properties. Compared with the (P-LDH/CTS)(10) barrier film based on plate-like LDH (P-LDH), the (H-LDH/CTS)(10) film exhibits significantly enhanced oxygen barrier properties with an oxygen transmission rate (OTR) below the detection limit of commercial instruments (<0.005 cm(3) m(-2) day(-1) atm(-1)). The greatly improved performance of the (H-LDH/CTS)(10) film is attributed to the tortuous diffusion path in hierarchical architecture space. Moreover, experimental results and theoretical calculations reveal the existence of the adhesive force between oxygen and H-LDH (adsorption energy = -2.46 eV), which further reduces the oxygen diffusion rate and thus promotes oxygen barrier properties. Therefore, this work provides a facile and cost-effective strategy to fabricate high gas barrier materials, which can serve as a promising candidate for food/pharmaceutical packaging and encapsulation of electronic devices.
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